• Title/Summary/Keyword: Si/Al 복합

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A Study on the Mechanical Properties of AC8A/$Al_2O_3$ Composites. (용탕단조법에 의한 AC8A/$Al_2O_3$ 복합재료의 기계적 성질에 관한 연구)

  • Kim, Ki-Bae;Kim, Kyoung-Min;Cho, Soon-Hyung;Yoon, Eui-Park
    • Journal of Korea Foundry Society
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    • v.11 no.6
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    • pp.475-481
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    • 1991
  • In this study the fabrication technology and mechanical properties of AC8A/$Al_2O_3$ Composites by squeeze casting process were investigated to develope for application as the piston materials that require good friction, wear resistance, and thermal stability. AC8A/$Al_2O_3$ composistes without a porosity and the break of preform were fabricated at the melt temperature of $740^{\circ}C$, the preform temperature of $500^{\circ}C$, and mold temperature of $400^{\circ}C$ under the applied pressure of $1200kg/cm^2$ as the results of the observation of microstructures. As the results of this study, the tensile strength of AC8A/$Al_2O_3$ composites was not increased linearly with $Al_2O_3$ volume fraction and so it seemed not to agree with the rule of mixture, which had been used often in metal matrix composite. Also the tensile strength after thermal fatigue test was little different from that before the test. Consequently it was thought that AC8A/$Al_2O_3$ composites fabricated under our experimental conditions had a good thermal stability and subsequently a good interface bonding. Wear rate(i.e., volume loss per unit sliding distance) of AC8A/$Al_2O_3$ composites was decreased with $Al_2O_3$ volume fraction and the sliding speed at both room temperature and $250^{\circ}C$ and so there was a good correlation between wear rate and hardness. Also the wear rate of AC/8A20% $Al_2O_3$ composities was obtained the value of $1.65cm^3/cm$ at sliding speed of 1.14m/sec as compared with about $3.0\;{\times}10^{-8}cm^3/cm$ hyereutectie Al-Si alloy(Al-16%Si-2%Cu-1%Fe-1%Ni), which applied presently for piston materials. The wear behavior of $Al_2O_3$ composites was observed to a type of abrasive wear by the SEM view of wear surface.

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Characteristics of Shear Strength for joined SiC-SiC Ceramics (SiC세라믹스 동종재 접합재의 전단강도 특성 평가)

  • Yoon, Han Ki;Jung, Hun Chea;Hinoki, T.;Kohyama, A.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.5
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    • pp.483-487
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    • 2014
  • In this study, joining methods with SiC powder as the joining adhesives were studied in order to avoid the residual stresses coming from CTE (Coefficient of Thermal Expansion) mismatch between substrate and joining layer. The shear strength and microstructure of joined material between SiC substrates are investigated. The commercial Hexoloy-SA (Saint-Gobain Ceramics, USA) used in this work as substrate material. The fine ${\beta}$-SiC nano-powder which the average particle size is below 30 nm, $Al_2O_3$, $Y_2O_3$, and $SiO_2$ were used as joining adhesives. The specimens were joined with 20MPa and $1400-1900^{\circ}C$ by hot pressing in argon atmosphere. The shear test was performed to investigate the bonding strength. The cross-section of the joint was characterized by using an optical microscope and scanning electron microscopy (SEM).

Endurance in Al Alloy Melts and Wear Resistance of Titanium Matrix Composite Shot-Sleeve for Aluminum Alloy Die-casting (Al 합금 다이캐스팅 용 타이타늄 기지 복합재료 슬리브의 내용손성 및 내마모성 평가)

  • Choi, Bong-Jae;Sung, Si-Young;Kim, Young-Jig
    • Korean Journal of Metals and Materials
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    • v.50 no.2
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    • pp.176-182
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    • 2012
  • The main purpose of this study was to evaluate the endurance against Al alloy melts and wear resistance of an in-situ synthesized titanium matrix composite (TMC) sleeve for aluminum alloy die-casting. The conventional die-casting shot sleeve material was STD61 tool steel. TMCs have great thermal stability, wear and oxidation resistance. The in-situ reaction between Ti and $B_4C$ leads to two kinds of thermodynamically stable reinforcements, such as TiBw and TiCp. To evaluate the feasibility of the application to a TMCs diecasting shot sleeve, the interfacial reaction behavior was examined between Al alloys melts with TMCs and STD61 tool steel. The pin-on-disk type dry sliding wear test was also investigated for TMCs and STD61 tool steel.

The Permeation Characteristics of $O_{2}/N_{2}$ Gas for Composite Membrane Prepared by Plasma Polymerization (플라즈마 종합에 의해 제조된 복합막에 대한 $O_{2}/N_{2}$의 기체투과 특성)

  • 현상원;정일현
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.147-155
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    • 1998
  • In this study, we prepared non-porous plasma membrane for having high permeability and selectivity and this membrane was deposited on the $Al_{2}O_{3}$ membrane by using $CHF_{3}$ & $SiH_{4}$ monomer. Also, we investigated for the permeation characteristics of the plasma polymer membrane by Ar plasma treatment. When the position of substrate was near cathode, the selectivity was increased with Ar plasma treatment time and rf-power. The pore size of $Al_{2}O_{3}$ membrane had an effect on the permeability and the position of substrate affected selectivity.

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Characterization of the Ceramic Reinforced AC4C Matrix Composites Processed by Squeeze Casting (용탕단조법으로 제조된 AC4C 합금기 세라믹강화 복합재료의 특성연구)

  • Kim, Eok-Soo
    • Journal of Korea Foundry Society
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    • v.25 no.2
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    • pp.88-94
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    • 2005
  • The microstructure and mechanical property of the ceramic reinforced AC4C matrix composites processed by squeeze casting were investigated. In this study Kaowool and Saffil fiber which are ceramic reinforcements are used as preform materials. As a matrix material, Al-7wt.%Si-0.3wt.%Mg(AC4C) has been used. In case of Kaowool and Saffil/AC4C composites, 7.5 MPa squeezing pressure and minimum 7.0% binder amount are needed to produce sound composite materials. The tensile strength of Kaowool/ AC4C composite is lower than the matrix metal and this can be explained by the melt unfilling due to formed cluster of Kaowool reinforcements. But the mechanical properties of hardness, wear resistance and thermal expansion are better than the matrix materials due to the strengthening effect of ceramic reinforcements.

A Study on Hot Extrusion Characteristics of Particulate Reinforced Aluminium Matrix Composite. (입자분산강화 알루미늄 복합재의 압출가공특성에 관한 연구)

  • Gwon, Hyeok-Cheon;Yun, Ui-Park
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.953-959
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    • 1995
  • It was investigated that reinforced species, billet condition and extrusion variation in Al 6061 composite material effected on extrusion process of particulate reinforced composite material. The strength of composite material with reinforcement species revealed SiC$\sub$w/> A1$_2$O$\sub$3f/ > A1$_2$O$\sub$3f/ > A1$_2$O$\sub$3f/ orderly. K$\sub$w/ increased as volute fraction increased in all composite material. The composite materials reinforced by A1$_2$ $O_3$required the larger pressure in hot extrusion process than those by SiC$\sub$p/ at all condition. Extrusion process tended to decrease as the semi-angle of extrusion dies increased because larger contact area caused larger shear friction. Extrusion temperature went up about 50$^{\circ}C$ in low elevated deformation temperature. In extrusion temperature above 500$^{\circ}C$, severe tearing occurred on extrusion surface. More reinforcement in volume fraction, more hot tearing.

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A Study of the Effects of Na Ion on Codeposition of Particles in the Formation of Electroless Ni Composite Coatings (무전해 Ni 복합도금에서 분말의 공석에 미치는 Na 이온의 영향)

  • 이원해;이승평
    • Journal of Surface Science and Engineering
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    • v.22 no.2
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    • pp.101-108
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    • 1989
  • Effects of Na+ ion on zeta potential of SiC and Al2O3 particles suspended in nikel sufate and nickel chloride solutions were investigated. various complexing agents for Ni2+ ion were added to electroless Ni composite bath and the effects of the complexing agents on zeta potential and codeposition of the particles from the baths were studied. It was confirmed that Na+ ion was absorbed on the particles bringing about the positive surface charge and thus they promoted the entrapment of the particles into the nickel deposit. On the basis of these results it was possible to deposit SiCc particle in nickel chloride electrolyte containing complex agent such as trisodium citrate+sodium succinate.

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Sintering and Characterization of SiC-matrix Composite Including TRISO Particles (TRISO 입자를 포함하는 SiC 복합소결체의 소결 및 특성 평가)

  • Lee, Hyeon-Geun;Kim, Daejong;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.418-423
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    • 2014
  • Fully ceramic micro encapsulated (FCM) nuclear fuel is a concept recently proposed for enhancing the stability of nuclear fuel. FCM nuclear fuel consists of tristructural-isotropic (TRISO) fuel particles within a SiC matrix. Each TRISO fuel particle is composed of a $UO_2$ kernel and a PyC/SiC/PyC tri-layer which protects the kernel. The SiC ceramic matrix is created by sintering. In this FCM fuel concept, fission products are protected twice, by the TRISO coating layer and by the SiC ceramic. The SiC ceramic has proven attractive for fuel applications owing to its low neutron-absorption cross-section, excellent irradiation resistivity, and high thermal conductivity. In this study, a SiC-matrix composite containing TRISO particles was sintered by hot pressing with $Al_2O_3-Y_2O_3$ additive system. Various sintering conditions were investigated to obtain a relative density greater than 95%. The internal distribution of TRISO particles within the SiC-matrix composite was observed using an x-ray radiograph. The fracture of the TRISO particles was investigated by means of analysis of the cross-section of the SiC-matrix composite.

Modeling of Size-Dependent Strengthening in Particle-Reinforced Aluminum Composites with Strain Gradient Plasticity (변형률 구배 소성을 고려한 입자 강화 알루미늄 복합재의 크기 종속 강화 모델링)

  • Suh, Yeong-Sung;Park, Moon-Shik;Song, Seung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.7
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    • pp.745-751
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    • 2011
  • This study proposes finite element modeling of dislocation punching at cooling after consolidation in order to calculate the strength of particle-reinforced aluminum composites. The Taylor dislocation model combined with strain gradient plasticity around the reinforced particle is adopted to take into account the size-dependency of different volume fractions of the particle. The strain gradients were obtained from the equivalent plastic strain calculated during the cooling of the spherical unit cell, when the dislocation punching due to CTE (Coefficient of Thermal Expansion) mismatch is activated. The enhanced yield stress was observed by including the strain gradients, in an average sense, over the punched zone. The tensile strength of the SiCp/Al 356-T6 composite was predicted through the finite element analysis of an axisymmetric unit cell for various sizes and volume fractions of the particle. The predicted strengths were found to be in good agreement with the experimental data. Further, the particle-size dependency was clearly established.

세라믹막의 $CO_2$ 분리계수

  • 현상훈;강범석;조상연
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.04a
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    • pp.57-57
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    • 1994
  • 졸-겔 침지코팅 (dipcoating) 또는 가압 졸-겔 코팅 (pressurized coating) 법으로 제조한 $\gamma-Al_2O_3, SiO_2, TiO_2$ 및 aluminosilicate 복합막에 대하여 $CO_2$, He, $N_2$, 및 $O_2$ 기체 투과율과 $CO_2$ 분리계수를 측정하였다. 이들 막을 통한 모든 기체의 이동은 Knudsen 유동이 지배적이었으며 $CO_2/N_2$의 분리계수는 0.9 ~ 1.1 정도로 Knudsen 분리계수 ($CO_2/N_2$의 경우 0.8)보다 약간 높은 값을 보여주었다. $CO_2$ 분리계수를 향상시키기 위하여 silane coupling 및 산화물 도핑법에 의한 복합막의 표면개질을 시도하였으며 분리막의 재질 및 표면개질 조건에 따른 $CO_2/N_2$ 분리계수 변화를 측정 비교하였다. Silane coupling에 의한 표면개질이 $CO_2$의 표면 친화성 (affinity)에 의한 표면확산속도를 증가시키기 때문에 $CO_2$ 분리에 있어서 산화물 도핑에 의한 표면개질보다 더욱 효과적이었다.

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