• Title/Summary/Keyword: Separation condition

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Effect of Pressure on HCl Absorption Behaviors of a K-based Absorbent in the Fixed Bed Reactor (고정층 반응기에서 K-계열 흡수제의 압력에 따른 HCl 흡수 거동 연구)

  • Kim, Jae-Young;Park, Young Cheol;Jo, Sung-Ho;Ryu, Ho-Jung;Baek, Jeom-In;Park, Yeong Seong;Moon, Jong-Ho
    • Clean Technology
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    • v.19 no.2
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    • pp.165-172
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    • 2013
  • In this study, the hydrogen chloride removal using K-based dry sorbents ($K_2CO_3/Al_2O_3$, KEPRI, Korea) was studied with varying the pressure in a fixed bed reactor (15 cm tall bed with 0.5 cm I.d.). Working temperature was $400^{\circ}C$ and feed gas concentration was 750 ppm (HCl vol%, $N_2$ balance). The chloride sorption capacity of sorbent increases with increasing pressure (1, 5, 10, 15 and 20 bar). Also, after forming KCl crystal by reaction with $K_2CO_3$ and HCl, owing to the strong bonding energy, sorbent regeneration was practically impossible. Its optical, physical and chemical characterizations were evaluated by SEM, EDAX, BET, TGA and XRD. At $400^{\circ}C$ and 20 bar condition, working condition for the dehalogenation process after gasification, K-based dry sorbent showed high HCl sorption capacity and HCl/$N_2$ separation performances comparing with Ca-based and Mg-based dry sorbents.

Optimal Condition of Microporous Membrane for Bone Marrow Stromal Cell Allotransplantation to Stimulate Wound Healing in Vitro (창상치유목적의 골수기질세포 동종이식을 위한 고분자막의 조건)

  • Lee, Eun-Sang;Kim, Myeong-Joo;Han, Seung-Kyu;Hong, Sung-Taek;Kim, Woo-Kyung
    • Archives of Plastic Surgery
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    • v.37 no.5
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    • pp.509-518
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    • 2010
  • Purpose: Major drawbacks of conventional bone marrow stromal cells (BSCs) transplantation method are mainly caused by direct transplanted cell to host cell interactions. We hypothesized that separation of the transplanted cells by a microporous membrane might inhibit most of the potential adverse effects and induce superior effect. The purpose of the study is to determine the optimal condition of the microporous membrane. Methods: First, BSCs were placed in polyethylene terephthalate (PET) transwell inserts with 3, 8, or $12{\mu}m$ pore size, and cultured in 24 well culture plates. After 5 days, bottoms of the plates were observed for presence of attached BSCs in monolayer and cell numbers were evaluated. Second, BSCs were placed PET, polycarbonate (PCT), and mixed cellulose esters (MCE) transwell inserts with 3 and $8{\mu}m$ pore size, and cultured in 24 well culture plates. After 3 days, the supernatants of the media left in culture plate were analyzed for collagen, vascular endothelial growth factor (VEGF), platelet derived growth factor BB (PDGF-BB), and basic fibroblast growth factor (bFGF). Third, BSCs were placed in 15% and 70% of the PET membrane with $3{\mu}m$ pore size. All the experimental conditions and methods were same as the second study. Results: The optimal pore sizes to prevent BSC leakage were $3{\mu}m$ and $8{\mu}m$. The amounts of type I collagen and three growth factors tested did not show significant differences among PET, PCT, and MCE groups. However, the collagen, VEGF, and bFGF levels were much higher in the high (70%) density group than in the low (15%) density group. Conclusion: This study revealed that the optimal pore size of membrane to prevent direct BSC to recipient cell contact is in between $3{\mu}m$ and $8{\mu}m$. Membrane materials and pore sizes do not influence the collagen and growth factor passage through the membrane. The most striking factor for collagen and growth factor transport is pore density of the membrane.

Adsorption/Desorption Characteristics of Vanadium from Ammonium Metavanadate using Anion Exchange Resin (음(陰)이온교환수지(交換樹脂)를 이용한 Ammonium Metavanadate로부터 바나듐 흡탈착(吸脫着) 특성(特性))

  • Jeon, Jong Hyuk;Kim, Young Hun;Hwang, In Sung;Lee, Jin Young;Kim, Joon Soo;Han, Choon
    • Resources Recycling
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    • v.22 no.1
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    • pp.55-63
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    • 2013
  • Considering considerable contents of vanadium and tungsten in spent SCR DeNOx catalysts, separation and recovery of those metals are required. In this respect, commercial anion exchange resin (MP600) was employed to recover vanadium from the synthetic solution of ammonium metavanadate. Experimental results indicated that vanadium exist as anion under the acidic condition (pH 2 ~ 6) and adsorbed on the resin. Although the adsorption rate was increased with temperature, the maximum amount of adsorption was not affected by temperature. Desorption took place under either strong acidic (less than pH 1) or strong caustic (higher than pH 13) condition. However, desorption seldom took place under moderate conditions (pH 3~11). Furthermore, adsorption equilibrium results agreed well with Freundlich isotherm and pseudo-second-order reactions. And, adsorption energy was evaluated using Dubinin-Radushkevich and Temkin isotherm.

Reproduction of Ocean Circulation around Korean Peninsula by using a Mesoscale Ocean Circulation Model (중규모 해양모형을 이용한 한반도 주변 해역 해양순환 재현)

  • Lee, Hae-Jin;Ahn, Joong-Bae
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.3
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    • pp.186-194
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    • 2000
  • In this study, the oceanic responses to given atmospheric boundary conditions are investigated using a mesoscale ocean circulation model. The numerical experiments are divided into two parts: One is, so called, spin-up experiment and the other is reproduction experiment. The spin-up experiment simulates climatic state of ocean by integrating the ocean model with upper boundary conditions of the monthly mean atmospheric climate data. In the reproduction experiment, for the reproduction of major oceanic changes around Korean Peninsula during the period of 1980-1998 (19 years), the model has been integrated under the boundary condition of the 19year monthly mean atmosphere data. The spined-up state of ocean generated from the spin-up experiment is assigned to the initial boundary condition of the reproduction experiment. In the spin-up experiment, the model properly simulates the major features of circulation structure around Korean Peninsula; such as separation of East Korean Warm Current (EKWC), formation of the polar front, cold water band associated with the small scale eddies in the East Sea, the formation of front along west coast, and the seasonal variation of circulation pattern caused by changing upwind current in the West Sea. In the reproduction experiment, the model has shown the interannual sea surface temperature variations and a warming trend of about 0.5$^{\circ}$C during the period around Korean Peninsula, as in the case of the observation. Therefore, it is concluded that the model is capable of simulating not only the mean states but also the variabilities of ocean under the given atmosphere boundary conditions.

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A New Integral Variable Structure Regulation Controller for Robot Manipulators with Accurately Predetermined Output Performance (로봇 매니플레이터를 위한 정확한 사전 결정 출력 성능을 갖는 새로운 적분 가변구조 레귤레이션 제어기)

  • Lee, Jung-Hoon
    • Journal of IKEEE
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    • v.8 no.1 s.14
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    • pp.96-107
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    • 2004
  • In this paper, a new integral variable structure regulation controller(IVSRC) is designed by using a special integral sliding surface and a disturbance observer for the improved regulation control of highly nonlinear robot manipulators with prescribed output performance. The sliding surface having the integral state with a special initial condition is employed in this paper to exactly predetermine the ideal sliding trajectory from a given initial condition to origin without any reaching phase. And a continuous sliding mode input using the disturbance observer is also introduced in oder to effectively follow the predetermined sliding trajectory within the prescribed accuracy without large computation burden. The performance of the prescribed tracking accuracy to the predetermined sliding trajectory is clearly investigated in detail through the two theorems together with the closed loop stability. The design of the proposed IVSRC is separated into the performance design and robustness design in each independent link. The usefulness of the algorithm has been demonstrated through simulation studies on the regulation control of a two link manipulator under parameter uncertainties and payload variations, in view of no reaching phase, no overshoot, predetermined response with prescribed accuracy, easy change of output performance, separation of design phase, and so on.

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The Evolution of Economic Structure and the Locational Characteristics of Enterprises in Border Region of Gyeonggi Province (경기도 접경지역의 경제구조변화와 기업의 입지특성)

  • 이현주;이승헌
    • Journal of the Economic Geographical Society of Korea
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    • v.7 no.2
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    • pp.203-225
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    • 2004
  • The purpose of this paper analyzes the characteristics of economic space in Gyeonggi border regions. Especially, this study focuses on understanding the environment enveloped the enterprises because today, largely influenced factor for regional economic development is enterprises. Since 1990's the change of the spacial organization in Korean Capital region has been inducing the functional transformation in Gyeonggi border regions so that new function -beyond military functions- is developed in these regions. By the disindustrialization in core region contributed to the industrialization in periphery, border regions are developed as a concentrated space of traditional industries and small size manufactural firms. The most important pull factor is facility for obtain a factory site and favorable condition of land price. Globally, the reasons to locate enterprise in these regions are found not in positive and progressive strategies but in passive and defensive strategies. Therefore few enterprise carried about influences of economic cooperation between North and South Korea at the moment of decision of their site. The survey reveal that enterprises didn't highly estimate the environment in border regions as their business activities. The first dissatisfied condition is insufficiency of labour and difficulty of access for administrative and high level services, due to geographical separation. Considering the recent tendency of spacial reorganization in Capital region is not always good for border regions, border regions have to employ a policy with the object of ameliorating regional business environments and growing up a potentiality of endogenous development.

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Performance Analysis of Shell Coal Gasification Combined Cycle systems (Shell 석탄가스화 복합발전 시스템의 성능해석 연구)

  • Kim, Jong-Jin;Park, Moung-Ho;Song, Kyu-So;Cho, Sang-Ki;Seo, Seok-Bin;Kim, Chong-Young
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.104-113
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    • 1997
  • This study aims to develop an analysis model using a commercial process simulator-ASPEN PLUS for an IGCC (Integrated Gasification Combined Cycle) system consisting a dry coal feeding, oxygen-blown entrained gasification process by Shell, a low temperature gas clean up process, a General Electric MS7001FA gas turbine, a three pressure, natural recirculation heat recovery steam generator, a regenerative, condensing steam turbine and a cryogenic air separation unit. The comparison between those results of this study and reference one done by other engineer at design conditions shows consistency which means the soundness of this model. The greater moisture contents in Illinois#6 coal causes decreasing gasifier temperature and the greater ash and sulfur content hurt system efficiency due to increased heat loss. As the results of sensitivity analysis using developed model for the parameters of gasifier operating pressure, steam/coal ratio and oxygen/coal ratio, the gasifier temperature increases while combustible gases (CO+H2) decreases throughout the pressure going up. In the steam/coal ratio analysis, when the feeding steam increases the maximum combustible gas generation point moves to lower oxygen/coal ratio feeding condition. Finally, for the oxygen/coal ratio analysis, it shows oxygen/coal ratio 0.77 as a optimum operating condition at steam/coal feeding ratio 0.2.

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A Study on the Improving Speech Intelligibility of Emergency Broadcast Equipment in the Apartments (공동주택 내 비상방송설비의 음성명료도 실태 분석 및 재실자 인지성 개선방안 연구)

  • Oh, So-Young;Cho, Hyun-Min;Lee, Young-Ju;Lee, Min-Joo;Yoon, Myung-Oh
    • Fire Science and Engineering
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    • v.32 no.4
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    • pp.60-68
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    • 2018
  • Due to the complicated plan structure of the apartment units and the improved room-to-room sound insulation performance, it is difficult to communicate and recognize the fire situation by emergency broadcast equipment. In this study, speech intelligibility was measured and analyzed for three types of apartment unit by emergency broadcast equipment on various measurement points. Simulations were also conducted to improve the speech intelligibility. As a result of field measurements 72, 84, and 101 Type were not satisfied with NFSC standard of 90 dBA at the point of 1 m distance from source. In addition, it was evaluated that 75 dBA and CIS 0.7 of NFPA standard was not satisfied at all measurement points except for the 72 Type at living room point with door opened condition. Based on the door opened condition of the bedroom, it satisfied the NFPA of 75 dBA and CIS 0.7 in each bedroom when more than 90 dBA was satisfied at the 1 m separation point provided in NFSC standard.

Influence of Carbonation for Chloride Diffusion in Concrete (탄산화 복합환경시 염소이온 확산에 관한 연구)

  • Oh Byung-Hwan;Lee Sung-Kyu;Lee Myung-Kue;Jung Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.179-189
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    • 2005
  • Corrosion of steel due to chloride attack is a major concern in reinforced concrete structures which are located in the marine environments. In this case, Fick's 2nd law has been used for the prediction of chloride diffusion related with service life of concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures and to investigate the validity of Fick's law to chloride attack combined carbonation. The test results indicate that the chloride ion profiles from Fick's law using the diffusion coefficient of immersion tests is not reflected the effect of separation of chloride ions in carbonation region but valid in sound region in case of combined action. On the other hand, the chloride ion profiles from Fick's law using the diffusion coefficient of Tang and Nilsson's method coincide with test results under dry-wet condition but not under combined condition. The results of present study may Imply that the new method for the measurement of diffusion coefficient is required to predict the chloride ion profiles in case of combined action at early.

Separation of Tantalum from Electronic Components on Laptop Printed Circuit Board Assembly (노트북 인쇄회로기판 전자부품으로부터 탄탈럼의 분리)

  • Kwon, Seokje;Park, Seungsoo;Kim, Seongmin;Joe, Aram;Song, Youjin;Park, Poongwon;Park, Jaikoo
    • Resources Recycling
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    • v.25 no.1
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    • pp.24-30
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    • 2016
  • The study to obtain tantalum concentration from electronic components (ECs) on Printed circuit board assembly (PCBA) of laptop was conducted. Electronic components on laptop PCBA were detached from boards by using self-developed experimental apparatus. The detached electronic components were sieved and 93.2 wt.% of tantalum capacitors were concentrated from the size interval from 2.80 mm to 6.35 mm. The tantalum capacitors were pulverized by hammer mill and electrodes (anode and cathode) were removed from the grinding products by using magnetic separators under the magnetic force of 300 Gauss. Finally, tantalum concentrate was concentrated from the magnetic separator products by using Knelson concentrator, and the maximum efficiency of 76.9% was achieved under the operating condition of bowl rotating speed of 200 rpm, and fluidizing water flowrate of 7 L/min. The grade and recovery of Ta concentrate under the condition were 81.1% and 78.8%, respectively.