• Title/Summary/Keyword: Separators

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Current Status and Future Research Directions of Separator Membranes for Lithium-Ion Rechargeable Batteries (리튬이차전지용 분리막 이해 및 최신 연구 동향)

  • Kim, Jung-Hwan;Lee, Sang-Young
    • Membrane Journal
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    • v.26 no.5
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    • pp.337-350
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    • 2016
  • Lithium-ion rechargeable batteries (LIBs) have garnered increasing attention with the rapid advancements in portable electronics, electric vehicles, and grid-scale energy storage systems which are expected to drastically change our future lives. This review describes a separator membrane, one of the key components in LIBs, in terms of porous structure and physicochemical properties, and its recent development trends are followed. The separator membrane is a kind of porous membrane that is positioned between a cathode and an anode. Its major functions involve electrical isolation between the electrodes while serving as an ionic transport channel that is filled with liquid electrolyte. The separator membranes are not directly involved in redox reactions of LIBs, however, their aforementioned roles significantly affect performance and safety of LIBs. A variety of research approaches have been recently conducted in separator membranes in order to further reinforce battery safeties and also widen chemical functionalities. This review starts with introduction to commercial polyolefin separators that are currently most widely used in LIBs. Based on this understanding, modified polyolefin separators, nonwoven separators, ceramic composite separators, and chemically active separators will be described, with special attention to their relationship with future research directions of advanced LIBs.

Separation of Blood Cell and Blood Plasma Using Microstructure (미세구조물을 이용한 혈구/혈장 분리)

  • Kim, Duckiong;Seo, Jee-Hoon;Son, Sang Uk;Kim, Jae Yun;Yoon, Eui Soo
    • 유체기계공업학회:학술대회논문집
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    • 2004.12a
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    • pp.743-747
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    • 2004
  • In this study, micro blood separators capable of separating blood cell and blood plasma using microstructure are fabricated and their feasibility and separation performance are evaluated. Test results show the possibility of separating blood cell and blood plasma using microstructure. To improve separation performance and anti-clogging characteristic, technical points of tested micro blood separators are discussed and improved designs are presented.

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Simplified Process for Passive Matrix OLEDs

  • Lee, Seung-Jun;Sin, Yun-Su;Im, Dae-U;Yu, Jae-Hun;Choe, Gyeong-Hui
    • Proceedings of the Optical Society of Korea Conference
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    • 2008.02a
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    • pp.397-398
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    • 2008
  • We have developed simplified processes for the formation of insulators, cathode separators and bus electrodes in PMOLEDs. The insulators and cathode separators are patterned simultaneously by a single layer of image reversal photoresist. And, the bus electrodes of low resistance are formed by the cathode separator and cathode metal. Using these simplified processes, we fabricated 1.17" $96{\times}RGB{\times}96$ panels and analyzed their performance and reliability.

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Preparation and Characterization of Sulfonated Poly (Arylene Ether Sulfone) Random Copolymer-Polyolefin Pore-filling Separators with Metal Ion Trap Capability for Li-ion Secondary Battery (리튬이온 이차전지용 금속이온 선택성 술폰화 폴리아릴렌에테르술폰 공중합체-폴리올레핀 함침격리막 제조 및 특성)

  • Jeong, Yeon Tae;Ahn, Juhee;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.4
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    • pp.310-317
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    • 2016
  • Lithium ion secondary battery (LISB) is an energy conversion system operated via charging-discharging cycle based on Lithium ion migration. LISB has a lot of advantages such as high energy density, low self-discharge rate, and a relatively high lifetime. Recently, increasing demands of electric vehicles have been encouraging the development of LISB with high capacity. Unfortunately, it causes some critical safety issues. It includes dendrite formation on negative electrode, resulting in electric shortage problems and battery explosion. Also, the elevated temperatures occurred during the LISB operation induces thermal shrinkage of polyolefin (e.g., polyethylene and polypropylene) separators. Consequently, the low thermal stability leads to decay of LISB performances and the reduction of lifetime. In this study, sulfonated poly (arylene ether sulfone) (SPAES) random copolymers were used as key materials to prepare polyolefin pore-filling separator. The resulting separators were evaluated in the term of metal ion chelation capability associated with dendrite formation, $Li^+$ ion conductivity and thermal durability.

Application and Type of Magnetic Separator (자력선별장비의 유형과 활용)

  • Lee, Sang-hun;Yang, Injae;Choi, Seungjin;Park, Jayhyun
    • Resources Recycling
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    • v.27 no.6
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    • pp.11-22
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    • 2018
  • Magnetic separators has been used in the mining and the recycling fields in general, and is still applied in wide variety of fields. It is classified into the equipments for separating coarse ferrous scrap from non-ferrous materials and the equipments for concentrating fine ferromagnetic particles below 3mm. Magnetic separation equipments for concentrating fine materials also falls into two categories of low intensity and high intensity magnetic separators. The former is used for ferromagnetic materials but also paramagnetic materials of high magnetic susceptibility, and the latter for paramagnetic materials of lower magnetic susceptibility. Both low and high intensity magnetic separators could be utilized either dry and wet. Recently, the High gradient magnetic separators(HGMS) used in the range of less than 0.7 tesla has been gradually replaced by the magnetic separator made of rare earth permanent magnets commercialized in the 1980s. In addition, the expansion of nanotechnology in terms of synthetic magnetic materials in the environmental and biological fields is expected to contribute positively to the development of magnetic separation technology.

Pulsating fluid induced dynamic stability of embedded viscoelastic piezoelectric separators using different cylindrical shell theories

  • Pour, H. Rahimi;Arani, A. Ghorbanpour;Sheikhzadeh, Gh.
    • Steel and Composite Structures
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    • v.24 no.4
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    • pp.499-512
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    • 2017
  • This paper deals with nonlinear dynamic stability of embedded piezoelectric nano-composite separators conveying pulsating fluid. For presenting a realistic model, the material properties of structure are assumed viscoelastic based on Kelvin-Voigt model. The separator is reinforced with single-walled carbon nanotubes (SWCNTs) which the equivalent material properties are obtained by mixture rule. The separator is surrounded by elastic medium modeled by nonlinear orthotropic visco Pasternak foundation. The separator is subjected to 3D electric and 2D magnetic fields. For mathematical modeling of structure, three theories of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT) are applied. The differential quadrature method (DQM) in conjunction with Bolotin method is employed for calculating the dynamic instability region (DIR). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the dynamic instability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that the magnetic and electric fields as well as SWCNTs as reinforcer are very important in dynamic instability analysis of structure.

Comparison of different cylindrical shell theories for stability of nanocomposite piezoelectric separators containing rotating fluid considering structural damping

  • Pour, H. Rahimi;Arani, A. Ghorbanpour;Sheikhzadeh, G.A.
    • Steel and Composite Structures
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    • v.23 no.6
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    • pp.691-714
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    • 2017
  • Rotating fluid induced vibration and instability of embedded piezoelectric nano-composite separators subjected to magnetic and electric fields is the main contribution of present work. The separator is modeled with cylindrical shell element and the structural damping effects are considered by Kelvin-Voigt model. Single-walled carbon nanotubes (SWCNTs) are used as reinforcement and effective material properties are obtained by mixture rule. The perturbation velocity potential in conjunction with the linearized Bernoulli formula is used for describing the rotating fluid motion. The orthotropic surrounding elastic medium is considered by spring, damper and shear constants. The governing equations are derived on the bases of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT). The nonlinear frequency and critical angular fluid velocity are calculated by differential quadrature method (DQM). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the stability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that with increasing volume fraction of SWCNTs, the frequency and critical angular fluid velocity are increased.

Development of a prediction model relating the two-phase pressure drop in a moisture separator using an air/water test facility

  • Kim, Kihwan;Lee, Jae bong;Kim, Woo-Shik;Choi, Hae-seob;Kim, Jong-In
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.3892-3901
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    • 2021
  • The pressure drop of a moisture separator in a steam generator is the important design parameter to ensure the successful performance of a nuclear power plant. The moisture separators have a wide range of operating conditions based on the arrangement of them. The prediction of the pressure drop in a moisture separator is challenging due to the complexity of the multi-dimensional two-phase vortex flow. In this study, the moisture separator test facility using the air/water two-phase flow was used to predict the pressure drop of a moisture separator in a Korean OPR-1000 reactor. The prototypical steam/water two-phase flow conditions in a steam generator were simulated as air/water two-phase flow conditions by preserving the centrifugal force and vapor quality. A series of experiments were carried out to investigate the effect of hydraulic characteristics such as the quality and liquid mass flux on the two-phase pressure drop. A new prediction model based on the scaling law was suggested and validated experimentally using the full and half scale of separators. The suggested prediction model showed good agreement with the steam/water experimental results, and it can be extended to predict the steam/water two-phase pressure drop for moisture separators.

Advances in Highly Selective Materials for the Separation of Oil-Water (고선택성 유수분리 소재 기술)

  • Uhm, Sunghyun;Choi, Kwang-Soon;Lee, Donghun
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.141-144
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    • 2019
  • Oil-water separators are commonly used in the oily wastewater treatment for the reuse of water resources. Recently, various approaches have been conducted to design and manipulate the oil-water separator installed with highly functionalized membranes. Membrane technologies should encompass the selectivity, durability, economics and processability of materials, and effective oil water separators be also developed to exhibit the optimal performance of the materials. In this mini-review, we highlight the large scale fabrication of membrane materials and the effective design of oil water separators.

Improving the Cycle Performance of Li Metal Secondary Batteries Using Three-Dimensional Porous Ag/VGCF-Coated Separators (3D 다공성 구조의 Ag-VGCF 코팅 분리막을 이용한 리튬금속 이차전지 수명향상)

  • Beom-Hui Lee;Dong-Wan Ham;Ssendagire Kennedy;Jeong-Tae Kim;Sun-Yul Ryou
    • Journal of the Korean Electrochemical Society
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    • v.27 no.3
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    • pp.88-96
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    • 2024
  • Lithium metal has garnered attention as a promising anode active material thanks to its high specific capacity, energy density, and the lowest reduction potential. However, the formation of dendrites, dendritic crystals that arise during the charge and discharge process, has posed safety and lifetime stability challenges. To resolve this, our study has introduced a novel separator design. This separator features a composite coating of vapor-grown carbon fiber, a conductive material in nanofibers, and silver. We have meticulously studied the impact of this innovative separator on the electrochemical properties of the lithium metal anode, unveiling promising results. To confirm the synergistic effect of VGCF and Ag, a separator with no surface treatment and a separator with only VGCF coated on one side were prepared and compared with the Ag-VGCF-separator. In the case of the bare separator, the Li metal surface is covered with dendrites during the initial charge and discharge process. In contrast, both the VGCF-separator and the Ag-VGCF-separator show Li precipitation inside the conductive coating layer coated on the separator surface. Additionally, the Ag-VGCF-separator showed a more uniform precipitate shape than the VGCF-separator. As a result, the Ag-VGCF-separators show improved electrochemical properties compared to the bare separators and the VGCF-separators.