• 제목/요약/키워드: Shear-Thinning Behavior

검색결과 120건 처리시간 0.026초

시판된장의 리올로지(Rheology) 특성에 관한 연구 (Flow Properties of Doenjang)

  • 양신철;김선화
    • 한국관광식음료학회지:관광식음료경영연구
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    • 제13권1호
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    • pp.55-68
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    • 2002
  • Flow properties of doenjang samples at various total solid contents (30, 32, 34, 36, 38, 40%) were evaluated in this study. Flow properties of doenjang samples was determined by using Haake concentric cylinderical viscometer and Instron testing machine with capillary extrusion viscometer, and consistency index(K), and flow behavior index(n) was also determined from power models, and yield stress was derived form Casson models and vanes methods. Doenjang samples showed shear-thinning (pseudoplastic) fluid with small magnitude of flow behavior index(n) (n=0.30-0.55). Casson yield stress was from 2.11 to 64.02(Pa). Vane yield stress was more effective than casson yield stress in property of reactivation. Apparent viscosity was decreased with the increase in temperature and activation energy was in the range of 6.58 to 10.70 kJ/mole. From the capillary extrusion method, K and n was increased with the increase in solid content with good correlation with. The result revealed that capillary extrusion method is useful for measuring the flow properties of doenjang.

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Transient filling simulations in unidirectional fibrous porous media

  • Liu, Hai Long;Hwang, Wook-Ryol
    • Korea-Australia Rheology Journal
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    • 제21권1호
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    • pp.71-79
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    • 2009
  • The incomplete saturation and the void formation during the resin infiltration into fibrous porous media in the resin transfer molding process cause failure in the final product during its service. In order to better understand flow behavior during the filling process, a finite-element scheme for transient flow simulation across the micro-structured fibrous media is developed in the present work. A volume-of- fluid (VOF) method has been incorporated in the Eulerian frame to capture the evolution of flow front and the vertical periodic boundary condition has been combined to avoid unwanted wall effect. In the microscale simulation, we investigated the transient filling process in various fiber structures and discussed the mechanism leading to the flow fingering in the case of random fiber distribution. Effects of the filling pressure, the shear-thinning behavior of fluid and the volume fraction on the flow front have been investigated for both intra-tow and the inter-tow flows in dual-scale fiber tow models.

Rheological properties of branched polycarbonate prepared by an ultrasound-assisted intensive mixer

  • Kim, Hyung-Su;Lee, Hoo-Seok;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제19권1호
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    • pp.1-5
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    • 2007
  • By combining ultrasonic energy which is essential for the chain scission of polymer molecules and a multifunctional agent (MFA) having double bonds at its ends, we were able to modify the molecular structure of polycarbonate (PC) from linear to a branched structure during melt processing. The three double bonds in chain ends of MFA were expected to act as sites for trapping macroradicals of PC during the course of ultrasound-assisted mixing process. The transformation of molecular structure of PC was confirmed by the measurements of rheological properties of the modified PC. After the ultrasonic irradiation of PC together with MFA, increase in complex viscosities and shear-thinning behavior were observed. The Cole-Cole plot and measurement of extensional viscosities revealed the characteristic features of branched structure with well-defined extensional behavior which is comparable to that of a commercial branched PC.

The rheological behavior of collagen dispersion/poly(vinyl alcohol) blends

  • Lai, Guoli;Du, Zongliang;Li, Guoying
    • Korea-Australia Rheology Journal
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    • 제19권2호
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    • pp.81-88
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    • 2007
  • Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.

그라비어에서 잉크 침투의 컴퓨터 시뮬레이션 (The Computer Simulation of Ink Penetration in the Gravure)

  • 윤종태
    • 한국인쇄학회지
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    • 제28권2호
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    • pp.45-56
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    • 2010
  • The computer simulation is presented of gravure ink transferring behavior and penetration to the paper when an gravure roller is used to transfer a printing ink onto a substrate. The three dimensional unsteady ink motion is simulated by Polyflow package software and experimented by IGT gravure printing test machine. The simulation is performed where the flow domain is bounded above by a stress free surface and bounded below by a moving substrate. Specific predictions are made for particular pattern of cells and substrates. Cell size and ink rheological properties are found to be the principal determination of transferring behavior. Simulation is currently restricted to the flow domain beneath the receding meniscus. Both Newtonian and shear thinning inks are considered.

말토 덱스트린 첨가 알루미나 슬러리의 유동특성에 미치는 초음파 처리 강도와 진동 시간의 영향 검토 (Effects of ultrasonication intensity and shaking time on the rheological behavior of alumina slurries with maltodextrin)

  • 김종철;오근호
    • 한국결정성장학회지
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    • 제10권1호
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    • pp.80-85
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    • 2000
  • 말토 덱스트린이 첨가된 알루미나 슬러리의 공정조건 변화에 따른 유동특성 변화를 실험계획법과 통계적 방법을 사용하여 분석하였다. 공정조건으로는 말토 덱스트린 첨가 여부, 말토 덱스트린 첨가 전.후에 슬러리에 대한 초음파 처리, 슬러리의 진동기 유지시간 등이 검토되었다. 대부분의 경우 슬러리의 점도는 전단 희석 특성을 나타내었으며 Ostwald-de-Weale 모델에 적합한 것으로 나타났다. 알루미나 슬러리의 점도는 말토 덱스트린이 첨가됨에 따라 감소하였으나 초음파 처리 강도가 증대됨에 따라 증가되었으며, 초음파 처리 전.후에 말토 덱스트린을 첨가하는 것은 슬러리의 점도에 별다른 영향을 미치지는 않았다.

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Preparation and Characterization of Anionic Emulsified Asphalt with Enhanced Adhesion Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제50권4호
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    • pp.304-313
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    • 2015
  • In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

무기충전재가 PAN의 수화용융특성에 미치는 영향에 관한 연구(I) -PAN 수화응용체의 유변학적 특성- (Effect of Inorganic Fillers on the Properties of Hydrated PAN Melt(I) -Rheological Properties of Hydrated PAN Melt-)

  • 민병길;손태원
    • 한국염색가공학회지
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    • 제12권5호
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    • pp.295-300
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    • 2000
  • The melting behavior of hydrated polyacrylonitrile (PAN) and the rheological properties of hydrated PAN melt were investigated using DSC md modified capillary rheometer. With increasing the water content, Tm of the hydrated PAN was rapidly decreased and finally levelled off above a critical water content. However, the melt viscosity was further decreased even above the critical water content. The hydrated PAN melt showed a typical shear thinning behavior. In arrhenius plot, when the hydrated PAN melt was supercooled, it exhibited a different dependency on temperature from that above melting temperature.

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마요네즈의 유동 특성과 유화 안정성에 미치는 초산 농도의 영향 (Effects of Acetic Acid Concentration on Rheological Characteristics and Emulsion Stability of Mayonnaise)

  • 배효미;오명숙
    • 한국식품조리과학회지
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    • 제5권1호
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    • pp.9-13
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    • 1989
  • 초산용액의 초산농도를 0, 1, 2, 4, 6%로 변화하여 제조한 마요네즈의 유동 특성, 유화 안정성, 색도에 대하여 조사하였다. 마요네즈의 유동은 항복응력을 가지는 소성유동이며, 초산농도가 높아질수록 항복응력 및 점주도지수가 커져서 초산농도가 높아질수록 마요네즈의 물성이 점주해지는 것을 나타내었다. 마요네즈의 유화안정성은 초산농도가 높아질수록 감소하는 경향을 보였고, 초산노도 4%일 때 가장 안정성이 낮았다. 색도는 초산함량이 증가할수록 L값(명도)이 증가하고 b값(yellowness)은 감소하였다.

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2종의 경화액과 혼합된 calcium phosphate cement의 유변학적 성질에 관한 연구 (Rheological Properties of Calcium Phosphate Cement Mixed with 2 Kinds of Setting Solution)

  • 장석우;권호범;유현미;박동성;오태석;배광식
    • 구강회복응용과학지
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    • 제24권3호
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    • pp.311-316
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    • 2008
  • Calcium phosphate cement (CPC)는 우수한 생체 친화성을 바탕으로 치과 및 의과 쪽에서 성공적인 bone substitute로 사용되어 왔다. 긴 경화시간 및 washout tendency 등 CPC의 단점을 개선하기 위해 다양한 종류의 경화액 및 첨가제등에 대한 연구가 이루어졌다. 그러나 첨가제의 종류에 따른 CPC paste의 점탄성을 정량적으로 비교한 연구는 많지 않다. 이 연구에서는 2% hydroxyprophyl methylcellulose (HPMC)와 35% polyacrylic acid (PAA)의 두 가지 경화액과 혼합된 CPC의 유변학적 성질을 관찰하고 비교하고자 하였다. Dicalcium phosphate dihydrate (DCPD)를 2% HPMC 및 35% PAA와 각각 1:1의 분액비로 30초간 섞은 후 cone and plate geometry를 가지는 rheometer를 사용하여 frequency sweep test와 time sweep test를 통해 shear storage modulus (G'), shear loss modulus (G''), 그리고 complex viscosity (${\eta}^*$)를 측정하였다. 2% HPMC군과 35% PAA군의 complex viscostiy의 차이를 Mann-whitney test with Bonferroni's collection을 사용하여 분석하였다. 실험결과 2% HPMC 및 35% PAA 군 모두에서 shear thinning과 yield behavior등 pseudoplastic property를 보였으며 complex viscosity는 HPMC 군에서 PAA 군보다 통계적으로 유의성 있게 높았다. (p<0.05).