The research attempted to develop a wood adhesive based on waste cooking oil, using ozonification technology for the chemical structure modification. The waste cooking oil (WCO) was reacted with $O_3$ for different times; 1 h, 2 h, and 3 h. The chemical structure modifications of the ozonized WCOs were examined by Fourier transform Infrared (FT-IR) spectrum. The FT-IR spectrum of WCO had an absorbance peak at 3,010 $cm^{-1}$ that was the characteristic peak of the unsaturated double bonds. As ozone treatment time increased, the peak of the double bond was disappeared and carboxyl peak appeared at 1,700 $cm^{-1}$. Especially, the double bond of 3 hrs-ozonized WCO was vanished almost. In results of the dry bonding strengths of the 3 hrs-ozonized WCO mixed with polymeric methylene diphenyl diisocyanate (pMDI) were the strengths of weight ratio of 3hrs-ozonized WCO : pMDI, 1 : 0.5, 8.08 kgf/$cm^2$, 1 : 0.75, 9.53 kgf/$cm^2$ 1 : 1, 44.16 kgf/$cm^2$, 1 : 2, 58.08 kgf/$cm^2$, 1 : 3, 61.41 kgf/$cm^2$, and 1 : 4, 46.95 kgf/$cm^2$. Therefore, it was found that the optimum equivalent ratio was formed at the ratio of 1 : 2 or 1 : 3. Under wetting the bonding strength of 1 : 3 ratio was appeared higher than that of 1 : 2 ratio, while the results obtained from hot-water and cyclic boiling shear test were similar.
The success of porcelain laminate veneer depends on the bond strength between tooth structure and ceramic restoration and the design of tooth preparation. In particular, incisal coverage and incisal finish line are the two most important factors in long-term fracture resistance. Although the majority of clinicians are practicing incisal coverage and there are various opinions on the geo-metrical ratio between the clinical crown length of the remaining tooth structure and the length of incisal extension in porcelain laminate veneer and the optimal incisal finish lines. scientific evidence still loaves much to be desired. The purpose of this study was to determine the effects of the amounts of incisal coverage and the types of incisal finish line on the stress distribution in maxillary anterior porcelain laminate veneers under two different loading conditions. Three-dimensional finite element models of a maxillary anterior porcelain veneer with differ-ent amounts of incisal coverage ; 0, 1, 2, and 3mm and different incisal finish lines feathered edge, incisal bevel, reverse bevel and lingual chamfer with various amounts of lingual extension were developed. 300N force was applied at the point 0.5mm cervical of the linguoincisal edge in two loading conditions ; A) 125 degrees, B) 132 degrees. Tensile and compressive stress in ceramic and shear stress in the resin cement layer were analyzed using three-dimensional finite element method. The results were as follows : 1. The types of incisal finish line had more influence on the stress distribution in porcelain laminate veneer than the amounts of incisal coverage. 2. In case of no incisal coverage, incisal beveled laminate exhibited more evenly distributed tensile stress than feathered edged laminate. And in case of incisal coverage, reverse beveled laminate and lingual chamfered laminate with 1mm lingual extension exhibited more evenly distributed tensile stress than lingual chamfered laminates with 2mm and 3mm lingual extension. 3. As long as the lingual chamfer goes, less tensile stress was found at the incisal edge, while much more tensile stress was found at the lingual margin area in proportion to the length of lingual extension. 4. Under 125 degree load, tensile stress in porcelain laminate veneer had increased compared with that under 132 degree load and the difference exhibited by the change of the amount of tooth support was larger. 5. The types of incisal finish line and the distance from the incisal finish line to the loading point had more influence on the shear stress distribution in the resin cement layer than the amounts of incisal coverage. In contrast loading condition had little influence.
Journal of the Korea institute for structural maintenance and inspection
/
v.26
no.2
/
pp.43-50
/
2022
Even though the structural safety is confirmed in the design stage, the structural safety is not guaranteed in the construction stage because the structural system is not completed. In addition, since the construction period is shorter than the period of use of the building after completion, it is excessive to apply the same seismic load to the construction stage as in the design stage. ASCE 37-14 presents the concept of seismic load reduction factor during construction, but does not provide a clear application method. Therefore, in this study, the seismic load reduced according to the return period was applied to the example model of a residential middle-rise RC building. The construction stage of the example model was divided into five-story units, and seismic load with the change of the return period was applied to the construction stage models to analyze the change of seismic load during construction and to check the sectional performances of structural members. By comparing the design strength ratio of the shear wall at the design stage and the construction stage, the range of seismic load magnitudes that can assure the safety during construction of a residential middle-rise RC building was analyzed in terms of the return period.
The anisotropic behavior of rocks is primarily attributed to the directional arrangement of rock-forming minerals and the distribution characteristics of microcracks. Notably, sedimentary and metamorphic rocks often exhibit distinct transverse isotropy in terms of their strength and deformation characteristics. Consequently, it is crucial to gain accurate insights into the deformation and failure characteristics of transversely isotropic rocks during rock mechanics design processes. The deformation of such rocks is described by five independent elastic constants, which are determined through laboratory testing. In this study, the characteristics of the directional variation of apparent elastic constants in transversely isotropic rocks were investigated using experimental data reported in the literature. To achieve this, the constitutive equation proposed by Mehrabadi & Cowin was introduced to calculate the apparent elastic constants more efficiently and systematically in a rotated Cartesian coordinate system. Four transversely isotropic rock types from the literature were selected, and the influence of changes in the orientation of the weak plane on the variations of the apparent elastic modulus, apparent shear modulus, and apparent Poisson's ratio was analyzed. Based on the investigation, a new constraint on the elastic constants has been proposed. If the proposed constraint is satisfied, the directional variation of the apparent elastic constants in transversely isotropic rocks aligns with intuitive predictions of their tendencies.
Kim, Daeyeon;Kim, Soonchoen;Park, Young IL;Kim, Young Chul;Lim, Choong-Sun
Clean Technology
/
v.21
no.1
/
pp.76-82
/
2015
Volatile organic compounds (VOC) free adhesives have been interested by many scientists and engineers due to environmental regulations and the safety of industrial workers. In this work, a series of composites composed with bisphenol A epoxy resin used as solvent, dicyandiamide, and promoter were prepared to investigate the most appropriate molar ratio for steel-steel adhesion. The cured test specimen of each composite were measured with universal testing machine (UTM) to figure out mechanical properties such as tensile strength, Young’s modulus, and elongation. Furthermore, the lap shear strength of the specimen was tested with UTM while impact resistance was measured with Izod impact tester. The composite whose molar ratio of epoxy resin to curing agent is 1 : 0.9 (sample 3), showed better tensile strength, coefficient of elastic modulus, elongation, and impact strength than other composites did. The highest tanδ from dynamic mechanical analysis (DMA) was observed from sample 2 (epoxy resin: dicy = 1 : 0.7) while sample 3 showed slightly lower tanδ than that of 2. The morphology of the fracture surface of the cured composites from SEM showed that the number of subtle lines on the surface caused by impact increase as the contents of amine curing agent accrete. Furthermore, the viscosity change of sample 5 (epoxy resin: dicy = 1 : 1.3) was observed to confirm its storage stability.
Ha, Kwang-Hyun;Lee, Sang-Eun;Chung, Sung-Rae;Chun, Byung-Sik
Journal of Soil and Groundwater Environment
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v.13
no.1
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pp.13-23
/
2008
The triaxial compression tests and consolidation tests using NaCl solution and leachates as substitute pore (or saturated) water in samples were carried out to find out the behavior characteristics of strength, deformation and permeability coefficient of contaminated clay. Also, the chemical property analysis on the clay samples using scanning electron microscope and energy dispersive x-ray spectrometer were involved. The magnitudes of composition ratio were shown in the order of O, C, Si, Al, and Fe as a result of chemical composition analysis for clay samples. Besides, as the results of triaxial compression tests and consolidation tests, the shear strength, compression and permeability properties were increased with increasing in the concentration of contaminant (NaCl). It may be considered that these circumstances be caused by the changes of soil structure to flocculent structure due to the decrease in the thickness of diffuse double layer with increasing in the concentration of electrolyte. MT3D model was also using to grasp the procedures that the groundwater may be contaminated by the leachates permeated through the clay liner. The results of contaminant transport analysis showed a tendency that the predicted concentration of groundwater was higher with increasing in the initial concentration of $Cl^-$ ion and increased as a nonlinear curves with time. The transportation distance calculated by the use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with increasing the initial concentration.
Journal of the Korea institute for structural maintenance and inspection
/
v.19
no.2
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pp.170-178
/
2015
In this study, it was developed eco-friendly alkali-activated slag fiber reinforced concrete using ground granulated blast furnace slag, alkali activator (water glass, sodium hydroxides), and steel fiber. Eight reinforced concrete beam using alkali-activated slag concrete were constructed and tested under monotonic loading. The major variables were mixture ratio of alkali activator, mixed/without of steel fiber. Experimental programs were carried out to improve and evaluate the flexural performance of such test specimens, such as the load-displacement, the failure mode, the maximum load carrying capacity, and ductility capacity. All the specimens were modeled in scale-down size. The reinforced concrete beams using the eco-friendly alkali-activated slag fiber reinforced concrete was failed by the flexure or flexure-shear in general. In addition, the maximum strength increased with the adding the mol of sodium hydroxide, and the specimen reinforced the steel fiber showed the value of maximum strength which is increased by 15.8% through 25.9%. It is thought that eco-friendly alkali-activated slag fiber reinforced concrete can be used with construction material and product to replace normal concrete. If there is applied to structures such as precast concrete member and production of 2nd concrete product, it could be improved the productivity and reduction of construction duration etc.
Kim, Min-Sung;Park, Chan-Yik;Cho, Chang-Min;Jun, Seung-Moon
Journal of the Korean Society for Aeronautical & Space Sciences
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v.41
no.11
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pp.891-899
/
2013
This paper suggests a test and evaluation procedure of conformal load-bearing antenna structure(CLAS) for high speed military jet application. A log periodic patch type antenna was designed for multi-band communication and navigation antenna. Carbon/Glass fiber reinforced polymer was used as a structure supporting aerodynamic loads and honeycomb layer was used to improve antenna performance. Multi-layers were stacked and cured in a hot temperature oven. Gain, VSWR and polarization pattern of CLAS were measured using anechoic chamber within 0.15~2.0 GHz frequency range. Tension, shear, fatigue and impact load test were performed to evaluate structural strength of CLAS. Antenna performance test after every structural strength test was conducted to check the effect of structural test to antenna performance. After the application of new test and evaluation procedure to validate a new CLAS, a design improvement was found.
Journal of the Korea Academia-Industrial cooperation Society
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v.10
no.10
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pp.2831-2836
/
2009
If a design load exceeding the frictional force of the contact surface is applied to the connection of steel members using a high-tension bolt friction joint, sliding occurs and the connection of the steel members bears the design load through the shear strength and bearing strength of the bolt and the base plate. The sliding distance can be determined by the tensile force of the bolt, the friction coefficient of the contact surface, and the position of the bolt in the base plate hole. This study measured and analyzed sliding according to standard bolt hole and oversize bolt hole when pure bending moment and tensile force were applied to high-tension bolt joints with different sizes of bolt holes made in the base plate and the cover plate. In a high-tension bolt joint receiving pure bending moment and tensile force, the load causing sliding in an oversize bolt hole was $74\sim94%$ of that in a standard bolt hole. In a member receiving tensile force, the sliding load ratio was lower when the size of oversize bolt holes in the base plate and the cover plate was large. In addition, the size of the oversize bolt hole in the base plate was more closely correlated with the change of sliding loadthan the size of the oversize bolt hole in the base plate.
Various kinds of reinforced soil methods have been developed by many researchers or companies for their economic merits mainly. These methods have generally used sandy soils which have high permeability as embanking or backfill material. That is because, if poor embanking materials, especially like a clayey soil which has very low permeability, are used in a reinforced soil embanking, and if excessive pore water pressure is produced by external factors, the friction resistance between reinforcing members and Boils decrease, as a result possible damage or collapse of the body of a reinforced embankment. In fact, clayey Boils can also be used as a embanking materials with reinforcement which has high permeable capacity, and are expected to be able to dissipate the excess pore water pressure effectively. In this study reinforcing effects have been examined through a serries of direct shear tests in which clayey soils are reinforced with nonwoven geotextiles of which permeability is very high and tensile strength is relatively weaker than geogrids which are usually used in reinforced soil wall. Even though such nonwoven geotextile are used as reinforcement of high saturated clayey soils. the test results show the possibility that nonwoven geoteztiles could be used as a reinforcement for reinforced soil walls effectively.
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