• Clean Technology
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• v.12 no.2
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• pp.87-94
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• 2006

The reduction of $SO_2$ to elemental sulfur by CO over a series of iron niobate with nominal Nb/Fe atomic ratios of 1/0, 10/1, 5/1, 1/1, 1/5, 1/10 and 0/1 was studied with a flow fixed-bed reactor. Strong synergistic phenomena in catalytic activity and selectivity were observed for the iron niobate catalysts, and the best catalytic performance was observed for the catalyst with Fe/Nb atomic ratio of 1/1. The active phase of the activated iron niobate catalysts was identified to be $FeS_2$ using XRD and XPS. Selective reduction of $SO_2$ by CO was followed by the COS intermediate mechanism.

• Journal of Korean Society on Water Environment
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• v.26 no.5
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• pp.747-753
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• 2010

A series of experiments with a laboratory scale ultrasound treatment system for MTBE polluted groundwater was performed to increase the efficiency of MTBE degradation in groundwater. This study evaluated several factors to increase the efficiency of MTBE treatment for artificial and natural groundwater. The treated volume of groundwater, ultrasound frequency and power, and pollutant concentrations have been changed to evaluate its effects on the degradation efficiency of MTBE in batch and continuous flow reactor. For the specific experimental conditions on this paper, MTBE degradations are more efficient at 580 kHz than those at 1 MHz. The efficiency of MTBE degradation is proportional to the intensity of ultrasound power per unit volume of MTBE polluted groundwater. The concentration of ions in groundwater does not much affect the efficiency of MTBE degradation. The $1^{st}$ order degradation constant of MTBE for different power per unit volume at 580 kHz shows linear relationship at same concentration. The $1^{st}$ order degradation constant for 0.1 mM MTBE solution is higher than that for 1 mM MTBE solution. These experimental results could be helpful to seek optimal conditions for relatively large volume of polluted groundwater treatment.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.4
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• pp.62-70
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• 2005

This paper presents the actual conditions and reform measures of voltage and current harmonics being made in low-voltage power systems supplying various loads. The measurements were carried out at the secondary output terminals of 22.9[kV]/380[V]220[V] customer's transformers, and the results were discussed on the basis of the comparison with IEEE and IEC harmonics control standards. The voltage THDs of the power systems employed in this survey were less than $5[\%]$ that is considered to be acceptable. On the contrary, the current distortions were significantly greater than the voltage distortions, and the current THDs were distributed over the wide-range from 15.7 to $60.4[\%]$. In particular, the current distortion on the low voltage power lines of office buildings in which many PC and fluorescent lamps are used is remarkably more serious than that of factory facilities. As a result, the voltage distortion factors are observed within the range of its allowable level or less than the limits, but the current distortion factors are significantly greater than the limits of IEEE and IEC standards.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.17-22
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• 2007

Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor. The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside the small autoclave. So the magnet type LVDT's were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. FEM calculated the displacement and the strain of the gauge length from the data measured at the shoulders. Tensile test properties in elastic and plastic behavior of CF8M material were used in the FEM analysis. A series of low cycle fatigue tests simulating the cyclic strain hardening effect verified that the FEM calculation was well agreed with the simulated tests. The process and method developed in this study would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

• Environmental Engineering Research
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• v.17 no.3
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• pp.157-165
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• 2012

This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was $59.67Am^3/hr$ via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of $CO_2$, CO, and $H_2$ in the synthetic gas of $38.63{\pm}3.11%$, $35.18{\pm}1.93%$, and $28.42{\pm}1.68%$, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and $H_2$ can be obtained from the pyrolysis of insulating oil containing PCBs.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.811-817
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• 2013

A two-stage bioreactor system using sulfur-oxidizing bacteria was studied to abate high strength hydrogen sulfide ($H_2S$) from biogas. The two-stage bioreactor consisted of a $H_2S$ absorption column (0.5 L) and a microbial oxidation column (1 L) in series, and the liquid medium was continuously recirculated through the columns. The objectives of this study were to determine the feasibility of the bioreactor for biogas desulfurization and to investigate the effect of the medium circulation rate on the system performance. An averaged concentration of $H_2S$ introduced to the bioreactor was 530 ppm, corresponding to an overall loading rate of $44.4g/m^3/hr$. During the initial 20 days period at the medium recirculation rate of 8 reactor volumes per hour (12 L/hr), the dissolved oxygen (DO) concentration in the oxidation column was 6 mg/L, while the DO in the absorption column was 0.5 mg/L showing that the oxygen contents of the biogas stream was not altered. Because of the biological oxidation of $H_2S$ in the oxidation column, the sulfate concentration increased from 200 mg/L to 5,600 mg/L in the liquid medium. The removal efficiency of $H_2S$ was greater than 99% in the initial operation period. After the initial period, the medium recirculation rate between the two columns was stepwise changed eight times from 1.0 to 40 vol/hr (1.5~60 L/hr). At the recirculation rate of faster than 4 vol/hr, the $H_2S$ removal efficiencies were found to be high, but the efficiency declined at the lower recirculation rates than the threshold.

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1613-1618
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• 2014

Perovskite-type oxides are promising oxygen carriers in producing oxygen-enriched $CO_2$ gas stream for oxyfuel combustion. In this study, a new series of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ (x = 0.2, 0.4, 0.6, 0.8) was prepared and used to produce $O_2/CO_2$ mixture gas. The phase, crystal structure, and morphological properties of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ were investigated through X-ray diffraction, specific surface area measurements, and environmental scanning electron microscopy. The oxygen desorption performance of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ was studied in a fixed-bed reactor system. Results showed that the different x values of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ have no obvious effects on crystalline structure. However, the oxygen desorption performance of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ is improved by Co doping. Moreover, $SrCo_{0.8}Fe_{0.2}O_{3-{\delta}}$ synthesized via a new EDTA method has a larger BET surface area ($40.396m^2/g$), smaller particle size (48.3 nm), and better oxygen production performance compared with that synthesized through a liquid citrate method.

• Nuclear Engineering and Technology
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• v.52 no.4
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• pp.846-855
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• 2020

A loose part monitoring system is used to detect unexpected loose parts in a reactor coolant system in a nuclear power plant. It is still necessary to develop a new methodology for the localization and mass estimation of loose parts owing to the high estimation error of conventional methods. In addition, model-based diagnostics recently emphasized the importance of a model describing the behavior of a mechanical system or component. The purpose of this study is to propose a new localization and mass-estimation method based on finite element analysis (FEA) and optimization technique. First, an FEA model to simulate the propagation behavior of the bending wave generated by a metal sphere impact is validated by performing an impact test and a corresponding FEA and optimization for a downsized steam-generator structure. Second, a novel methodology based on FEA and optimization technique was proposed to estimate the impact location and mass of a loose part at the same time. The usefulness of the methodology was then validated through a series of FEAs and some blind tests. A new feature vector, the cross-correlation function, was also proposed to predict the impact location and mass of a loose part, and its usefulness was then validated. It is expected that the proposed methodology can be utilized in model-based diagnostics for the estimation of impact parameters such as the mass, velocity, and impact location of a loose part. In addition, the FEA-based model can be used to optimize the sensor position to improve the collected data quality in the site of nuclear power plants.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.8
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• pp.689-693
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• 2009

We investigate the comparison of fault current characteristics between the separates three-phase flux-lock type superconducting fault current limiter(SFCL) and integrated three-phase flux-lock type superconducting fault current limiter(SFCL). The single-phase flux-lock type SFCL consists of two coils. The primary coil is wound in parallel to the secondary coil on an iron core and superconducting elements are connected to secondary coil in series. Superconducting elements are used by the YBCO coated conductor. The separated three-phase flux-lock type SFCL consists of single-phase flux-phase type SFCL in each phase. But the integrated three-phase flux-lock type SFCL consists of three-phase flux-reactors wound on an iron core. Flux-reactor consists of the same turn's ratio between coil 1 and coil 2 for each single phase. To compare the current limiting characteristics of the separated three-phase flux-lock type SFCL and integrated three-phase flux-lock type SFCL, the short circuit experiments are carried out fault condition such as the single line-to-ground fault. The experimental result shows that fault current limiting characteristic of the separated three-phase flux-lock type SFCL was better than integrated three-phase flux-lock type SFCL. And the integrated three-phase flux-lock type SFCL has an effect on sound phase.

• Journal of the Korean Institute of Intelligent Systems
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• v.16 no.3
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• pp.383-388
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• 2006

SBR is one of the most general sewage/wastewater treatment processes and, particularly, has an advantage in high concentration wastewater treatment like sewage wastewater. A Kernel PCA based fault diagnosis system for biological reaction in full-scale wastewater treatment plant was proposed using only common bio-chemical sensors such as ORP(Oxidation-Reduction Potential) and DO(Dissolved Oxygen). During the SBR operation, the operation status could be divided into normal status and abnormal status such as controller malfunction, influent disturbance and instrumental trouble. For the classification and diagnosis of these statuses, a series of preprocessing, dimension reduction using PCA, LDA, K-PCA and feature reduction was performed. Also, the diagnosis result using differential data was superior to that of raw data, and the fusion data show better results than other data. Also, the results of combination of K-PCA and LDA were better than those of LDA or (PCA+LDA). Finally, the fault recognition rate in case of using only ORP or DO was around maximum 97.03% and the fusion method showed better result of maximum 98.02%.