• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.399-405
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• 2018

We report the fabrication of organic field-effect transistors (OFETs) via spray coating of electrochemically exfoliated graphene (EEG) and conducting polymer hybrid as electrodes. To reduce the roughness and sheet resistance of the EEG electrodes, subsequent coating of conducting polymer (poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)) and acid treatment was performed. After that, active channel layer was developed by spin coating of semiconducting poly(3-hexylthiophene) on the hybrid electrodes to define the bottom gate bottom contact configuration. The OFET devices with the EEG/PEDOT:PSS hybrid electrodes showed a reasonable electrical performances (field effect mobility = $0.15cm^2V^{-1}\;s^{-1}$, on/off current ratio = $10^2$, and threshold voltage = -1.57V). Furthermore, the flexible OFET devices based on the Polydimethlsiloxane (PDMS) substrate and ion gel dielectric layer exhibited higher electrical performances (field effect mobility = $6.32cm^2V^{-1}\;s^{-1}$, on/off current ratio = $10^3$, and threshold voltage = -1.06V) and excellent electrical stability until 1000 cycles of bending test, which means that the hybrid electrode is applicable to various organic electronic devices, such as flexible OFETs, supercapacitors, organic sensors, and actuators.

• Computers and Concrete
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• v.29 no.4
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• pp.219-235
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• 2022

Strengthening slender reinforced concrete (RC) columns is a challenge. They are susceptible to overall buckling that induces bending moment and axial compression. This study presents the precise three-dimensional finite element modeling of slender RC columns strengthened with fiber-reinforced polymer (FRP) composites sheets with various patterns under concentric or eccentric compression. The slenderness ratio λ (height/width ratio) of the studied columns ranged from 15 to 35. First, to determine the optimal modeling procedure, nine alternative nonlinear finite element models were presented to simulate the experimental behavior of seven FRP-strengthened slender RC columns under eccentric compression. The models simulated concrete behavior under compression and tension, FRP laminate sheets with different fiber orientations, crack propagation, FRP-concrete interface, and eccentric compression. Then, the validated modeling procedure was applied to simulate 58 FRP-strengthened slender RC columns under compression with minor eccentricity to represent the inevitable geometric imperfections. The simulated columns showed two cross sections (square and rectangular), variable λ values (15, 22, and 35), and four strengthening patterns for FRP sheet layers (hoop H, longitudinal L, partial longitudinal L_w, and longitudinal coupled with hoop LH). For λ=15-22, pattern L showed the highest strengthening effectiveness, pattern L_w showed brittle failure, steel reinforcement bars exhibited compressive yielding, ties exhibited tensile yielding, and concrete failed under compression. For λ>22, pattern L_w outperformed pattern L in terms of the strengthening effectiveness relative to equivalent weight of FRP layers, steel reinforcement bars exhibited crossover tensile strain, and concrete failed under tension. Patterns H and LH (compared with pattern L) showed minor strengthening effectiveness.

• Journal of the Korean Society for Heat Treatment
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• v.37 no.1
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• pp.16-22
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• 2024

The conventional degreasing process involves removing oil and contaminants at temperatures above 80℃, resulting in excessive energy consumption, increased process costs, and environmental issues. In this study, we aimed to find the optimal degreasing conditions for the pre-treatment process of electro-galvanizing cold-rolled steel sheets, conducted efficiently at room temperature without the need for a separate heating device. To achieve this, we developed a room temperature degreasing solution and a brush-type degreasing tool, aiming to reduce energy consumption and normalize the decrease in degreasing efficiency caused by temperature reduction. Alkaline degreasing solution were prepared using KOH, SiO₂, NaOH, Na₂CO₃, and Sodium Lauryl Sulfate, with KOH and NaOH as the main components. To enhance the degreasing performance at room temperature, we manufactured additives including sodium oleate, sodium stearate, sodium palmitate, sodium lauryl sulfate, ammonium lauryl sulfate, silicone emulsion, and EDTA-Na. Room temperature additives were added to the alkaline degreasing solution in quantities ranging from 0.1 to 20 wt.%, and the uniformity of degreasing and the adhesion of the galvanized layer were evaluated through Dyne Test, T-bending Test, OM, SEM, and EDS analyses. The results indicated that the optimal degreasing solution composition consisted of NaOH (30 g/L), Na₂CO₃ (30 g/L), SLS (6 g/L), and room temperature additives (≤1 wt%).

• Computers and Concrete
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• v.33 no.1
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• pp.27-39
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• 2024

In this study, the authors investigate the free vibration behavior of three-phases functionally graded sandwich plates using a novel nth-order shear deformation theory. These plates are composed of a homogeneous core and two face-sheet layers made of different functionally graded materials. This is the novel type of the sandwich structures that can be applied in many fields of mechanical engineering and industrial. The proposed theory only requires four unknown displacement functions, and the transverse displacement does not need to be separated into bending and shear parts, simplifying the theory. One noteworthy feature of the proposed theory is its ability to capture the parabolic distribution of transverse shear strains and stresses throughout the plate's thickness while ensuring zero values on the two free surfaces. By eliminating the need for shear correction factors, the theory further enhances computational efficiency. Equations of motion are established using Hamilton's principle and solved via Navier's solution. The accuracy and efficiency of the proposed theory are verified by comparing results with available solutions. The authors then use the proposed theory to investigate the free vibration characteristics of three-phases functionally graded sandwich plates, considering the effects of parameters such as aspect ratio, side-to-thickness ratio, skin-core-skin thicknesses, and power-law indexes. Through careful analysis of the free vibration behavior of three-phases functionally graded sandwich plates, the work highlighted the significant roles played by individual material ingredients in influencing their frequencies.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2000.06a
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• pp.16-23
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• 2000

The increasing functional needs of top-quality printing papers and packaging paperboards, and especially the rapid developments in electronic printing processes and various computer printers during past few years, set new targets and requirements for modern paper quality. Most of these paper grades of today have relatively high filler content, are moderately or heavily calendered , and have many coating layers for the best appearance and performance. In practice, this means that many of the traditional quality assurance methods, mostly designed to measure papers made of pure. native pulp only, can not reliably (or at all) be used to analyze or rank the quality of modern papers. Hence, introduction of new measurement techniques is necessary to assure and further develop the paper quality today and in the future. Paper formation , i.e. small scale (millimeter scale) variation of basis weight, is the most important quality parameter of paper-making due to its influence on practically all the other quality properties of paper. The ideal paper would be completely uniform so that the basis weight of each small point (area) measured would be the same. In practice, of course, this is not possible because there always exists relatively large local variations in paper. However, these small scale basis weight variations are the major reason for many other quality problems, including calender blacking uneven coating result, uneven printing result, etc. The traditionally used visual inspection or optical measurement of the paper does not give us a reliable understanding of the material variations in the paper because in modern paper making process the optical behavior of paper is strongly affected by using e.g. fillers, dye or coating colors. Futhermore, the opacity (optical density) of the paper is changed at different process stages like wet pressing and calendering. The greatest advantage of using beta transmission method to measure paper formation is that it can be very reliably calibrated to measure true basis weight variation of all kinds of paper and board, independently on sample basis weight or paper grade. This gives us the possibility to measure, compare and judge papers made of different raw materials, different color, or even to measure heavily calendered, coated or printed papers. Scientific research of paper physics has shown that the orientation of the top layer (paper surface) fibers of the sheet paly the key role in paper curling and cockling , causing the typical practical problems (paper jam) with modern fax and copy machines, electronic printing , etc. On the other hand, the fiber orientation at the surface and middle layer of the sheet controls the bending stiffness of paperboard . Therefore, a reliable measurement of paper surface fiber orientation gives us a magnificent tool to investigate and predict paper curling and coclking tendency, and provides the necessary information to finetune, the manufacturing process for optimum quality. many papers, especially heavily calendered and coated grades, do resist liquid and gas penetration very much, bing beyond the measurement range of the traditional instruments or resulting invonveniently long measuring time per sample . The increased surface hardness and use of filler minerals and mechanical pulp make a reliable, nonleaking sample contact to the measurement head a challenge of its own. Paper surface coating causes, as expected, a layer which has completely different permeability characteristics compared to the other layer of the sheet. The latest developments in sensor technologies have made it possible to reliably measure gas flow in well controlled conditions, allowing us to investigate the gas penetration of open structures, such as cigarette paper, tissue or sack paper, and in the low permeability range analyze even fully greaseproof papers, silicon papers, heavily coated papers and boards or even detect defects in barrier coatings ! Even nitrogen or helium may be used as the gas, giving us completely new possibilities to rank the products or to find correlation to critical process or converting parameters. All the modern paper machines include many on-line measuring instruments which are used to give the necessary information for automatic process control systems. hence, the reliability of this information obtained from different sensors is vital for good optimizing and process stability. If any of these on-line sensors do not operate perfectly ass planned (having even small measurement error or malfunction ), the process control will set the machine to operate away from the optimum , resulting loss of profit or eventual problems in quality or runnability. To assure optimum operation of the paper machines, a novel quality assurance policy for the on-line measurements has been developed, including control procedures utilizing traceable, accredited standards for the best reliability and performance.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.3
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• pp.551-565
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• 2017

A spray-applied waterproofing membrane which consists of polymers has a relatively higher constructability and adhesion than the conventional sheet-type waterproofing materials. Additionally, the spray-applied waterproofing membrane generally shows a waterproofing ability as a composite structure with shotcrete or concrete lining. Because its purpose is waterproofing at the structure, structural effects were not well reported than waterproofing abilities. In this study, structural effects of the membrane-attached concrete lining were evaluated using 3-point bending test by the numerical method. From the analysis, a load-displacement behavior of the concrete lining and fracturing energy after yielding were compared with various conditions. Consequently, concrete lining with spray-applied waterproofing membrane shows higher flexural strength and fracturing energy than the single-layer concrete lining.

• Journal of the Microelectronics and Packaging Society
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• v.31 no.1
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• pp.29-34
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• 2024

The heating element utilizing the Joule heating generated when current flows through a conductor is widely researched and developed for various industrial applications such as moisture removal in automotive windshield, high-speed train windows, and solar panels. Recently, research utilizing heating elements with various nanostructures has been actively conducted to develop flexible heating elements capable of maintaining stable heating even under mechanical deformation conditions. In this study, flexible polyurethane possessing excellent flexibility was selected as the substrate, and silver (Ag) thin films with low electrical resistivity (1.6 μΩ-cm) were fabricated as the heating layer using magnetron sputtering. The 2D heating structure of the Ag thin films demonstrated excellent heating reproducibility, reaching 95% of the target temperature within 20 seconds. Furthermore, excellent heating characteristics were maintained even under mechanically deforming environments, exhibiting outstanding flexibility with less than a 3% increase in electrical resistance observed in repetitive bending tests (10,000 cycles, based on a curvature radius of 5 mm). This demonstrates that polyurethane/Ag planar heating structure bears promising potential as a flexible/wearable heating element for curved-shaped appliances and objects subjected to diverse stresses such as human body parts.