• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.33 no.3
• /
• pp.194-200
• /
• 2020

Perylene bisimide derivatives are developed for red organic phosphor because of their advantages, such as excellent luminous efficiency and high thermal stability. Despite these advantages, they have poor solubility characteristics in organic solvents and short emission wavelength as red organic phosphor for hybrid light-emitting diodes (LEDs). In this study, we prepared terrylene bisimide using a coupling reaction and swallow-tail imide group, which has excellent solubility. The structures and properties of swallow-tail terrylene bisimide (9C) were analyzed using ¹H-nuclear magnetic resonance (¹H-NMR), Fourier-transform infrared (FT-IR), UV/Vis spectroscopy, and thermal gravimetric analysis (TGA). The maximum absorption wavelength of (9C) in the UV/Vis spectrum was 647 nm, and the maximum emission wavelength was 676 nm. In the TGA, (9C) demonstrated good thermal stability with less than 5 wt% weight loss up to 415℃. In the solubility test, (9C) has a good solubility of more than 5 wt% in chloroform and dichloromethane. When the compounds (9C) were mixed with PMMA (polymethly methacrylate), the films showed peaks at 680 nm in the PL spectra. The results verify the suitability of (9C) as a red organic phosphor for hybrid LEDs.

• Current Optics and Photonics
• /
• v.5 no.2
• /
• pp.186-190
• /
• 2021

In this study, a compact, picosecond, mid-infrared 3.8 ㎛ MgO:PPLN optical parametric oscillator (OPO) laser output with high peak power is realized using a master oscillator power amplifier (MOPA) 1 ㎛ solid-state laser seeded by a picosecond fiber laser as the pump source. The pump source was a 50 MHz and 10 ps fiber seed source. After AOM pulse selection and two-stage solid-state amplification, a 1,064 nm laser output with a repetition frequency of 1-2 MHz, pulse width of 9.5 ps, and a maximum average power of 20 W was achieved. Furthermore, a compact short cavity with a unsynchronized pump is adopted through the design of an OPO cavity structure. When the injection pump power was 15 W and the repetition frequency was 1 MHz, the average output power of idler light was 1.19 W, and the corresponding peak power was 119 kW. The optical conversion efficiency was 7.93%. When the repetition frequency was increased to 2 MHz, the average output power of idler light was 1.63 W, the corresponding peak power was 81.5 kW, and the optical conversion efficiency was 10.87%. At the same time, the output wavelength was measured at 3,806 nm, and the beam quality was MX2 = 3.21 and MY2 = 3.34.

• Journal of the Korean earth science society
• /
• v.43 no.2
• /
• pp.312-323
• /
• 2022

This study began with the hypothesis of whether "solar radiation" and "terrestrial radiation" can be replaced by "visible radiation" and "infrared radiation", respectively. To this end, we investigated the perceptions of high school students who completed the Earth Science I course through a questionnaire to reveal how they perceived each concept. We also analyzed the descriptions and illustrations of textbooks that may have affected their perceptions. All of the students who participated in the questionnaire recognized solar radiation as radiation emitted only in the visible light region. About 35% of the students recognized convection, conduction, and latent heat as energy transfer by radiation in the Earth's heat budget. By analyzing six types of Earth Science I textbooks in the 2015 revised curriculum, we observed that two types introduced the terms "shortwave radiation" and "longwave radiation" but had no explanation for them, while the other two described solar radiation as "radiation mainly in the visible light region" or "radiation in short wavelengths". Regarding solar and terrestrial radiation in the last two types, there was no explanation for the wavelength regions, or ambiguous terms such as "short wavelength" and "long wavelength" were used. In addition, the two textbooks contained some errors in the illustration of the energy budget. Considering that textbooks described solar and terrestrial radiation without defining the exact terms for shortwave and longwave radiation, learners are likely to recognize solar and terrestrial radiation as visible and infrared radiation, respectively. This finding implies that vague statements or errors in textbooks can cause or reproduce students' misconceptions. The discussion in this study is expected to be used as a helpful reference material for teaching and learning processes regarding the Earth's radiation equilibrium and heat budget, and thereby contribute to proposing reasonable description plans for future textbook writing.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.11 no.5
• /
• pp.985-990
• /
• 2007

The method of enhancing visibility in optical fiber sensor was investigated by improving coherence length of light source. The optical feedback technique is used to enhance coherence length in fiber laser which generates laser in near infrared wavelength region and utilizes low loss characteristics of optical communication grade fiber. In this paper, the effect to coherence length by short and long optical feedback paths are investigated by using Mach-Zehnder interferometer technique. The effect to coherence length by changing optical feedback power and optical modulation are investigated. The spectral drift was calculated by measuring the degree of phase perturbation in unbalanced Mach-Zehnder interferometer having loom path difference. The short optical feedback path was effective to reduce spectral drift to 450kHz/sec and the long optical feedback path in combination with short optical feedback path was found to further reduce spectral drift to 50kHz/sec.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2012.05a
• /
• pp.68.1-68.1
• /
• 2012

The best part of graphene is - charge-carriers in it are mass less particles which move in near relativistic speeds. Comparing to other materials, electrons in graphene travel much faster - at speeds of $10^8cm/s$. A graphene sheet is pure enough to ensure that electrons can travel a fair distance before colliding. Electronic devices few nanometers long that would be able to transmit charge at breath taking speeds for a fraction of power compared to present day CMOS transistors. Many researches try to check a possibility to make it a perfect replacement for silicon based devices. Graphene has shown high potential to be used as interconnects in the field of high frequency electrical devices. With all those advantages of graphene, we demonstrate characteristics of electrical and optical properties of graphene such as the effect of graphene geometry on the microwave properties using the measurements of S-parameter in range of 500 MHz - 40 GHz at room temperature condition. We confirm that impedance and resistance decrease with increasing the number of graphene layer and w/L ratio. This result shows proper geometry of graphene to be used as high frequency interconnects. This study also presents the optical properties of graphene oxide (GO), which were deposited in different substrate, or influenced by oxygen plasma, were confirmed using different characterization techniques. 4-6 layers of the polycrystalline GO layers, which were confirmed by High resolution transmission electron microscopy (HRTEM) and electron diffraction analysis, were shown short range order of crystallization by the substrate as well as interlayer effect with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups on its layers. X-ray photoelectron Spectroscopy (XPS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation, and Fourier Transform Infrared spectroscopy (FTIR) and XPS analysis shows the changes in oxygen functional groups with nature of substrate. Moreover, the photoluminescent (PL) peak emission wavelength varies with substrate and the broad energy level distribution produces excitation dependent PL emission in a broad wavelength ranging from 400 to 650 nm. The structural and optical properties of oxygen plasma treated GO films for possible optoelectronic applications were also investigated using various characterization techniques. HRTEM and electron diffraction analysis confirmed that the oxygen plasma treatment results short range order crystallization in GO films with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups. In addition, Electron energy loss spectroscopy (EELS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation and XPS analysis shows that epoxy pairs convert to more stable C=O and O-C=O groups with oxygen plasma treatment. The broad energy level distribution resulting from the broad size distribution of the $sp^2$ clusters produces excitation dependent PL emission in a broad wavelength range from 400 to 650 nm. Our results suggest that substrate influenced, or oxygen treatment GO has higher potential for future optoelectronic devices by its various optical properties and visible PL emission.

• Journal of Astronomy and Space Sciences
• /
• v.33 no.3
• /
• pp.177-183
• /
• 2016

Active galactic nuclei (AGN) are too compact to be resolved by any existing optical telescope facility, making it difficult to understand their structure and the emission processes responsible for their huge energy output. However, variability, one of their characteristic properties, provides a tool to probe the inner regions of AGN. Blazars are the best candidates for such a study, and hence a considerable amount of effort is being made to investigate variability in these sources across the electromagnetic spectrum. Here, using the Mt. Abu infrared observatory (MIRO) blazar monitoring program, we present intra-night, inter-night, and long term aspects of the variability in S5 0716+71, 3C66A, and OJ 287. These stars show significant variability on short (a few tens of mins, to a few hours, to a few days) to long term (months to years) timescales. Based on the light travel time argument, the shortest variability timescales (micro-variability) provide upper limits to the size of the emission region. While S5 0716 shows a very high duty cycle of variability (> 80 %), 3C66A shows a much lower intra day variability (IDV) duty cycle (< 20 %). All three show rapid variations within 2.5 to 3.5 hr, which, perhaps, are generated near the vicinity of black holes. Assuming this, estimates of the masses of the black holes are made at ~10⁹, 8×10⁸, and 2.7×10⁹ M_⨀ for S5 0716+71, 3C66A, and OJ 287, respectively. Multi-wavelength light-curves for the blazar PKS 1510-089 are discussed to infer the emission processes responsible for the recent flaring episodes in this source.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.35 no.2
• /
• pp.165-171
• /
• 2022

The SiO₂/TiO₂ multilayer thin films used for narrow band pass filter were fabricated using E-beam evaporation method. The narrow band pass filter was used to enhance the resolution of spectroscopy and sensor applications with near infrared (NIR) light source. The narrow band pass filter with multilayer thin films were designed with Essential Macleod program. The multilayers of SiO₂/TiO₂ with 32 layers were deposited on the silicon encapsulation of IR with peak wavelength (λ_p) of 660 nm and NIR LEDs with λ_p of 830 nm, 880 nm, and 955 nm. After NIR light passed through the narrow band pass filter, the full width of half maximum of 33.4~48.6 nm became narrow to 20~24 nm owing to the absorption of photons with short or long wavelength of designed band of 20 nm. The SiO₂/TiO₂ band pass filter fabricated in this study can be used for sensor, optoelectronics, and NIR spectroscopy applications.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.19 no.4
• /
• pp.24-36
• /
• 2015

In the present study, numerical predictions of infrared spectrum of rocket plume with considering effect of particles based on approximation theories were performed by using a line-by-line radiation model with radiation databases. The high-resolution radiation databases were used to predict thermal emission spectra of gas molecules within the rocket plume regime. The particles were modeled as soot particles by using 1st term approximation of Mie theory and Rayleigh approximation. The reliability of modeled effect of soot particles using the two approximation theories was verified, and the spectral radiance of rocket plume was predicted based on the verification. The results were improved in the short wavelength range by considering the effect of soot particles.

• Proceedings of the KSRS Conference
• /
• 2002.10a
• /
• pp.734-738
• /
• 2002

We present spectral characteristics of tidal flat sediments and algal mat that were tested in the Gomso and Saemangum tidal flats, Korea. The objective of this study is to investigate the spectral reflectance and the radar scattering modeling in the tidal flats. Ground truth data obtained in the tidal flats include grain size, soil moisture content and its variation with time, surface roughness, chlorophyll, ground leveling, and field spectral reflectance measurement. The concept of an effective exposed area (EEA) is introduced to accommodate the effect of remnant surface water, and it seriously affects the reflection of short wavelength infrared and microwave. The nin size of 0.0625 mm has been normally used as a critical size of mud and sand discrimination. But we propose here that 0.25 mm is more practical grain size criterion to discriminate by remote sensing. Algal mat is the primary product in tidal flats, and it is found to be very important to understand spectral characteristics for tidal flat remote sensing. We have also conducted radar scattering modeling, and showed L-band HV-polarization would be the most effective combination.

• Korean Journal of Remote Sensing
• /
• v.3 no.1
• /
• pp.1-10
• /
• 1987

The study was performed to recognize the most preferable spectral chennels for discriminating geological materials using the portable radiometer. The portable radiometer covers the visible and short infrared regions from approximately 0.4 to 2.5 microns which are coincided with Landsat TM, and the rock samples used for the study are pyrophylites, andesites, granite, granodiorite and silicified sedimentary rocks which are collected in Yangsan-Dongrae fault area. The analysis of the rock sample provides a preliminary basis for determining the wavelength regions showing diagnostic spectral features and for discriminating hydrothermal altered rocks from the unaltered rocks. The measurement of spectral of spectral reflectance for the rock samples was carried out in the laboratory which environment condition such as temperature, light sources, and humidity are constant. The analysis of the measured data was based on correlation between the reflectance value of the rock samples, and the follow discriptions are output of the study. 1) Pyrophyllite shows absorption at 0.83 $\mu\textrm{m}$ due to the oxidation of pyrite, and absorption at 2.22 $\mu\textrm{m}$ due to OH. 2) The altered rocks have generally higher reflectance than the unaltered rocks. 3) The ratio mesurement of pyrophyllites shows strong absorption at band 5/6 and band 6/4(in Landsat TM 5/7, 7/4). The ratio 1/5(Landsat TM 1/5) may be useful to discriminate andesite from the granite.