• Title/Summary/Keyword: Shrinkage suppression

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Suppression of Shrinkage Mismatch in Hetero-Laminates Between Different Functional LTCC Materials

  • Seung Kyu Jeon;Zeehoon Park;Hyo-Soon Shin;Dong-Hun Yeo;Sahn Nahm
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.151-157
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    • 2023
  • Integrating dielectric materials into LTCC is a convenient method to increase the integration density in electronic circuits. To enable co-firing of the high-k and low-k dielectric LTCC materials in a multi-material hetero-laminate, the shrinkage characteristics of both materials should be similar. Moreover, thermal expansion mismatch between materials during co-firing should be minimized. The alternating stacking of an LTCC with silica filler and that with calcium-zirconate filler was observed to examine the use of the same glass in different LTCCs to minimize the difference in shrinkage and thermal expansion coefficient. For the LTCC of silica filler with a low dielectric constant and that of calcium zirconate filler with a high dielectric constant, the amount of shrinkage was examined through a thermomechanical analysis, and the predicted appropriate fraction of each filler was applied to green sheets by tape casting. The green sheets of different fillers were alternatingly laminated to the thickness of 500 ㎛. As a result of examining the junction, it was observed through SEM that a complete bonding was achieved by constrained sintering in the structure of 'calcium zirconate 50 vol%-silica 30 vol%-calcium zirconate 50 vol%'.

Properties of CLC using Silica to Suppress Cracking due to Drying Shrinkage (건조수축에 따른 균열 억제를 위한 규사 혼입 CLC의 특성)

  • Lee, Chang-Woo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.125-126
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    • 2021
  • In order to improve the housing culture, construction changes for the utilization of diverse and multifunctional spaces are appearing in response to the increasing diverse needs of consumers. Cellular Light-weight Concrete (CLC) is being developed for use in fire-resistant heat-insulating walls and non-bearing walls. However, manufacturing non-uniformity has become a problem as a drawback due to the use of foamed bubbles and normal temperature curing, and additional research is required. Therefore, in order to suppress cracks due to drying shrinkage, silica sand is mixed with CLC to try to understand its characteristics. In the experiment, the compressive strength from 7 to 28 days of age was measured via a constant temperature and humidity chamber, and the drying shrinkage was analyzed according to each condition using a strain gauge. The compressive strength of matrix tends to decrease as the substitution rate of silica sand increases. This is judged by the result derived from the fact that the specific surface area of silica sand is smaller than that of slag. Based on KS F 2701 (ALC block), the compressive strength of 0.6 products is 4.9 MPa or more as a guide, so the maximum replacement rate of silica sand that satisfies this can be seen at 60%. Looking at the change in drying shrinkage for just 7 days, the shrinkage due to temperature change and drying is 0.7 mm, and the possibility of cracking due to shrinkage can be seen, and it seems that continuous improvement and supplementation are needed in the future.

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Influence of Bismuth and Antimony Additions on the Structures and Casting Properties of Lead-free Cu-Zn-Sn Bronze Castings (무연 Cu-Zn-Sn 청동의 조직과 주조성에 미치는 Bi 및 Sb 첨가의 영향)

  • Park, Heung-Il;Park, Sung-Ik;Kim, Sung-Gyu
    • Journal of Korea Foundry Society
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    • v.32 no.2
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    • pp.91-97
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    • 2012
  • The effects of Bi and Sb additions on the microstructures and casting properties in lead-free Cu-Zn-Sn broze were investigated. (1) When only Bi was added to the bronze, Bi was precipitated on the ${\delta}$ phase of ${\alpha}$ dendrite cell boundary. When Bi and Sb were added together, Bi was precipitated on the ${\delta}_A$ which was the Sb-rich area in the ${\delta}$ phase. (2) The addition of Sb accelerated the formation of ${\delta}$ phase, and when Sb, Bi and Pb were added, Bi and Pb were precipitated as mixed solution in the ${\delta}_A$ phase. (3) The combined addition of Sb and Bi resulted in the suppression of shrinkage due to the complementary effects of the mass feeding of ${\alpha}$-dendrite cluster covered with ${\delta}$ phase and sealing of micro-shrinkage in the ${\delta}$ phase by solidification expansion of Bi.

Study on the Fire Suppression by Heat Transfer of Thermal Insulation Materials (건축물 외단열재의 열전달평가를 통한 화재 억제 방안 연구)

  • Ryu, Hwa Sung;Shin, Sang Hun;Song, sung young;Kim, Deuck Mo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.277-278
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    • 2018
  • Improvement of insulation performance of buildings is a major part. Adiabatic method The adiabatic method minimizes the heat loss of the building. External insulation uses insulation to prevent fire. Ambient air hazards are less prone to fire. When a fire occurs, a phenolic pattern is formed and bond strength with the wall increases. EPS insulation and phenol foam were used to compare external heat transfer and external heat transfer. The heat transfer properties of phenolic foam and styrofoam were evaluated as follows. In the mortar and styrofoam structure, the problem of styrofoam reaching the burning point occurred before the collapse of the mortar, and the phenol foam had a problem in that when the direct fire was continued on the phenol foam. The characteristics of continuous infiltration appeared. In the case of mortar and phenol foam + styrofoam, the heat penetrated into the interior due to the shrinkage due to the shrinkage of the carbon screen on the phenol foam. However, when reinforced with glass mesh on the outer surface, And to reduce infiltration.

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Developement of the reinforced acrylic-based hybrid denture composite resin with vinyloligosilsesquioxane (POSS)

  • Nam, Kwang-Woo;Chang, Myung-Woo;Chang, Bok-Sook;Han, Dong-Hoo;Shim, June-Sung;Chang, Ik-Tae;Heo, Seong-Joo;An, Jung-Ho;Chung, Dong-June
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.6
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    • pp.782-790
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    • 2000
  • The mainly used polymeric material for the denture is PMMA because of its cost and easiness to handle. So it was widely used material among dentists for past decades. But the acrylic-based denture materials have several common weak points such as shrinkage after curing and lack of strength. In order to solve these problems, we adapted one of hybrid system using acrylic polymer and vinyloligosilsesquioxane(POSS). POSS, which is a well known expandable monomer during polymerization process, may eventually suppress volumetric shrinkage. And the hybrid system makes it possible for the polymer to be stable in various severe conditions. Eight different kinds of samples were designed and synthesized. Each samples were characterized with dynamic mechanical analyser(DMA) to confirm their thermodynamic properties, fractured to analyze the cross-sectional morphology of the samples. And elongation, flexural and impact tests were also executed to evaluate the mechanical properties of the samples. From the results, hybrid composites had well defined crosslinked network structure compared to the widely used denture materials, and the mechanical strength improved without changing any surface condition as increment with POSS ratio in hybrid system. Fractured morphology showed homogeneous surfaces in spite of mutli component system, therefore we can conclude that the adoption of the POSS brought the reinforcement of the denture resin.

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Properties of Specialty Cellulose Fiber Reinforced Concrete at Early Ages (특수 가공된 셀룰로오스섬유보강 콘크리트의 초기 특성)

  • 원종필;박찬기
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.349-354
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    • 1999
  • Specialty cellulose fibers processed for the reinforcement of concrete offer relatively high levels of elastic modulus and bond strength. The hydrophilic surfaces of specialty cellulose fibers facilitate their dispersion and bonding in concrete. Specialty cellulose fibers have small effective diameters which are comparable to the cement particle size, and thus promote close packing and development of dense bulk and interface microstructure in the matrix. The relatively high surface area and the close spacing of specialty cellulose fibers when combined with their desirable mechanical characteristic make them quite effective in the suppression and stabilization of microcracks in the concrete matrix. The properties of fresh mixed specialty cellulose fiber reinforced concrete and the contribution of specialty cellulose fiber to the restrained shrinkage crack reduction potential of cement composites at early age and theirs evaluation are presented in this paper. Results indicated that specialty cellulose fiber reinforcement showed an ability to reduce the total area significantly (as compared to plain concrete and polypropylene fiber reinforced concrete.

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Mechanism of Action of Nigella sativa on Human Colon Cancer Cells: the Suppression of AP-1 and NF-κB Transcription Factors and the Induction of Cytoprotective Genes

  • Elkady, Ayman I;Hussein, Rania A;El-Assouli, Sufian M
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.17
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    • pp.7943-7957
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    • 2015
  • Background and Aims: Colorectal cancer is one of the leading causes of death in the world. The aim of this study was to investigate the growth-suppression potentiality of a crude saponin extract (CSENS) prepared from medicinal herb, Nigella sativa, on human colon cancer cells, HCT116. Materials and Methods: HCT116 cells were subjected to increasing doses of CSENS for 24, 48 and 72 h, and then harvested and assayed for cell viability by WST-1. Flow cytometry analyses, cell death detection ELISA, fluorescent stains (Hoechst 33342 and acridine orange/ethidium bromide), DNA laddering and comet assays were carried out to confirm the apoptogenic effects of CSENS. Luciferase reporter gene assays, quantitative reverse transcription-polymerase chain reaction and Western blot analyses were performed to assess the impact of CAERS and CFEZO on the expression levels of key regulatory proteins in HCT116 cells. Results: The results demonstrated that CSENS inhibited proliferation and induced apoptosis. Apoptosis was confirmed by flow cytometry analyses, while CSENS-treated cells exhibited morphological hallmarks of apoptosis including cell shrinkage, irregularity in cellular shape, cellular detachment and chromatin condensation. Biochemical signs of apoptosis, such as DNA degradation, were observed by comet assay and gel electrophoresis. The pro-apoptotic effect of CSENS was caspase-3-independent and associated with increase of the Bax/Bcl-2 ratio. CSENS treatment down-regulated transcriptional and DNA-binding activities of NF-${\kappa}B$ and AP-1 proteins, associated with down-regulation of their target oncogenes, c-Myc, cyclin D1 and survivin. On the other hand, CSENS up-regulated transcriptional and DNA-binding activities of Nrf2 and expression of cytoprotective genes. In addition, CSENS modulated the expression levels of ERK1/2 MAPK, p53 and p21. Conclusions: These findings suggest that CSENS may be a valuable agent for treatment of colon cancer.

Mechanism on Suppression of Alkali Silica Reaction by Ground Granulated Blast-Furnace Slag in NaCl Solution (NaCl 수용액 중에서 고로슬래그미분말의 알칼리실리카반응에 대한 팽창억제 메카니즘)

  • 김창길;삼포상;강원호
    • Magazine of the Korea Concrete Institute
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    • v.9 no.1
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    • pp.115-121
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    • 1997
  • This study deals with the suppressing characteristics of alkali-silica reaction by ground granulated blast-furnace slag(GGBS) in NaCl solution. NaCl contents used in the experiment ranges over 0%, 2.8% and 20%. Reactive aggregate used is Japanese andesite. Also, three GGBSs of about 4.000. 6, 000 and $8, 000cm^2/g$ were used in the experiment. The replacement proportions of portland cement by GGBSs were 40%. 60%, 70% and 80%. respectively. The specimens with GGBS were severely contracted according to the increasing replacement ratio in NaCl solution. The contraction rate increases according to the increasing in NaCl content. Also. it does with increasing the blaine fineness of GGRS. It is concluded that the suppression of alkali-silica reaction by GGBS in NaCl solution is complished by contraction of GGBS due to chloride ion induced chemical shrinkage.

Bandwidth Enhanced Miniaturization Method of Parallel Coupled-Line Filter (대역폭 특성이 개선된 평행 결합 선로 필터의 소형화 기법)

  • Myoung, Seong-Sik;Yook, Jong-Gwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.2 s.117
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    • pp.126-135
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    • 2007
  • This paper proposes a new miniaturization method for a parallel coupled line filter with enhanced bandwidth characteristics. A previous method incorporated several advantages, such as size reduction through the use of only a small number of capacitors, in addition to grounding, suppression of harmonic characteristics, and improved skirt characteristics for the parallel coupled line filter, which is conventional in the field of RE filters due to its design and fabrication simplicity. However, the previous method also has disadvantages related to the bandwidth shrinkage of the miniaturized filters. In this paper, the amount of bandwidth shrinkage is analyzed in terms of the relationship between the loaded Q(quality factor) and the group delay of a resonator. Moreover, the reduction in the bandwidth is solved by a design with new design equations. To show the validity of the proposed method, a hairpin filter with a center frequency of 5.2 GHz and an fractional bandwidth(FBW) of 10% was scaled down to half its original dimension by the proposed method with the enhanced bandwidth characteristics. The measured result shows a high level of agreement with theoretical results.

Experimental Study on Flame Extinction in Buoyancy-minimized Counterflow Diffusion Flame (부력의 영향을 최소화한 조건에서 대향류 확산화염의 화염 소화에 관한 실험적 연구)

  • Chung, Yong Ho;Park, Jin Wook;Park, Jeong;Kwon, Oh Boong;Yun, Jin-Han;Keel, Sang-In
    • Journal of the Korean Society of Combustion
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    • v.19 no.2
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    • pp.8-14
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    • 2014
  • Experiments were conducted to clarify role of the outermost edge flame on low-strain-rate flame extinction in buoyancy-suppressed non-premixed methane flames diluted with He and $N_2$. The use of He curtain flow produced a microgravity level of $10^{-2}-10^{-3}g$ in $N_2$- and He-diluted non-premixed counterflow flame experiments. The critical He and $N_2$ mole fractions at extinction with a global strain rate were examined at various burner diameters (10, 20, and 25 mm). The results showed that the extinction curves differed appreciably with burner diameter. Before the turning point along the extinction curve, low-strain-rate flames were extinguished via shrinkage of the outermost edge flame with and without self-excitation. High-strain-rate flames were extinguished via a flame hole while the outermost edge flame was stationary. These characteristics could be identified by the behavior of the outermost edge flame. The results also showed that the outermost edge flame was not influenced by radiative heat loss but by convective heat addition and conductive heat losses to the ambient He curtain flow. The numerical results were discussed in detail. The self-excitation before the extinction of a low-strain-rate flame was well described by a dependency of the Strouhal number on global strain rate and normalized nozzle exit velocity.