• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.1.1-1.1
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• 2011

Electrospinning has known to be very effective tool for production of versatile one-dimensional (1D) nanostructured materials such as nanofibers, nanorod, and nanotubes and for easily assembly to two-, three-dimensional(2D, 3D) nanostructures such as thin film, membrane, and nonwoven web, etc. We have studied on the electrospinning technology for novel energy storage and conversion materials such as advanced separator, dye sensitized solar cell, supercapacitor, etc. High heat-resistive nanofibrous membrane as a new separator for future lithium ion polymer battery was prepared by electrospinning of PVdF based composite solution. The novel nanofibrous composite nonwovens have tensile strength of above 50 MPa and modulus of above 1.3 GPa. The internal structure of the electrospun composite nanofiber with a diameter of few hundreds nanometer were composed of core-shell nanostructure. And also electrospun $TiO_2$ nanorod/nanosphere based dye-sensitized solar cells with high efficiency are successfully prepared. Some battery performance will be introduced.

• Journal of Powder Materials
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• v.17 no.2
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• pp.123-129
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• 2010

The fabrication of interconnect from titanium powders and $TiN_x$ powders is investigated. Corrosion-resistant titanium and $TiN_x$ are used as reinforcement in order to reveal high heat and corrosion resistance at the elevated temperature. We fabricated the plates for interconnect reinforced with $TiN_x$ by mixing titanium powders with 10 wt.% of nano-sized $TiN_x$. Spark Plasma Sintering (SPS) was chosen for the sintering of these composites. The plate made of titanium powders and $TiN_x$ powders demonstrates higher corrosion resistance than that of the plate of titanium powders alone. The physical properties of specimens were analyzed by performing hardness test and biaxial strength test. The electrochemical properties, such as corrosion resistance and hydrogen permeability at high temperature, were also investigated. The microstructures of the specimens were investigated by FESEM and profiles of chemical compositions were analyzed by EDX.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.4 no.2
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• pp.50-56
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• 2008

The tubes in heat exchanger are typically made of copper alloy, stainless steel, carbon steel, titanium alloy material. Type-439 ferritic stainless steel is ferromagnetic material, and furnish higher heat transfer rates than austenitic stainless steels and higher resistance to corrosion-induced flaws. Ferritic stainless steel can be found in low-pressure(LP) feedwater heaters and moisture separator reheaters(MSRs) in turbine system. LP feedwater heaters generally utilize thin wall Type-439 stainless steel tubing, whereas MSRs typically employ a heavier wall tubing with integral fins. Service-induced damage can occur on the O.D(outside diameter) surface of Type-439 ferritic stainless steel tubing which is employed for MSRs tubing, and the most typical damage mechanism is vibration-induced tube-to-TSP(tube support plate) wear and fatigue cracking. The wear has been reported that occurs mainly on the OD surface. Accordingly, in this study, we have evaluated the flaw sizing capability of magnetic saturation eddy current technique using magnetic saturation probe and flawed specimen.

• Journal of the Korean Electrochemical Society
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• v.3 no.3
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• pp.136-140
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• 2000

A stainless steel separator for a molten carbonate fuel cell is usually coated with aluminum diffusive layer to protect its surface against corrosion by the molten carbonate at high temperatures. In this study, a relatively simple method was devised to form the aluminum diffusive layer on a stainless steel substrate. Slurry coating of aluminum on the substrate followed by heat treatment under reducing atmosphere at $650\~800^{\circ}C$ produced the aluminum diffusive layer of $25\~80{\mu}m$ thickness. The thickness of aluminum diffusive layer increased with increasing the temperature or duration of the heat-treatment. The corrosion resistance against molten carbonate under oxidizing atmosphere was significantly improved by aluminum diffusive layer formed by the sluny painting and heat treatment method. Moreover, the sample prepared in this study showed corrosion behavior similar to the sample with aluminum diffusive layer prepared by ion vapor deposition and heat treatment.

• Korean Journal of Materials Research
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• v.7 no.1
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• pp.76-80
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• 1997

'4 NiAl coating process was applied on 316 stainless steel to retard the corrosion of the wet- seal area of separator for the molten carbonate fuel cell. The Nit11 phasc on the stainless steel substrate could be formed by pre-coating with Ni, plated with A1 and ther, heat treated at $800^{\circ}C$ for 3 hr in $H_2/N_2$ gas atmosphere. The corrosion protection behavior of YiAl coating layer was stuilied under immersion condition in molten cxhonate salt($62^{m}/_{o}Li_2CO_3-38^{m}/_{o}/K_{2}CO_{3}$) at $650^{\circ}C$. The NiAl coating layer ticposited on the AiSi 316 stainless steel had high corrosion resistance in molten carbor. dte salt. The corrosion resistance of XiAl (~~jpoared to be associated with the .A1 oxide formed on the surface of coating layer.

• Transactions of Materials Processing
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• v.20 no.3
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• pp.193-205
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• 2011

Because of its rustproof property, stainless steel is widely used in kitchen appliances, building materials, electronics, chemical plants and automobile exhausts. In addition, the utilization of stainless steel for fuel cell application is growing. As the demand for this material increases, it is necessary to study the basic properties of stainless steel such as corrosion resistance, heat transfer, formability, cutting or shearing ability and weldability. In this article, the mechanical properties, formability and press forming performance of stainless steel are reviewed. Since temperature and strain rate affect the press forming performance of STS304(austenitic) stainless steel, the influence of these parameters on the plastic behavior should be investigated. Moreover, measures for the prevention of ridging of STS430(ferritic) and delayed fracture of STS430, which respectively appear during and after press forming, should be considered. Recently, stainless steel sheets with a thickness lower than 0.2 mm have been widely used in applications for mobile phone, digital camera and fuel cell separator. Therefore, there is a growing interest of studying the grain size effect and plasticity at the crystal scale in order to understand the anisotropic behavior and micro forming ability of thin sheets. This review paper was written with the objective of helping engineers and researchers to understand the forming characteristics of stainless steel and to establish standards in plastic forming techniques.

• Journal of the Korean Society for Nondestructive Testing
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• v.28 no.5
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• pp.407-415
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• 2008

The tubes in heat exchanger are typically made from copper alloy, stainless steel, carbon steel, titanium alloy material. type-439 ferritic stainless steel is ferromagnetic material, and furnish higher heat transfer rates than austenitic stainless steels and higher resistance to corrosion-induced flaws. Ferritic stainless steel can typically be found in low-pressure(LP) feedwater heaters and moisture separator reheaters(MSRs). LP feedwater heaters generally utilize thin wall type-439 stainless steel tubing, whereas MSRs typically employ a heavier wall tubing with integral fins. Service-induced damage can occur on the OD(outside diameter) surface of type-439 ferritic stainless steel tubing which is employed for MSRs tubing, and the most typical damage mechanism is vibration-induced tube-to-TSP(tube support plate) wear and fatigue cracking. The wear has been reported that occurs mainly on the OD surface. Accordingly, in this study, we have evaluated the flaw sizing capability of magnetic saturation eddy current technique using magnetic saturation probe and flawed specimen.