• Title/Summary/Keyword: Sharp interface method

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MBE growth of topological insulator $Bi_2Se_3$ films on Si(111) substrate

  • Kim, Yong-Seung;Bansa, Namrata;Edrey, Eliav;Brahlek, Mathew;Horibe, Yoichi;Iida, Keiko;Tanimura, Makoto;Li, Guo-Hong;Feng, Tian;Lee, Hang-Dong;Gustafsson, Torgny;Andrei, Eva;Cheong, Sang-Wook;Oh, Seong-Shik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.59-59
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    • 2011
  • We will report atomically sharp epitaxial growth of $Bi_2Se_3$ three-dimensional topological insulator films on Si(111) substrate with molecular beam epitaxy (MBE). It was achieved by employing two step growth temperatures to prevent any formation of second phase, like as $SiSe_2$ clusters, between $Bi_2Se_3$ and Si substrate at the early stage of growth. The growth rate was determined completely by Bi flux and the Bi:Se flux ratio was kept ~1:15. The second-phase-free atomically sharp interface was verified by RHEED, TEM and XRD. Based on the RHEED analysis, the lattice constant of $Bi_2Se_3$ relaxed to its bulk value during the first quintuple layer implying the absence of strain from the substrate. Single-crystalline XRD peaks of $Bi_2Se_3$ were observed in films as thin as 4 QL. TEM shows full epitaxial structure of $Bi_2Se_3$ film down to the first quintuple layer without any second phases. This growth method was used to grow high quality epitaxial $Bi_2Se_3$ films from 3 QL to 3600 QL. The magneto-transport properties of these thin films show a robust 2D surface state which is thickness independent.

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Comparison of a Groundwater Simulation-Optimization Numerical Model with the Analytical Solutions (해안지하수개발 최적화수치모델과 해석해의 비교연구)

  • Shi, Lei;Cui, Lei;Lee, Chan-Jong;Park, Nam-Sik
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.905-908
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    • 2009
  • In the management of groundwater in coastal areas, saltwater intrusion associated with extensive groundwater pumping, is an important problem. The groundwater optimization model is an advanced method to study the aquifer and decide the optimal pumping rates or optimal well locations. Cheng and Park gave the analytical solutions to the optimization problems basing on Strack's analytical solution. However, the analytical solutions have some limitations of the property of aquifer, boundary conditions, and so on. A simulation-optimization numerical method presented in this study can deal with non-homogenous aquifers and various complex boundary conditions. This simulation-optimization model includes the sharp interface solution which solves the same governing equation with Strack's analytical solution, therefore, the freshwater head and saltwater thickness should be in the same conditions, that can lead to the comparable results in optimal pumping rates and optimal well locations for both of the solutions. It is noticed that the analytical solutions can only be applied on the infinite domain aquifer, while it is impossible to get a numerical model with infinite domain. To compare the numerical model with the analytical solutions, calculation of the equivalent boundary flux was planted into the numerical model so that the numerical model can have the same conditions in steady state with analytical solutions.

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Classification of Warm Temperate Vegetation Using Satellite Data and Management System (위성영상을 이용한 난대림 식생 분류와 관리 시스템)

  • 조성민;오구균
    • Korean Journal of Environment and Ecology
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    • v.18 no.2
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    • pp.231-235
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    • 2004
  • Landsat satellite images were analyzed to study vegetation change patterns of warm-temperate forests from 1991 to 2002 in Wando. For this purpose, Landsat TM satellite image of 1991 and Landsat ETM image of 2002 were used for vegetation classification using ENVI image processing software. Four different forest types were set as a classification criteria; evergreen broadleaf, evergreen conifer, deciduous broadleaf, and others. Unsupervised classification method was applied to classily forest types. Although it was impossible to draw exact forest types in rocky areas because of differences in data detection time and rough resolution of image, 2002 data revealed that total 2,027ha of evergreen broadleaf forests were growing in Wando. Evergreen broadleaves and evergreen conifers increased in total areas compared to 11 years ago, but there was sharp decrease in deciduous broadleaves. GIS-based management system for warm-temperate forest was done using Arc/Info. Geographic and attribute database of Wando such as vegetation, soils, topography, land owners were built with Arc/Info and ArcView. Graphic user interface which manages and queries necessary data was developed using Avenue.

Software for adaptable eccentric analysis of confined concrete circular columns

  • Rasheed, Hayder A.;El-Fattah, Ahmed M. Abd;Esmaeily, Asad;Jones, John P.;Hurst, Kenneth F.
    • Computers and Concrete
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    • v.10 no.4
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    • pp.331-347
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    • 2012
  • This paper describes the varying material model, the analysis method and the software development for reinforced concrete circular columns confined by spiral or hoop transverse steel reinforcement and subjected to eccentric loading. The widely used Mander model of concentric loading is adapted here to eccentric loading by developing an auto-adjustable stress-strain curve based on the eccentricity of the axial load or the size of the compression zone to generate more accurate interaction diagrams. The prediction of the ultimate unconfined capacity is straight forward. On the other hand, the prediction of the actual ultimate capacity of confined concrete columns requires specialized nonlinear analysis. This nonlinear procedure is programmed using C-Sharp to build efficient software that can be used for design, analysis, extreme event evaluation and forensic engineering. The software is equipped with an elegant graphics interface that assimilates input data, detail drawings, capacity diagrams and demand point mapping in a single sheet. Options for preliminary design, section and reinforcement selection are seamlessly integrated as well. Improvements to KDOT Bridge Design Manual using this software with reference to AASHTO LRFD are made.

PACVD of Plasma Polymerized Organic Thin Films and Comparison of their Electrochemical Properties

  • I.S. Bae;S.H. Cho;Kim, M.C.;Y.H. Roh;J.H. Boo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.05a
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    • pp.53-53
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    • 2003
  • Plasma polymerized organic thin films were deposited on Si(100) glass and metal substrates using thiophene and ethylcyclohexane precursors by PECVD method. In order to compare electrochemical properties of the as-grown thin films, the effects of the RF plasma power in the range of 30~100 W. AFM showed that the polymer films with smooth surface and sharp interface could be grown under various deposition conditions. Impedance analyzer was utilized for the determination of I-V curve for leakage current density and C-V for dielectric constants, respectively. To obtain C-V curve, we used a MIM structure of metal(Al)-insulator(plasma polymerized thin film)-metal(Pt) structure. Al as the electrode was evaporated on the thiophene films that grew on Pt coated silicon substrates, and the dielectric constants of the as-grown films were then calculated from C- V data measured at 1MHz. From the electrical property measurements such as I-V and C-V characteristics, the minimum dielectric constant and the best leakage current of thiophene thin films were obtained to be about 3.22 and $1{\;}{\times}10^{-11}{\;}A/cm^2$. However, in case of ethylcyclohexane thin films, the minimum dielectric constant and the best leakage current were obtained to be about 3.11 and $5{\;}{\times}10^{-12}{\;}A/cm^2$.

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Molecular Dynamics Simulation on the Thermal Boundary Resistance of a Thin-film and Experimental Validation (분자동역학을 이용한 박막의 열경계저항 예측 및 실험적 검증)

  • Suk, Myung Eun;Kim, Yun Young
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.32 no.2
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    • pp.103-108
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    • 2019
  • Non-equilibrium molecular dynamics simulation on the thermal boundary resistance(TBR) of an aluminum(Al)/silicon(Si) interface was performed in the present study. The constant heat flux across the Si/Al interface was simulated by adding the kinetic energy in hot Si region and removing the same amount of the energy from the cold Al region. The TBR estimated from the sharp temperature drop at the interface was independent of heat flux and equal to $5.13{\pm}0.17K{\cdot}m^2/GW$ at 300K. The simulation result was experimentally confirmed by the time-domain thermoreflectance technique. A 90nm thick Al film was deposited on a Si(100) wafer using an e-beam evaporator and the TBR on the film/substrate interface was measured using the time-domain thermoreflectance technique based on a femtosecond laser system. A numerical solution of the transient heat conduction equation was obtained using the finite difference method to estimate the TBR value. Experimental results were compared to the prediction and discussions on the nanoscale thermal transport phenomena were made.

Deposition of Plasma Polymerized Films on Silicon Substrates Using Plasma Assisted CVD Method For Low Dielectric Application

  • Kim, M.C.;S.H. Cho;J.H. Boo;Lee, S.B.;J.G. Han;B.Y. Hong;S.H. Yang
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.06a
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    • pp.72-72
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    • 2001
  • Plasma polymerized thin films have been deposited on Si(lOO) substrates at $25-400^{\circ}C$ using thiophene ($C_4H_4S$) precursor by plasma assisted chemical vapor deposition (PACVD) method for low-dielectric device application. In order to compare physical properties of the as-grown thin films, the effects of the plasma power, gas flow ratio and deposition temperature on the dielectric constant and thermal stability were mainly studied. XRD and TED studies revealed that the as-grown thin films have highly oriented amorphous polymer structure. XPS data showed that the polymerized thin films that grown under different RF power and deposition temperature as well as different gas ratio of $Ar:H_2$ have different stoichiometric ratio of C and S compared with that of monomer, indicating a formation of mixture polymers. Moreover, we also realized that oxygen free and thermally stable polymer thin films could be grown at even $400^{\circ}C$. The results of SEM, AFM and TEM showed that the polymer films with smooth surface and sharp interface could be grown under various deposition conditions. From the electrical property measurements such as I-V and C-V characteristics, the minimum dielectric constant and the best leakage current were obtained to be about 3.22 and $10-11{\;}A/\textrm{cm}^2$, respectively.

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The Study on the Crystal Growing of Mn-Zn Ferrite Single Crystals by Floating Zone Method (Floating Zone법에 의한 Mn-Zn Ferrite 단결정성장에 관한 연구)

  • 정재우;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.1
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    • pp.10-19
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    • 1992
  • Mn - Zn Ferrite has physical properties of the high initial permeability, saturation magnetic flux density, and low loss factor as a representative magnetic material of soft ferrites, in addition the mechanical property is excellent as a single crystal. Therefore it is important electronic components and used for VTR Head. Mn - Zn Ferrite single crystals with the diameter 8mm were grown in atmosphere mixed with $O_2$ and Ar gas by the Floating Zone(FZ) method that impurities can not be incorporated to the crystals because of not-using the crucible to put in the melt, and the sharp temperature gradient results from making a focus at one point utilizing the infrared ray emitted from the halogen lamp as a heat source. During the crystal growing, the highest temperature of melting area was maintained to be $1650^{\circ}C$, growth rate and rotation rate were 10 mm/hr, 20 rpm respectively. The phases and the growth directions of crystals were determined from the analysis of X RD patterns, Laue, TEM diffraction patterns and etch pit shapes were observed by the optical microscope through the chemical etching. The corelation of optimum conditions for acquiring the better crystals was found out with the growth rate, the length and diameter of melt at the interface according to the diameter of feed rod, and the patterns of growing interface also studied.

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Electrical Conductance and Electrode Reaction of $RbAg_4I_5$ Single Crystals (고체전해질 $RbAg_4I_5$ 단결정의 전기전도성과 전극반응)

  • Jong Hee Park;Woon-Kie Paik
    • Journal of the Korean Chemical Society
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    • v.24 no.4
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    • pp.295-301
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    • 1980
  • The electrical conductivity of solid electrolyte $RbAg_4I_5$ single crystal was studied at various temperatures. The four-probe method was used in measuring the conductance with an ac signal imposed on the specimen. The ionic conductivity was $0.284 ohm^{-1} cm^{-1}\;at\;25^{\circ}C$, and the activation energy for $Ag^+$ ion migration was calulated to be 1.70 kcal/mole. These values agree well with those reported for polycrystalline samples. Reactions at $Ag/RbAg_4I_5$ interface were studied by cyclic voltammetry with a silver reference electrode. It was found that silver ion is reversibly reduced at silver surfaces below zero volt, and iodide was oxidized above +0.67 volt.The anodic current arising from the oxidation of the electrode was small in magnitude initially over a wide range of potential, but, after silver was cathodically deposited on the electrode, reversing the potential sweep to the anodic direction resulted in a sharp peak of anodic current.

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Effectiveness of Double Negative Barriers for Mitigation of Sewater Intrusion in Coastal Aquifer: Sharp-Interface Modeling Investigation (경계면 수치 모델을 이용한 해안 지역 이중 양수정의 해수침투 저감 효과)

  • Jung, Eun Tae;Lee, Sung Jun;Lee, Mi Ji;Park, Namsik
    • Journal of Korea Water Resources Association
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    • v.47 no.11
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    • pp.1087-1094
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    • 2014
  • Saltwater pumping method can be used to mitigate saltwater intrusion in coastal aquifers. However, the saltwater pumping well may discharge large freshwater along with saltwater, thereby wasting precious resources. A double negative barrier was proposed: an inland well to capture freshwater and a saltwater well near the coastline to pump saltwater. A previous study anaylzed effects of double negative barriers in dispersion-dominated coastal aquifers and determined the critical pumping rate at the saltwater well which minimized the saltwater ratio at the freshwater well. However, the study resulted in 1~15% of saltwater ratios, which were too high, for example, for drinking water standards. This study analyzed cases that were considered in the previous study, but for advection-dominated cases, and found that freshwater with sufficiently low saltwater ratios could be developed at the freshwater well. In addition, for optimal groundwater management of a watershed not only the minimum saltwater ratio at the freshwater well but also the least freshwater wasted at the saltwater well must be pursued.