• Ocean and Polar Research
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• v.25 no.4
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• pp.447-457
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• 2003

In order to understand the distribution of changes of geochemical characteristics in surface sediments according to various environmental changes around the artificial Lake Shihwa, surface sediments were sampled at $13{\sim}15$ sites form 1997 to 1999 and analyzed by C/S analyzer, ICP/MS and AAS. The average $S/C_{org}$ ratio was 0.35 in the surface sediments, which is similar to 0.36, the characteristic ratio of marine sediments. Heavy metal contents and enrichment factors in the surface sediments tended to be decreasing from the head to the mouth of the Lake Shihwa. With the deposition of fine-grained sediments in the central part of lake, anoxic water column induced the sulfides compounds with Cu, Cd and Zn. Metals such as Al, Fe, Cr, Co, Ni, Cu, Zn and Cd except for Mn and Pb showed relatively high correlation coefficients among them. The contents of Cr, Co, Ni, Cu, Zn and Cd in the surface sediments of the lake were two to five times higher than those in the lake before dike construction and also in outer part of the dike. These are mainly due to the Input of untreated industrial and municipal waste-waters into the lake, and the accumulation of heavy metals by limitation of physical mixing. Although metal contents of the surface sediments at the sites near the water-gate due to outer seawater inflow tended to be lower than those during the desalination, heavy metals were deposited in areas around the new industrial complex in the evidence of spatial distribution of heavy metals in the sediments. This is mainly due to the input of untreated waste-waters from tributaries.

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.1
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• pp.40-50
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• 2011

We study the characteristic and total flux of non-point pollutants such as total suspended solids (TSS), chemical oxygen demand (COD), dissolved nutrients, total phosphorus (TP) and total nitrogen (TN) in the storm water runoff from urban streams and sewer outlets of Banweol Industrial Complex around Shihwa Lake. The concentrations of non-point pollutants were generally increased with increasing of the duration and intensity of rainfall. Mean TSS concentration of Ansan stream was higher than that of sewer outlets but mean concentrations of COD, TP and TN were approximately 2~5 times higher of sewer outlet than of urban stream. TSS showed statistically positive relationships with COD and TP but it had negative correlation with dissolved nutrients. There was a significant correlation between total flux of non-point pollutants in the storm water runoff and total basin area of each sewer outlet, showing that the highest runoff flux was observed at 3rd sewer outlet which represents the largest basin area from Banweol industrial complex. Total runoff fluxes for TSS, COD, TP and TN in this study were 187,536 kg, 17,118 kg, 922 kg, 13,519 kg, respectively. Given the basin area of sewer outlet in Banweol industrial complex which corresponds only 3% from total catchment area around Shihwa Lake, enormous amount of non-point pollutants will be entered into Shihwa Lake without any treatment. It is necessary to manage and reduce of various non-point sources and pollutants because the runoff of nonpoint pollutants during storm events should be deteriorating the water quality of Shihwa Lake. Our results provides useful informations on the development of best managements practices (BMPs) for effective implementation of total pollution loads management system of Shihwa Lake.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.2 no.2
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• pp.49-52
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• 1997

The man-made lake, Shihwa, was constructed in January, 1994 as a part of the 'development project of the Shihwa area'. The lake area was a typical coastal ocean environment before the construction, but after constructing the dikes to block the sea water inflow, the lake is in the process of becoming a freshwater lake, and faces various ecological changes. Due to the polluted water inflow from the neighboring industrial complex and Ansan city, many negative effects appear. In this group study we conducted integrated ecosystem investigations of the lake Shihwa and the adjacent coastal area in order to find out how the ecosystem is controlled by artificial changes of the lake environment. The results are compiled in the following several articles of this issue: Park et ai. (1997), Han et al. (1997). Choi et ai. (1997), Park and Huh (1997), Ryu et at. (1997), Lee et al. (1997).

• Journal of Environmental Impact Assessment
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• v.29 no.1
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• pp.8-25
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• 2020

Industrialization has increased the production of road-deposited sediments (RDS) and the level of heavy metals in those RDS, which can have a significant impact on the surrounding aquatic environments through non-point pollution. Although the relationship between contamination characteristics and particle size of RDS is important for pollution control, there is very little information on this. In this study, we investigated the characteristics of grain size distribution and heavy metal concentrations in the road-deposited sediments (RDS) collected from 25 stations in Shihwa Industrial Complex. The environmental impact of RDS with particle size is also studied. I_geo, the contamination assessment index of each metal concentration, represents the RDS from Shihwa Industrial Complex are very highly polluted with Cu, Zn, Pb and Sb, and the levels of those metals were 633~3605, 130~1483, 120~1997, 5.5~50 mg/kg, respectively. The concentrations of heavy metals in RDS increased with the decrease in particle size. The particle size fraction below 250 ㎛ was very dominant with mass and contamination loads, 78.6 and 70.4%, respectively. Particles less than 125 ㎛ of RDS were highly contaminated and toxic to benthic organisms in rivers. RDS particles larger than 250 ㎛ and smaller than 250 ㎛ were contaminated by the surrounding industrial facility and vehicle activities, respectively. As a result of this study, the clean-up of fine particles of RDS, smaller than 125-250 ㎛, is very important for the control and reduction of non-point pollution to nearby water in Shihwa Industrial Complex.

• Ocean and Polar Research
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• v.35 no.2
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• pp.69-83
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• 2013

Metal concentrations in creek water, sewer outlets and core sediments were analyzed to identify the potential origin of metal pollution and to evaluate the extent of metal pollution and potential toxicity of Lake Shihwa. Mean concentrations for dissolved metals in creek water and sewer outlets were 1.6~136 times higher than those in the surface seawater of Lake Shihwa. Metal concentrations in creek water from an industrial region were also higher than those from municipal and agricultural regions, indicating that the potential source of metal pollution in the study area might be mainly due to industrial activities. The vertical profiles of metals in core sediments showed an increasing trend toward the upper sediments. Extremely higher concentrations of metals were observed in the vicinity of Banweol industrial complex. The results of a geo-accumulation index indicated that Cu, Zn and Cd were highly polluted. By comparing the sediment quality guidelines such as TEL and PEL, six metals such as Cr, Ni, Cu, Zn, Cd and Pb levels in core sediments nearby industrial complex exceeded the PEL value. Mean PEL quotient (mPELQ) was used to integrate the estimate of potential toxicity for measured metals in the present study. Mean PELQs in core sediments from Lake Shihwa ranged from 0.2~2.3, indicating that benthic organisms nearby the industrial complex may have been adversely affected.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.4
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• pp.289-299
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• 2011

We studied the characteristics of pollutant concentrations in 9 streams that flow into Shihwa Lake in order to provide the scientific data for effective implementation of total pollution loads management system (TPLMS) of the Lake. Suspended solid (SS), chemical oxygen demand (COD), dissolved nutrients ($NO_2$, $NO_3$, $NH_4$, $PO_4$ and $SiO_2$), total phosphorus (TP) and total nitrogen (TN) in stream water from industrial complexes, urban and agricultural regions were determined. Pollutant concentrations in December were higher than that in other sampling periods. COD concentration from industrial complex region with average of 12.6 mg/L was 2 times higher those from urban region (6.6 mg/L) and agricultural region (5.9 mg/L). TP concentration from industrial region also showed higher concentration than other regions. TN concentration in stream water was 5.89 mg/L for industrial region, 3.02 mg/L for urban region and 5.27 mg/L for agricultural region, respectively, suggesting inflow of TN due to fertilizer usage in agricultural field. Relative percentage of nitrogen compounds in TN follows the sequence: $NH_4$ (35.1%) > $NO_2$ (20.0%) > DON (22.8%) > PON (8.9%) > $NO_2$ (3.2%). Concentrations of dissolved nutrients, TP and TN in stream water were 3.2~37.2 times higher than that in Shihwa Lake seawater, therefore large amount of pollutants may be directly entered into Shihwa Lake without any treatment. For Gunja stream of industrial region, pollutants at midstream showed relatively higher concentration compared to upstream and downstream. It is necessary to manage the illegal discharging of sewage and waste water. Our results provide valuable informations on the estimation and reduction of total pollutant loads in the process of establishing adequately strategic and implemental plan of Shihwa Lake TPLMS.

• Journal of the korean society of oceanography
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• v.35 no.2
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• pp.89-97
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• 2000

The pyritization of heavy metals in Lake Shihwa sediments was investigated to determine sedimentary Pyrite-heavy metal associations influenced by various metal fractions, organic carbon, and total reduced sulfur. Parameters indicating the degree of heavy metal pyritization (DTMP) and degree of pyritization (DOP) were used to study the incorporation of heavy metals into the pyrite phase. The DOP levels ranged from 3.28-39.45%, showing wide differences among sampling stations. The levels were greater near the water gate and the center of the lake than near the industrial complex. The spatial pattern of the DOP levels was similar to the S/C ratio and also to the salinity. Based on the measured relationships between DOP and DTMP, heavy metals can be divided into three groups. In the first group was As, which showed a high affinity for pyrite. In the second group were Ni, Co and Cu, which showed a gradual increase in DTMP with increasing DOP. In the final group were Pb, Zn, Mn and Cr, which all showed a low DTMP with constant values with respect to DOP.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.11
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• pp.790-796
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• 2011

In this study, we measured the concentrations of volatile organic compounds (VOCs) in Shiwha area by using active and passive sampler. We did a comparative analysis of the characteristics of the active sampler and passive sampler. In the case of the passive sampler, the average TVOC concentration of the industrial area was 1.86 times higher than that of the residential area. In the case of the active sampler, the average TVOC concentration of the industrial area was 1.07 times higher than that of the residential area. When using the passive sampler, the concentration of VOCs in the industrial area was noted to be higher than the concentration found in the residential area. However, when we used the thermal desorption tube, the concentration of residential area was higher rather than that of industrial area in some substances such as trichloroethylene, toluene, ethylbenzene, and xylene. Toluene was a larger percentage of the overall BTEX ratio. In case of the passive sampler, the relative ratio of toluene, ethylbenzene, and xylene was higher in the industrial area than in the residential area. In contrast in case of the thermal desorption tube, the ratio of these substances was higher in the residential area rather than in the industrial area. The passive sampling in this study showed an appropriate method to analyze the temporal and spatial concentrations of air contaminants. This assessment would prove to be useful for its observance of standards or epidemical study.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.3
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• pp.332-343
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• 2007

The concentrations of major volatile organic compounds (VOCs) were measured using a passive sampler in the leather industries, Shihwa and Banwol industrial complex. The leather industries were classified into four groups in raw materials and main product. The concentrations of total VOCs measured in process for ${\ulcorner}$ manufacture of reconstituted leather and special treated leather${\lrcorner}$was highest. The main VOCs measured in the leather industries was found to be toluene with a average concentration of 1,200 ppb. The major group selected in the leather industries was divided into three groups by the fingerprint analysis and the principal component analysis. The major VOCs in the groups classified by fingerprint analysis were found to be dependent on the characteristics of raw materials and main products.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.18 no.3
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• pp.262-267
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• 2006

For the concentration management in COD parameters, it requires the measurement and estimation of the COD pollutants load (hereinafter PL) in the watershed. The estimation method of the PL, however, is provided only based on the BOD parameters. The development of COD PL estimation schemes is expected to execute total PL management in coastal zone and needs to more observation and much time. This study provides COD PL estimation schemes using statistical information about ratio analysis with COD & BOD concentration of rivers and drainages of an industrial complex in Lake Shiwha and Incheon Coastal Zone watershed. The COD PL is computed with ease by multiplying the conversion factor, which is calculated as the sum of the average and 1 to 3 (safety factors) times standard deviation. The conversion factor of Lake Shihwa and Incheon Coastal Zone is estimated as 1.7, 2.3 and 2.9 with respect to the safety factor 1, 2, and 3, respectively.