• Title/Summary/Keyword: Sequential Extraction

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Chemical Speciation of Arsenic in the Water System from Some Abandoned Au-Ag Mines in Korea (국내 폐금은광산 주변 수계내의 As의 화학적 특성)

  • 이지민;이진수;전효택
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.481-490
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    • 2003
  • The objectives of this study are (1) to determine the extent and degree of As contamination of the water and sediments influenced by mining activity of the abandoned Au-Ag mines, (2) to examine As speciation In contaminated water, (3) to monitor variation of As contamination in water system throughout the dry and wet seasons, and (4) to investigate the As chemical form in the sediments through the sequential extraction analyses. Natural water(mine water, surface water and groundwater) and sediments were collected in six abandoned Au-Ag mine(Au-bearing quartz veins) areas. The contamination level of As in mine water of the Dongil(524${\mu}m$/L) is more higher than the tolerance level(500 ${\mu}m$/L) for waste water of mine area in Korea. Elevated levels of As in stream water were also found in the Dongil(range of 63.7∼117.6 ${\mu}m$/L.) and Gubong(range of 56.1∼62.9 ${\mu}m$/L) mine areas. Arsenic contamination levels in groundwater used by drinking water were more significant in the Dongil(11.3∼63.5 ${\mu}m$/L), Okdong(0.2∼68.9 ${\mu}m$/L) and Gubong(2.0∼101.0${\mu}m$/L) mine areas. Arsenate[As(V), $H_2AsO_4^-$] is more dominant than arsenite[As(III), $H_3AsO_3$] in water system of the most mine areas. The concentration ratios of As(III) to As(total), however, extend to the 95% in stream water of the Okdong mine area and 70∼82% in groundwater of the Okdong and Dongjung mine areas. As a study of seasonal variation in the water system, relatively high levels of As from the dongil mine area were found in April rather than in September. Sequential extraction analysis showed that As was predominantly present as coprecipitated with Fe hydroxides from sediment samples of the Dongjung and Gubong mine(35.9∼40.5%), which indicates its possibility of re-extraction and inducing elevated contamination of As in the reductive condition. In sediments from the Dongil, Okdong and Hwachon mine area, high percentage(55.2∼83.4%) of As sulfide form was found.

A Study on the Remediation of Lead Contaminated Soil in a Clay Shooting Range with Soil Washing (토양세척법에 의한 클레이사격장 납 오염토양의 정화에 관한 연구)

  • Lee, In-Hwa;Seol, Myung-Soo
    • Journal of Soil and Groundwater Environment
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    • v.15 no.5
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    • pp.23-31
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    • 2010
  • For an efficient remediation of Pb-contaminated soil (S-1) in a clay shooting range, a soil washing test was performed with mineral acid, organic acid, chelating agent, and chloride. The Pb extraction efficiency of extractant (0.1 M) used in the washing test showed the order of HCl > $Na_2$-EDTA > NTA > DTPA > citric acid > malic acid > succinic acid > acetic acid > $CaCl_2$ > $MgCl_2$, for S-1 soil. As compared to initial Pb concentration, extraction efficiency by the concentration of extractant was 93.35%, 80.80%, 73.92%, and 24.57% in S-1 soil for HCl (0.5 M, pH 1.10), $Na_2$-EDTA (0.01 M, pH 3.99), citric acid (0.5 M, pH 1.27), and $MgCl_2$ (0.1 M, pH 8.82), respectively. S-1 soil had 56.83% of residue form and 43.17% of non-residue form (18.04% of exchangeable form), respectively. Although the concentrations of these fractions sharply decreased after HCl washing, since the exchangeable forms with relatively large mobility are still distributed as high as 18.78% (to Pb total content in residual soils) in S-1 soil, it is necessary to devise a proper management plan for residual soils after soil washing application.

Lead Stabilization in Soil Amended with Lime Waste: An Extended X-ray Absorption Fine Structure (EXAFS) Investigation

  • Lim, Jung Eun;Lee, Sang Soo;Yang, Jae E.;Ok, Yong Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.443-450
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    • 2014
  • To determine Pb species in soils following the immobilization process, sequential extraction has been used despite the possibility of overestimating Pb species from unintended reactions during chemical extraction. Meanwhile, the application of extended X-ray absorption fine structure (EXAFS) has been shown to provide a more precise result than chemical extraction. In this study, the immobilization of Pb in contaminated soils treated with liming materials such as oyster shell (OS) or eggshell (ES) was evaluated with thermodynamic modelling and EXAFS analysis. Thermodynamic modelling by visual MINTEQ predicted the precipitation of $Pb(OH)_2$ in OS and ES treated soils. In particular, the values of saturation index (SI) for $Pb(OH)_2$ in OS (SI=0.286) and ES (SI=0.453) treated soils were greater than in the control soil (SI=0.281). Linear combination fitting (LCF) analysis confirmed the presence of $C_{12}H_{10}O_{14}Pb_3$ (lead citrate, 44.7%) by citric acid from plant root, Pb-gibbsite (Pb adsorbed gibbsite, 26.4%), and Pb-kaolinite (Pb adsorbed kaolinite, 20.3%) in the control soil. On the other hand, $Pb(OH)_2$ (16.8%), Pb-gibbsite (39.3%), and Pb-kaolinite (25.6%) were observed in the OS treated soil and $Pb(OH)_2$ (55.2%) and Pb-gibbsite (33.8%) were also confirmed in the ES treated soil. Our results indicate that the treatment with OS and ES immobilizes Pb by adsorption of Pb onto the soil minerals as a result of the increase in soil negative charge and the formation of stable $Pb(OH)_2$ under high pH condition of soils.

Large-Scale Text Classification with Deep Neural Networks (깊은 신경망 기반 대용량 텍스트 데이터 분류 기술)

  • Jo, Hwiyeol;Kim, Jin-Hwa;Kim, Kyung-Min;Chang, Jeong-Ho;Eom, Jae-Hong;Zhang, Byoung-Tak
    • KIISE Transactions on Computing Practices
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    • v.23 no.5
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    • pp.322-327
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    • 2017
  • The classification problem in the field of Natural Language Processing has been studied for a long time. Continuing forward with our previous research, which classifies large-scale text using Convolutional Neural Networks (CNN), we implemented Recurrent Neural Networks (RNN), Long-Short Term Memory (LSTM) and Gated Recurrent Units (GRU). The experiment's result revealed that the performance of classification algorithms was Multinomial Naïve Bayesian Classifier < Support Vector Machine (SVM) < LSTM < CNN < GRU, in order. The result can be interpreted as follows: First, the result of CNN was better than LSTM. Therefore, the text classification problem might be related more to feature extraction problem than to natural language understanding problems. Second, judging from the results the GRU showed better performance in feature extraction than LSTM. Finally, the result that the GRU was better than CNN implies that text classification algorithms should consider feature extraction and sequential information. We presented the results of fine-tuning in deep neural networks to provide some intuition regard natural language processing to future researchers.

A Stereo Image Recognition-Based Method for measuring the volume of 3D Object (스테레오 영상 인식에 기반한 3D 물체의 부피계측방법)

  • Jeong, Yun-Su;Lee, Hae-Won;Kim, Jin-Seok;Won, Jong-Un
    • The KIPS Transactions:PartB
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    • v.9B no.2
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    • pp.237-244
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    • 2002
  • In this paper, we propose a stereo image recognition-based method for measuring the volume of the rectangular parallelepiped. The method measures the volume from two images captured with two CCD (charge coupled device) cameras by sequential processes such as ROI (region of interest) extraction, feature extraction, and stereo matching-based vortex recognition. The proposed method makes it possible to measure the volume of the 3D object at high speed because only a few features are used in the process of stereo matching. From experimental results, it is demonstrated that this method is very effective for measuring the volume of the rectangular parallelepiped at high speed.

Stabilization of Heavy Metals in Contaminated Marine Sediment using Bentonite (벤토나이트에 의한 해양오염퇴적물 내 중금속 안정화 특성)

  • Shin, Woo-Seok;Na, Kyu-Ri;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.38 no.6
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    • pp.655-661
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    • 2014
  • In this study, stabilization treatment of heavy metals such as Ni, Cu, Pb, and Zn in contaminated marine sediment was achieved using bentonite. Stabilization experiment was accomplished by wet-curing with bentonite for 150 days. From the sequential extraction results of heavy metals, it was observed that the easily extractable fraction (exchangeable, carbonate, and oxides forms) of Ni, Cu, Pb, and Zn in a treated sediment decreased to 8.5%, 5.6%, 19.2%, and 28.2%, respectively, compared with untreated sediment. Moreover, the TCLP(Toxicity Characteristic Leaching Procedure) results evaluating efficiency of extraction reduction of heavy metals showed that extraction of heavy metals reduced drastically to 95.7%, 96.8%, 99.2%, 85.9% for Ni, Cu, Pb, and Zn by stabilization when compared to untreated sediment. From these results, we can confirm that bentonite as a capping material exhibits good stabilization of heavy metals in contaminated marine sediment.

Feature Extraction of Welds from Industrial Computed Radiography Using Image Analysis and Local Statistic Line-Clustering (산업용 CR 영상분석과 국부확률 선군집화에 의한 용접특징추출)

  • Hwang, Jung-Won;Hwang, Jae-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.45 no.5
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    • pp.103-110
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    • 2008
  • A reliable extraction of welded area is the precedent task before the detection of weld defects in industrial radiography. This paper describes an attempt to detect and extract the welded features of steel tubes from the computed radiography(CR) images. The statistical properties are first analyzed on over 160 sample radiographic images which represent either weld or non-weld area to identify the differences between them. The analysis is then proceeded by pattern classification to determine the clustering parameters. These parameters are the width, the functional match, and continuity. The observed weld image is processed line by line to calculate these parameters for each flexible moving window in line image pixel set. The local statistic line-clustering method is used as the classifier to recognize each window data as weld or non-weld cluster. The sequential procedure is to track the edge lines between two distinct regions by iterative calculation of threshold, and it results in extracting the weld feature. Our methodology is concluded to be effective after experiment with CR weld images.

Improvement of protein extraction efficiency from defatted sesame meal with thermal and enzymatic treatments (열 처리와 효소 처리에 의한 탈지 참깨박 단백질의 추출율 향상)

  • In, Man-Jin
    • Journal of Applied Biological Chemistry
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    • v.63 no.4
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    • pp.291-295
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    • 2020
  • In order to increase the utilization of defatted sesame meal (DSM), a by-product of sesame oil production, the conditions of extraction of insoluble proteins from DSM by enzyme treatment were investigated. As a result of comparing the treatment results of proteolytic enzymes Alcalase, Flavorzyme, Neutrase, and Protamex with control, Protamex was effective in increasing the total solid and protein content. At the reaction conditions of Protamex (50 ℃, pH 6.0), the dosage of enzymes was appropriate for 1% of DSM and 3 h of enzyme reaction time. To improve the efficiency of enzymatic treatment, the protein content extracted increased as the heat treatment temperature increased, and slightly increased above 110 ℃. As a result of investigating the effect of the combination treatment of cell lytic enzyme (Tunicase) and protease (Protamex) on protein solubilization, it was most effective to treat the cell lytic enzyme after processing the protease. After heat treatment (110 ℃, 10 min), sequential treatment of Protamex and Tunicase increased the protein content by about 3.5 times (9.85→35.58 mg/mL) of the non-heated control and 2.2 times (15.83→35.58 mg/mL) of the heat treated control.

Mining Maximal Frequent Contiguous Sequences in Biological Data Sequences (생물학적 데이터 서열들에서 빈번한 최대길이 연속 서열 마이닝)

  • Kang, Tae-Ho;Yoo, Jae-Soo
    • The KIPS Transactions:PartD
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    • v.15D no.2
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    • pp.155-162
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    • 2008
  • Biological sequences such as DNA sequences and amino acid sequences typically contain a large number of items. They have contiguous sequences that ordinarily consist of hundreds of frequent items. In biological sequences analysis(BSA), a frequent contiguous sequence search is one of the most important operations. Many studies have been done for mining sequential patterns efficiently. Most of the existing methods for mining sequential patterns are based on the Apriori algorithm. In particular, the prefixSpan algorithm is one of the most efficient sequential pattern mining schemes based on the Apriori algorithm. However, since the algorithm expands the sequential patterns from frequent patterns with length-1, it is not suitable for biological dataset with long frequent contiguous sequences. In recent years, the MacosVSpan algorithm was proposed based on the idea of the prefixSpan algorithm to significantly reduce its recursive process. However, the algorithm is still inefficient for mining frequent contiguous sequences from long biological data sequences. In this paper, we propose an efficient method to mine maximal frequent contiguous sequences in large biological data sequences by constructing the spanning tree with the fixed length. To verify the superiority of the proposed method, we perform experiments in various environments. As the result, the experiments show that the proposed method is much more efficient than MacosVSpan in terms of retrieval performance.

Characterization of Heavy Metal-enriched Particles from Contaminated Soils in a Military Shooting Range (군사격장 오염토양 내 고농도 중금속함유 입자의 기초특성연구)

  • Kim, Jeeeun;Kim, Jeongjin;Bae, Bumhan;Kim, Younghun
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.11
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    • pp.25-31
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    • 2013
  • Civil and military firing ranges are usually contaminated with heavy metals such as lead and copper and remediation is required. Acid washing and extraction are common remediation methods. Lead contaminated firing range soil samples were collected and a preliminary study was conducted to evaluate the characteristics of the contamination and the contribution of high specific gravity particles. Ethylenediamine tetra acetic acid(EDTA) extraction was applied for the removal of heavy metal but the extraction was not feasible for the firing range soil. Even after the repeated EDTA extraction, the contamination were still over the Korean environmental standard indicating that soil particles highly contaminated with heavy metal which release the heavy metal ion even after the repeated extraction. Some colored and higher specific gravity particles were separated from the soil samples and analyzed. The colored particles have specific gravity of 2.5-6.6. The saturation ratio of Pb and EDTA was 4.9-32%. After removal of these colored particles, the sandy soil showed moderate contamination which can be treated with soil washing. This was proved with the five-level sequential extraction and TCLP tests.