• Title/Summary/Keyword: Si(III)-H

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A Study on the Physical Characteristics of III-V Compound Boron Phosphide using CVD (CVD를 이용해 증착한 III-V 화합물 보론 포스파이드의 물성분석에 관한 연구)

  • Hong, Kuen-Kee;Kim, Chul-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.332-335
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    • 2004
  • Boron Phosphide films were deposited on(III) Si substrate at $650^{\circ}C$, by the reaction of $B_2H_6$ with $PH_3$ using CVD. $N_2$ was employed as carrier gas. The optimal gas rates were 20 ml/min for $B_2H_6$, 60 ml/min for $PH_3$ ml/min and $1{\ell}/min$ for $N_2$. The films were annealed for 1hour in $N_2$ ambient at $550^{\circ}C$ and measured. The measurement of AFM shows that the average surface roughness is each $10.108{\AA}$ and $29.626{\AA}$. So, we could know every commonplace thing. The measurement of XRD shows that the films have the preferred orientation of(1 0 1). From SEM images, we could see that Boron Phosphide is showed of a structure, which is grain size, which is grain boundary size. Also, the measurement of AES is shown the films have $B_{13}P_2$ Stoichiometry. From WDX See that ingredient is detected each Boron and Phosporus. So, we could see that deposited BP thin film. In this study, we obtained the BP thin film by deposited in atmosphere pressure, and known to applicate as microwave absorbtion material of BP thin film.

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A Study of Galactic Molecular Clouds through Multiwavelength Observations

  • Park, Sung-Joon;Min, Kyoung-Wook;Seon, Kwang-Il;Han, Won-Yong;Lee, Dae-Hee;Edelstein, Jerry;Korpela, Eric;Sankrit, Ravi
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.68.1-68.1
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    • 2010
  • We focus on two Galactic molecular clouds that are located in wholly different environments and both are observed by FIMS instrument onboard STSAT-1. The Draco cloud is known as a translucent molecular cloud at high Galactic latitude. The FUV spectra show important ionic lines of C IV, Si IV+O IV], Si II* and Al II, indicating the existence of hot and warm interstellar gases in the region. The enhanced C IV emission inside the Draco cloud region is attributable to the turbulent mixing of the interacting cold and warm/hot media, which is supported by the detection of the O III] emission line and the $H{\alpha}$ feature in this region. The Si II* emission covers the remainder of the region outside the Draco cloud, in agreement with previous observations of Galactic halos. Additionally, the H2 fluorescent map is consistent with the morphology of the atomic neutral hydrogen and dust emission of the Draco cloud. In the Aquila Rift region near Galactic plane, FIMS observed that the FUV continuum emission from the core of the Aquila Rift suffers heavy dust extinction. The entire field is divided into three sub-regions that are known as the- "halo," "diffuse," and "star-forming" regions. The "diffuse" and "star-forming" regions show various prominent H2 fluorescent emission lines, while the "halo" region indicates the general ubiquitous characteristics of H2. The CLOUD model and the FUV line ratio are included here to investigate the physical conditions of each sub-region. Finally, the development of an infrared imaging system known as the MIRIS instrument onboard STSAT-3 is briefly introduced. It can be used in WIM studies through $Pa{\alpha}$ observations.

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STREAMING CIRCUMNUCLEAR GAS OF THE SEYFERT 2 GALAXY NGC 5728

  • Son, Dong-Hoon;Hyung, Siek;Lee, Seong-Jae;Ferruit, Pierre
    • Journal of The Korean Astronomical Society
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    • v.42 no.5
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    • pp.125-134
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    • 2009
  • We investigated the circumnuclear region of the Seyfert 2 galaxy NGC 5728, using the CFHT 3.6 m OASIS $[S_{II}]$, $[O_{III}]$ & $H\beta$ spectral images complemented with the IUE spectra. The physical condition of the circumnuclear zone has been derived: the gas density (indicated by $[S_{II}]$6716/31 ratio) around the C core is generally similar to that around the NW core, i.e., $\sim500cm^{-3}$. However, there appears to be evidence of a higher density shell in front of the NW core, $\sim10^4cm^{-3}$ at -250 km $s^-1$. The IUE $Si_{III}$]1892/$C_{III}$]1909 ratio implies a possible presence of a broad emission region of gas densities of $\sim10^{10}cm^{-3}$. The SE cone and surrounding area show several prominent features, while the NW cone does not show any particular structure: we identified three prominent blobs in the SE cone and one possible candidate in the NW cone. The outflow activities exist within the relatively large conic opening angle. We discussed the possibility of inflow or outflow activities of blobs found in the circumnuclear region of NGC 5728. The gas around two cores, two cones, and several blobs, is likely to be excited by the AGN hot source(s).

The Treatment of LNAPL(BETXlMTBE) Contaminated Groundwater Applying Photo-assisted Fenton Reaction with Various Fe(III) Chelator (Photo-assisted Fenton 반응에 다양한 Fe(III) chelator를 적용한 LNAPL(BTEX/MTBE)오염 지하수 처리에 관한 연구)

  • Park, Jong-Hun;Do, Si-Hyun;Lee, Hong-Kyun;Jo, Young-Hoon;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.14 no.2
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    • pp.26-32
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    • 2009
  • In this study, the degradation of BTEX (benzene, toluene, ethylbenzene, xylene) was tested in both (Fe$^{3+}$+chelating agent)/H$_2$O$_2$system [Fe(III) 1 mM, oxalate 6 mM, H$_2$O$_2$ 3%, and pH 6] and UV/(Fe3++ chelating agent)lHzOz system [UV dose 17.4 kWhlL, Fe(III) 1mM, oxalate 6 mM,H$_2$O$_2$ 1%, and pH 6]. The types of chelating agents used in experiments were catechol, NTA, gallic, acetyl acetone, succinic, acetate, EDTA, citrate, malonate, and oxalate and the optimum chelating agent for BTEX degradation was determined. The results showed that acetate was the optimum chelating agent for BTEX degradation in both (Fe$^{3+}$+chelating agent)/H$_2$O$_2$ and UV/(Fe$^{3+}$+chelating agent)/H$_2$O$_2$ system, and UV radiation enhanced the degradation of BTEX with any types of chelating agents. Moreover, UV/(Fe$^{3+}$+chelating agent)/H$_2$O$_2$ system, which chelating agent was acetate, removed effectively mixtures of BTEX and MTBE (methyl tert-butyl ether) when the concentration of both BTEX and MTBE was 200 mg/L, respectively. In this system, BTEX was degraded completely and 85% of MTBE was degraded at the reaction time of 180 min. Therefore, UV/((Fe$^{3+}$+chelating agent)/H$_2$O$_2$ system with acetate as a chelating agent removed not only BTEX but also BTEX and MTBE, effectively.

STUDY OF M82 USING SPECTRA FROM THE INFRARED SPACE OBSERVATORY

  • SOHN JUNGJOO;ANN H. B.;PAK SOOJONG;LEE H. M.
    • Journal of The Korean Astronomical Society
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    • v.34 no.1
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    • pp.17-24
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    • 2001
  • We have studied the central parts of M82, which is a well-known infrared luminous, starburst galaxy, by analyzing archival data from the Infrared Space Observatory (ISO). M82 was observed at 11 positions covering $\pm$45" from the center along the major axis. We analyzed 4 emission lines, [ArIII] 8.99 ${\mu}m$, $H_2$ 17.034 ${\mu}m$, [FeII] 25,98 ${\mu}m$, and [SiII] 34,815 ${\mu}m$ from $SWSO_2$ data. The integrated flux distributions of these lines are quite different. The $H_2$ line shows symmetric twin peaks at $\~$18" from the center, which is a general characteristic of molecular lines in starburst or barred galaxies. This line appears to be associated with the rotating molecular ring at around $\~$200 pc just outside the inner spiral arm. The relative depletion of the $H_2$ line at the center may be due to the active star formation activity which dissociates the $H_2$ molecules. The other lines have peaks at the center and the distributions are nearly symmetric. The line profiles are deconvolved assuming that both intrinsic and instrumental profiles are Gaussian. The velocity dispersion outside the core is found to be $\~50 km s^{-1}$. The central velocity dispersion is much higher than $50 km s^{-1}$, and different lines give different values. The large central velocity dispersion ($\sigma$) is mostly due to the rotation, but there is also evidence for a high $\sigma$ for [ArIII] line. We also generated position-velocity maps for these four lines. We found very diverse features from these maps.

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Solid Phases in Polyphase Inclusions from North Ore Deposits, Dunjeon Gold Mine (둔전금광산 북광상에서 산출되는 다상포유물내의 고상)

  • Park, Hee-In;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.24 no.1
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    • pp.1-8
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    • 1991
  • North ore deposits of the Dunjeon gold mine is disseminated-stockworks deposits emplaced in Ordovician Dongjeom quartzite. Six types of fluid inclusions are recongnized in the stage I quartz. Among them polyphase inclusions(type-IV-A, B) are predominent in the lower part of stage I quartz crystals whereas liquid and gas inclusions(type I, II) are abundant in the upper part of the same quartz crystals. Liquid $CO_2$-bearing inclusions(type III-A, B)occur as pseudosecondary inclusions. Solid phases in polyphase inclusions are identified by using scanning electron microscopy combined with energy dispersive x-ray spectroscopy. The solid phases are as follows; halite, sylvite, hydrophyllite, quartz, muscovite, calcite, ankerite, K-Mg-Fe-Al-Si mineral, Ca-Fe-Si mineral, Mg-Al-Si mineral, two kinds of Fe-mineral and Cu-Fe mineral. Results of freezing and heating experiments of fluid inclusions and identification of daughter minerals in polyphase inclusions in the stage I quartz reveal that ore fluids were high saline system NaCl-KCl-$CaCl_2$-$H_2O$ in the earier stage and then evolved to rather simple system NaCl-$H_2O$ in the later stage, and temporally fluid mixing occured with system $CO_2$-$H_2O$. Homogenization temperatures and salinity of fluid inclusions in the stage I range from 290 to $454^{\circ}C$ and from 0.2 to 54.2 wt. % equivalent to NaCl.

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DEVELOPMENT OF AN ASTRONOMICAL INFRARED PtSi CAMERA (천문관측용 PtSi 전하결합소자 적외선 카메라의 개발)

  • Hong, Seung-Su;;Gu, Bon-Cheol;Kim, Kwang-Tae;Kim, Chil-Yeong;Oh, Gap-Su;Lee, Myeong-Gyun;Lee, Hyeong-Mok;Kang, Yong-Woo;Park, Won-Gi
    • Publications of The Korean Astronomical Society
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    • v.11 no.1
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    • pp.1-26
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    • 1996
  • We have built a near-infrared imaging camera with a PtSi array detector manufactured by the Mitsubishi Company. The PtSi detector is sensitive in the wavelength range 1 to $5{\mu}m$. Quantum efficiency of PtSi is much lower than that of InSb and HgCdTe types. However, the PtSi array has advantages over the latter ones: (i)The read-out noise is very low; (ii)the characteristics of the array elements arc uniform and stable; (iii)it is not difficult to make a large PtSi array; and (iv) consequently the price is affordably low. The array used consists of $512{\times}512$ pixels and its size is $10.2\;mm{\times}13.3\;mm$. The filter wheel of the camera is equipped with J, H, K filters, and an aluminum plate for measuring the dark noise. The dewar is cooled with liquid nitrogen. We have adopted a method of installing the clock pattern and the observing softwares in the RAM, which Gill he easily used for other systems. We have developed a software with a pull-down menu for operating the camera and data acquisition. The camera has been tested by observing $\delta$ Orionis.

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Characteristics of Sialon ceramics by Kinds of Additive $Al_2O_3\;and\;Y_2O_3$ (소결보조재 $Al_2O_3$$Y_2O_3$종류에 따른 사이알론 세라믹스의 특성)

  • Park, S.W.;Moon, S.J.;Ahn, S.H.;Kim, J.S.;Nam, K.W.
    • Journal of Power System Engineering
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    • v.12 no.3
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    • pp.50-54
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    • 2008
  • Various Sialon ceramics were fabricated by hot-pressing mixtures of $Si_3N_4$ with additive $Y_2O_3$ and $Al_2O_3$. The polished specimen of SiAlON $I{\sim}III$ went on increasing in strength by heat treatment, heat treated non-polished specimen were similar or up to polished specimen in strength. The polished specimen of both SiAlON IV and V showed a very high strength, but were not Increasing of strength by heat treatment. All specimens were fractured on the surface and at the inner flaws. Surface fractures were initiated from the polished surface flaw and corner flaw. Inner fractures were initiated from an internal defect.

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Highly-conformal Ru Thin Films by Atomic Layer Deposition Using Novel Zero-valent Ru Metallorganic Precursors and $O_2$ for Nano-scale Devices

  • Kim, Su-Hyeon
    • Electrical & Electronic Materials
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    • v.28 no.2
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    • pp.25-33
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    • 2015
  • Ruthenium (Ru) thin films were grown on thermally-grown $SiO_2$ substrates by atomic layer deposition (ALD) using a sequential supply of four kinds of novel zero-valent Ru precursors, isopropyl-methylbenzene-cyclohexadiene Ru(0) (IMBCHDRu, $C_{16}H_{22}Ru$), ethylbenzen-cyclohexadiene Ru(0) (EBCHDRu, $C_{14}H_{18}Ru$), ethylbenzen-ethyl-cyclohexadiene Ru(0) (EBECHDRu, $C_{16}H_{22}Ru$), and (ethylbenzene)(1,3-butadiene)Ru(0) (EBBDRu, $C_{12}H_{16}Ru$) and molecular oxygen (O2) as a reactant at substrate temperatures ranging from 140 to $350^{\circ}C$. It was shown that little incubation cycles were observed for ALD-Ru processes using these new novel zero-valent Ru precursors, indicating of the improved nucleation as compared to the use of typical higher-valent Ru precursors such as cyclopentadienyl-based Ru (II) or ${\beta}$-diketonate Ru (III) metallorganic precursors. It was also shown that Ru nuclei were formed after very short cycles (only 3 ALD cycles) and the maximum nuclei densities were almost 2 order of magnitude higher than that obtained using higher-valent Ru precursors. The step coverage of ALD-Ru was excellent, around 100% at on a hole-type contact with an ultra-high aspect ratio (~32) and ultra-small trench with an aspect ratio of ~ 4.5 (top-opening diameter: ~ 25 nm). The developed ALD-Ru film was successfully used as a seed layer for Cu electroplating.

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온천수가 반죽의 발효와 품질에 미치는 영향

  • 이예경;김순동;이명예;김미영
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.121.1-121
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    • 2003
  • 증류수, 수도수, 온천수(경산 사이판 온천) 희석액 (55배 희석; I, 4배 희석; II, 2배희석; III을 사용한 반죽의 발효와 빵의 품질에 미치는 영향을 조사하였다. 경산사이판 온천수는 총고형물이 8,765 ppm 이였으며 주요 무기질로는 Na가 2296 ppm, Ca가 287 ppm, Mg와 K가 각각 65 및 8 ppm을 함유하였다. Fe, Cu, Co, F. Zn Al, S, Mo, Se 및 Si 등이 0.002~5.2 ppm을 함유하였다. 온천수를 사용한 반죽의 pH는 6.95~7.68로 증류수의 6.40보다 높았다. 반죽부피는 온천수의 농도가 높아짐에 따라 감소하였다. pH를 5.5로 조정한 온천수를 사용한 반죽의 부피는 대조구 보다 오히려 높았다. 온천수를 사용한 빵의 경도 (hardness)와 신장성(strength)는 대조구 보다 높았으나 pH를 조정한 온천수의 경우는 낮았다. 점착성은 경도 및 신장성과는 역으로 희석 온천수에서 낮았다. pH 조정 없이 구운 빵의 부드러운 정도는 4배로 희석한 온천수가 증류수 및 55배, 2배 희석 온천수보다 높았다. 쫄깃한 맛도 온천수가 대조구에 비하여 높았으며 종합적인 기호도는 4배 희석 온천수가 가장 좋았다.

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