• Title/Summary/Keyword: Sequential extraction

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Characteristics of roadside soils and effects of pH and Time on their reaching behaviors of Pb, Zn, Cd and Mn (도로변 토양의 오염 특성과 Pb, Zn, Cd 및 Mn의 침출거동에 미치는 pH와 반응시간의 영향)

  • 이평구
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.53-62
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    • 1999
  • The possibility of heavy metal pollution by contaminated roadside soils was studied under controlled conditions. The soil samples from roadside and those from a retention pond consisting of settling particles were characterized by the XRD analyses and the sequential extraction experiments. Characterization by sequential extraction, for roadside soil indicates elevate total concentrations of heavy metals. The leaching behavior of the samples under different pH and time conditions were also studied. Differences between both types of samples result mainly from the buffering effect of carbonates, present in roadside soils and lacking from settling particles. Acid leaching of the settling particles is equivalent to the sum of FI+FII+FIII, while the amounts leached from roadside soil are lower probably from kinetic reasons. The buffering effects of carbonates were found to greatly delay the onset of the leaching reactions and the extent of dissolution in most metals except for Ca and Mn. The study of leaching kinetics at pH of 6.5 and 5 showed that Cd and Zn reached the maximum possible concentration within 3 days, while Pb did not show any sign of dissolution at both ph values. The absolute amounts of dissolved Cd and Zn increased by 7 to 9 times by decreasing the pH from 6.5 to 5, indicating slightly acidified rain may result in significant metal dissolution. As deduced from both sequential extraction and leaching experiments, the relative mobility of heavy metals is found to be : Mn=Cd>Zn>>Pb>Fe, in spite of large differences in heavy metal contents and localizations.

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Non-tensed VP Coordination in Korean: Structure and Meaning

  • Cho Sae-Youn
    • Language and Information
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    • v.9 no.1
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    • pp.35-49
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    • 2005
  • Lakoff(1986) claim that sequential fading alone suffices to sanction ATB violations cannot be supported in Korean verbal coordination of TP, since extraction from the conjunction of TP in Korean is impossible regardless of whether the conjuncts are interpreted sequentially or non-sequentially. However, ATB violations are allowed in the coordination of Non-TP, only when the conjuncts are interpreted sequentially. 1 will argue that Non-TP, in coordination are ambiguous between a conjunct and adjunct analysis. Furthermore, a claim made here is that the distinction between the sequential and non-sequential reading in Non-TP coordination is a distinction made by syntax, while the sequential vs. non-sequential reading in TP coordination is derived from semantics or pragmatics.

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국내 토양공정법과 산처리 방법의 비교: 최종 pH와 용출률의 관계

  • 이평구;최선규;오창환;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.46-51
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    • 2000
  • Environmental quality regulations are used to establish the maximum permissible concentrations of heavy metals before a site can be deemed to be polluted or contaminated. This paper compares the results obtained by 0.IN HCl extraction and acid extraction method(HNO$_3$+HClO$_4$.HCl). The leaching efficiency of 0.1N HCl extraction is directly proportional to the final pH of leachate, due to the different solubilities of the heavy metals at different pH values, The severe differences between 0.1N HCl-extractable and total metal contents result mainly from the buffering effect of carbonates, present in sediment. samples. Application of sequential extraction experiments to some sediments collected from gully pot in Seoul illustrates a much stronger scavenging effect by Fe and Mn-hydroxides, carbonates and organic phases. As deduced from both sequential extraction and leaching experiments, the relative mobility of heavy metals is found to be: Mn>Zn>>Co>Cd>>Cu>Pb>Cr>Fe, in spite of large differences in heavy metal content and localization. Changes in the physicochemical environments (such as acidification) caused by a traffic accident may result in the severe environmental pollution of heavy metals of surrounding area( surface water and rivers).

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FPGA-Based Hardware Accelerator for Feature Extraction in Automatic Speech Recognition

  • Choo, Chang;Chang, Young-Uk;Moon, Il-Young
    • Journal of information and communication convergence engineering
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    • v.13 no.3
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    • pp.145-151
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    • 2015
  • We describe in this paper a hardware-based improvement scheme of a real-time automatic speech recognition (ASR) system with respect to speed by designing a parallel feature extraction algorithm on a Field-Programmable Gate Array (FPGA). A computationally intensive block in the algorithm is identified implemented in hardware logic on the FPGA. One such block is mel-frequency cepstrum coefficient (MFCC) algorithm used for feature extraction process. We demonstrate that the FPGA platform may perform efficient feature extraction computation in the speech recognition system as compared to the generalpurpose CPU including the ARM processor. The Xilinx Zynq-7000 System on Chip (SoC) platform is used for the MFCC implementation. From this implementation described in this paper, we confirmed that the FPGA platform is approximately 500× faster than a sequential CPU implementation and 60× faster than a sequential ARM implementation. We thus verified that a parallelized and optimized MFCC architecture on the FPGA platform may significantly improve the execution time of an ASR system, compared to the CPU and ARM platforms.

Identification of Hydrophobic Components in Cambodian Kapok Fiber (캄보디아산 케이폭 섬유의 소수성에 영향을 미치는 성분규명)

  • Sung, Yong Joo;Yun, Su-Young;Oh, Sung-Hoon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.5
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    • pp.30-36
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    • 2013
  • Hydrophobic property of Kapok fiber was investigated by sequential removal of its components by different extraction methods. Acetone extraction for the removal of the hydrophobic extractives, holo-cel-lulose preparation after the removal of lignin and xylan extraction by potassium hydroxide was applied. The degree of hydrophobicity of each samples were measured by the water sorption ability. The water sorption ability of Kapok fiber was increased by the sequential treatment of acetone extraction, holocellulose preparation and xylan removal. Based on holocellulose compositional analysis by $^1H$-NMR spectroscopic method, the unusual high amount of the acetyl groups in the holocellulose of Kapok partially contributed to the hydrophobicity of Kapok holocellulose fiber.

Heavy metals leaching behavior and ecological risks in water and wastewater treatment sludges

  • Wuana, Raymond A.;Eneji, Ishaq S.;Ugwu, Ezekiel C.
    • Advances in environmental research
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    • v.6 no.4
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    • pp.281-299
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    • 2017
  • Single (0.005 M DTPA), sequential (six-step) and kinetic (0.05 M EDTA) extractions were performed to assess Cd, Cr, Cu, Ni, Pb, and Zn mobilization and their potential ecological risks in Abuja (Nigeria) water (WTS) and wastewater (WWTS) treatment sludges. Total metal levels (mg/kg) in WTS and WWTS, respectively were: Cd(3.67 and 5.03), Cr(5.70 and 9.03), Cu(183.59 and 231.53), Ni(1.33 and 3.23), Pb(13.43 and 17.87), Zn(243.45 and 421.29). DTPA furnished metal extraction yields (%) in WTS and WWTS, respectively as: Cd(11 and 6), Cr (15 and 7), Cu(17 and 13), Ni(23 and 3), Pb(11 and 12), and Zn(37 and 33). The metals were associated with the soluble/exchangeable, carbonate, Mn/Fe-oxide, organic matter and residual forms to varying degrees. Kinetic extractions cumulatively leached metal concentrations akin to the mobilizable fractions extracted sequentially and the leaching data fitted well into the Elovich model. Metal mobilities were concordant for the three leaching procedures and varied in the order:WTS>WWTS. Calculated ecological risk indices suggested moderate and considerable metal toxicity in WTS and WWTS, respectively with Cd as the worst culprit. The findings may be useful in predicting heavy metals bioavailability and risks in the sludges to guide their disposal and use in land applications.

Evaluation of Electrokinetic Removal of Heavy Metals from Tailing Soils

  • Kim, Soon-Oh;Kim, Kyoung-Woong;Yun, Seong-Taek
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.40-43
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    • 2002
  • Electrokinetic remediation was studied for the removal of toxic heavy metals from tailing soils. This study emphasized the dependency of removal efficiency upon heavy metal speciation, as demonstrated by different extraction methods (sequential extraction, total digestion, and 0.1 N HC1 extraction). The tailing soils examined showed different physicochemical characteristics, in view of initial pH, particle size distribution, and major mineral constituents, and contained high concentrations of target metal contaminants in various forms. The electrokinetic removal efficiency of heavy metals was significantly influenced by their partitioning prior to treatment, and by the pHs of the tailing soils. The mobile and weakly bound fractions of heavy metals, such as exchangeable fraction, were easily removed by electrokinetic treatment (more than 90% in removal efficiency), whereas immobile and strongly bound fractions, such as organically bound and residual fractions, were not effectively removed (less than 20% in removal efficiency).

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Comparative Investigation of the Contamination characteristics on As contaminated Sites (비소 오염지역의 오염특성 비교조사)

  • Yu, Chan;Yun, Sung-Wook;Baek, Seung-Hwan;Park, Jin-Chul;Lee, Jung-Hoon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1647-1654
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    • 2008
  • The characteristics of arsenic(As) contamination were investigated on soils of 3 abandoned metal mine sites in Gangwon-do, Korea. Total forty nine soils were sampled to conduct standard methods(extraction by 1HCl), sequential extraction and column leaching test. Concentration of As extracted by 1N HCl was ordered as follows: A mine > B mine > C mine, and the concentration of arsenic in the soils of A mine was significantly greater than that at any other cases and all samples of A mine were exceeded the national regulation of $6mg \;kg^{-1}$. In the results of sequential extraction, the potential contamination risk for groundwater and plants was ordered as follows: C mine > B mine > A mine because the C mine showed the relatively greater mobility and bioavailability of fraction than any other mines. And, in colume test, concentration of As was ordered as follows: C mine > B mine > A mine, and it was expected that these results were connected with fraction characteristics of the mine sites. Therefore adequate leaching investigations should be used to simulate the effect of natural leaching conditions, and to predict both the potential mobility of metals to groundwater and their bioavailability to plants under natural conditions.

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Sequential Extraction of Cd, Zn, Cu, and Pb from the Polluted Paddy Soils and Their Behavior (중금속 오염지 논토양의 Cd, Zn, Cu, Pb의 연속 침출 방법 비교와 연차적 오염도 변화)

  • Yoo, Sun-Ho;Lee, Jong-Ryul;Kim, Key-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.207-217
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    • 1995
  • Extracting efficiencies of seven extracting solutions currently employed in extracting heavy metals from soils were compared and the functional relationships among them were calculated by regression analysis for Cd, Zn, Cu, and Pb. Extracting solutions employed were 0.1M HCl, 0.1M $HNO_3$, 0.05M EDTA, 0.001M DTPA(pH 7.3), 1M $NH_4OAc$ (pH 7.0), 0.1M $NH_4Ox$, and 4M $HNO_3$ respectively. Soil samples were collected from rice paddy fields near old zinc mining sites and from rice paddy fields near agro-industry complexes. Soils sampled from old zinc mining sites were also extracted using a sequential extraction method. Extraction by 4M $HNO_3$ and sequential extraction were performed on the samples collected both in 1979 and in 1991 to investigate the change in content and in chemical form of heavy metals. Functional relationships among the extracting solutions were highly correlated for Cd and Zn, whereas those for Cu and Pb were not. The predominant chemical form of Cd. Zn, Cu, and Pb in soils from old zinc mining sites was found to be of sulfide/residue form. The exchangeable form of Cd, the organically bound form of Cu, and the carbonate form of Pb were relatively high, while the sulfide/residue form of Zn was very high(> 79%). Although transformation among the extracted forms was not clear during those 12 years, a decrease in total content of Cd, Zn, Cu, and Pb was clearly observed.

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