• 한국재료학회지
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• 제23권7호
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• pp.373-378
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• 2013

In order to clarify the effect of C/Ti atom ratios(${\chi}$) on the deformation behavior of $TiC_{\chi}$ at high temperature, single crystals having a wide range of ${\chi}$, from 0.56 to 0.96, were deformed by compression test in a temperature range of 1183~2273 K and in a strain rate range of $1.9{\times}10^{-4}{\sim}5.9{\times}10^{-3}s^{-1}$. Before testing, $TiC_{\chi}$ single crystals were grown by the FZ method in a He atmosphere of 0.3MPa. The concentrations of combined carbon were determined by chemical analysis and the lattice parameters by the X-ray powder diffraction technique. It was found that the high temperature deformation behavior observed is the ${\chi}$-less dependent type, including the work softening phenomenon, the critical resolved shear stress, the transition temperature where the deformation mechanism changes, the stress exponent of strain rate and activation energy for deformation. The shape of stress-strain curves of $TiC_{0.96}$, $TiC_{0.85}$ and $TiC_{0.56}$ is seen to be less dependent on ${\chi}$, the work hardening rate after the softening is slightly higher in $TiC_{0.96}$ than in $TiC_{0.85}$ and $TiC_{0.56}$. As ${\chi}$ decreases the work softening becomes less evident and the transition temperature where the work softening disappears, shifts to a lower temperature. The ${\tau}_c$ decreases monotonously with decreasing ${\chi}$ in a range of ${\chi}$ from 0.86 to 0.96. The transition temperature where the deformation mechanism changes shifts to a lower temperature as ${\chi}$ decreases. The activation energy for deformation in the low temperature region also decreased monotonously as ${\chi}$ decreased. The deformation in this temperature region is thought to be governed by the Peierls mechanism.

• 한국자기공명학회논문지
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• 제11권2호
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• pp.64-72
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• 2007

[ $^1H$ ] nuclear magnetic resonance (NMR) experiments have been performed at 30 - 300 K and 7 T to investigate dynamics of hydrogen bond network in the single crystal $(NH_4)_3H(SO_4)_2$. The two proton sites, ammonium proton and hydrogen-bond proton, are identified from the $^1H$ NMR MAS spectrum at 340 K. As temperature decreases, the $^1H$ NMR spectrum shifts to the higher frequency side with a larger linewidth. The spectrum at 65 K shows a distinctive change in line shape toward the ferroelectric transition at 63 K. The measured values of $T_1$ for ammonium and hydrogen-bond protons are similar in the whole range of temperature. $T_1$ of $^1H$ NMR shows a gradual decrease down to 120 K and starts to steeply increase below 100 K. Then $T_1$ shows abrupt decrease below 70 K with a sharp minimum at 63 K, where the ferroelectric transition occurs. This temperature dependence of spectrum and $T_1$ clearly prove that the large change in the dynamics of hydrogen bond network is associated with the ferroelectric phase transition at 63 K.

• 대한기계학회논문집B
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• 제31권11호
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• pp.895-903
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• 2007

CMBT(Curved Moving Boundary Treatment) is a newly developed scheme for the treatment of a no slip condition on the curved solid wall of moving obstacle in a flow field. In our research CMBT was used to perform LBM simulation of a flow over a moving circular cylinder to determine the flow feature and aerodynamics characteristic of the cylinder. To ascertain the applicability of CMBT on the complex shape of the obstacle, it was first simulated for the case of the flow over a fixed circular cylinder in a channel and the results were compared against the solution of Navier-Stokes equation with deforming mesh technique. The simulations were performed in a moderate range of reynolds number at each moving cylinder to identify the flow feature and aerodynamic characteristics of circular cylinder in a channel. The drag coefficients of the cylinder were calculated from the simulation results. We have numerically confirmed that the critical reynolds number for vortex shedding is ar Re=250 and the result is the same as the case of fixed cylinder. As the cylinder approaching to one wall, the 2nd vortex is developed by interacting with the wall boundary-layer vorticity. As the velocity ratio increase the third vortex are generated by interacting with the 2nd vortexes developed on the upper and lower wall boundary layer. The resultant $C_d$ decrease as reynolds number increasing and the Cd approached to a value when Re>1000.

• 한국철도학회논문집
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• 제13권5호
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• pp.500-503
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• 2010

지금까지 궤도회로는 레일을 전기회로의 일부로 사용하여 열차의 위치 검지용으로만 사용하였으나 철도차량이 고속화 되면서, 지상신호의 한계를 극복하기 위하여 차상신호시스템의 사용이 일반화 되어가고 있다. 궤도회로의 전원은 직류나 고전압 임펄스를 사용하던 방식에서 가청주파수를 사용하는 고주파 교류궤도회로의 사용이 일반화 되고 있다. 철도도상도 환경과 궤도의 유지보수성 개선을 위하여 철근콘크리트 도상의 사용이 증대되고 있다. 철근 콘크리트 도상에서 고주파 교류궤도회로를 사용할 경우 도상의 내구성 향상을 위하여 사용되는 수많은 격자모양의 철근들로 인하여 전기적 절연에 의한 누설전류가 아닌 자기결합에 의한 손실로 인한 궤도정수의 변화를 초래할 수 있다. 본 논문은 철근콘크리트도상에서 AF(Audio Frequency)궤도회로를 사용하였을 경우 도상 철근에 의한 궤도회로신호의 영향과 손실을 시뮬레이션을 통하여 알아보고 이를 방지할 수 있는 방안을 제시하였다.

• 한국공작기계학회논문집
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• 제16권6호
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• pp.146-152
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• 2007

An active micro-mixer, which was composed of an oscillating micro-stirrer in the microchannel to provide rapid, effective mixing at high flow, rates was analyzed. The effects of molecular diffusion and disturbance by the stirrer were considered with regard to two types of mixer models: the simple straight microchannel and microchannel with an oscillating stirrer. Two types of mixer models were studied by analyzing mixing behaviors such as their interaction after the stirrer. The mixing was calculated by Lattice Boltzmann methods using the D2Q9 model. In this study, the time-averaged mixing index formula was used to estimate the mixing performance of time-dependent flow. The mixing indices of the two models compared. From the results, it was found that the mixer with an oscillating stirrer was much more enhanced and stabilized. Therefore, an optimum design for a dynamic micro-mixer with an oscillating stirrer was performed using Taguchi method in order to obtain a robust solution. The design parameters were established as the frequency, the length and the angle of the stirrer and the optimal values were determined to be 2, 0.8D and ${\pm}75^{\circ}$, respectively. It was found that the mixing index of the optimal design increased 80.72% compared with that of the original design.

• 한국재료학회지
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• 제9권8호
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• pp.854-857
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• 1999

Fe-Se-Te계(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8)의 특성을 X-선 회절법 및 Mossbauer 분광법에 의해 조사하였다. 결정구조는 세 시료 모두 주된 tetragonal PbO 구조와 hexagonal NiAs 구조가 일부 혼합된 형태를 보였으며 x=0.5의 경우 tetragonal 구조의 격자상수 값은 a=3.795$\AA$, c=5.896$\AA$ 이며 c/a=1.55로 나타났다. 다양한 온도변화에 의해 측정된 Mossbauer 스펙트럼은 전체 시료 모두 초미세 자기구조를 갖지 않는 강한 이중선(doublet)이 관측되었다. 조성 및 온도변화에 대해 뚜렷한 선형(line shape)의 변화는 관측되지 않았으나 결합상태에 약간의 변화를 보였다. 이성질체 이동(isomer shift)값과 사중극자 분열(quadrupole splitting)값 및 온도의존성을 분석한 결과 Fe는 low spin이 +2가 상태로 존재하며 강한 공유 결합상태임을 알 수 있었다. x=0.8의 경우 이성질체 이동값의 온도변화는 제2차 도플러 효과(second order Doppler effect)의 영향인 것으로 나타났다.

• 한국전자파학회논문지
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• 제12권7호
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• pp.1182-1190
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• 2001

본 논문에서는 마이크로스트립 선로상의 금속부분을 일부 제거한 형태의 Photonic bandgap (PBG) 구조의 특성을 분석하고 형태를 최적화 한 후 전력 증폭기에 적용하여 고조파 동조를 수행하였다. 이 구조는 제작 및 접지에서 타 구조에 비해 유리하다. PCB 제작 과정의 오차를 줄이기 위해 단위 격자의 크기를 수직방향으로 증가시키고, 테이퍼 선로를 이용하여 입출력을 50 $\Omega$으로 유지시켰다. EM 시뮬레이션으로 PBG 구조의 특성을 분석하고 설계하였으며, 최종적으로 통과대역 손실 0.3~0.4dB, 저지대역폭 6~7GHz의 특성을 얻었다. 전력 증폭기에 PBG구조를 적용한 후 출력 전력은 0.72~0.99dB, PAE는 1.14~7.8 %, 3차 IMD는 1 dBc 증가하는 결과를 얻을 수 있었다.

• Journal of Magnetics
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• 제19권2호
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• pp.126-129
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• 2014

We report the crystallographic and magnetic properties of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ by means of X-ray diffractometer (XRD), a superconducting quantum interference device (SQUID) magnetometer, and a M$\ddot{o}$ssbauer spectroscopy. In particular, $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was studied by M$\ddot{o}$ssbauer analysis for evidence of spin reorientation. The chalcogenide material $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was fabricated by a direct reaction method. XRD analysis confirmed that $Ni_{0.3}Fe_{0.7}Ga_2S_4$ has a 2-dimension (2-D) triangular lattice structure, with space group P-3m1. The M$\ddot{o}$ssbauer spectra of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ at spectra at various temperatures from 4.2 to 300 K showed that the spectrum at 4.2 K has a severely distorted 8-line shape, as spin liquid. Electric quadrupole splitting, $E_Q$ has anomalous two-points of temperature dependence of $E_Q$ curve as freezing temperature, $T_f=11K$, and N$\acute{e}$el temperature, $T_N=26K$. This suggests that there appears to be a slowly-fluctuating "spin gel" state between $T_f$ and $T_N$, caused by non-paramagnetic spin state below $T_N$. This comes from charge re-distribution due to spin-orientation above $T_f$, and $T_N$, due to the changing $E_Q$ at various temperatures. Isomer shift value ($0.7mm/s{\leq}{\delta}{\leq}0.9mm/s$) shows that the charge states are ferrous ($Fe^{2+}$), for all temperature range. The Debye temperature for the octahedral site was found to be ${\Theta}_D=260K$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.453-453
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• 2010

In this study, zinc germanate ($Zn_2GeO_4$) thin films has been synthesized by using radio frequency magnetron sputtering and the divalent manganese-activated luminescence was characterized. X-ray diffraction patterns of the as-deposited $Zn_2GeO_4$:Mn films showed only a broad feature, indicative of an amorphous structure. Scanning electron microscopy images revealed that the as-deposited $Zn_2GeO_4$:Mn has a smooth surface morphology. The $Zn_2GeO_4$:Mn films were found to be crystallized by annealing in air ambient at temperatures as low as $700^{\circ}C$. The annealed $Zn_2GeO_4$:Mn possessed a rhombohedral polycrystalline structure. The broad-band photoluminescent emission spectrum from 470 to 650nm was obtained at room temperature from the $Zn_2GeO_4$:Mn films. The emission peak was centered at around 535nm in the green range, which originates from the intrashell transition of manganese $3d^5$ electrons from $^4T_1$ excited-state level to the $^6A_1$ ground state. The PL emission spectrum had an asymmetric line shape, which results from the $^3d_5$ electron transitions of divalent manganese ions located at different sites of the zinc germanate host crystal lattice. Electroluminescent devices were fabricated using $Zn_2GeO_4$:Mn as an emission layer. The fabricated devices showed a green EL emission similar to the PL emission. The CIE chromaticity color coordinates of the EL emission were determined to be x=0.308 and y=0.657.

• 박물관보존과학
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• 제16권
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• pp.14-31
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• 2015

고령 지산동 고분군 39호분에서 출토된 장식대도(M310)는 손잡이 끝의 둥근 고리 안에 용의 머리를 장식한 환두대도로 금과 은을 활용하여 금장, 은장, 도금, 투조, 조금의 기술로 제작되었다. 장식대도는 손잡이 금구의 변형과 손상, 도신의 결실, 부식 등이 발생하여 보존처리를 진행하였다. 보존처리는 표면 이물질 및 부식물 제거, 재질의 안정화처리, 강화 처리 순으로 진행하였으며 보존처리와 병행하여 유물의 재질 및 제작기법을 조사하였다. 조사 결과 환두 내 용장식은 아말감도금기법으로 표면이 장식되었고 병두금구는 동제지판에 얇은 금판을 덧씌워 장식되었다. 병판은 은제판을 사격자문으로 투조하여 원통형으로 만들었으며 대도의 칼은 외날의 철제이다. 초구금구 역시 동제지판에 얇은 금판을 덧씌워 장식한 것으로 확인되었다.