• Title/Summary/Keyword: Separation condition

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Fabrication of the pyramid-type silicon tunneling devices for displacement sensor applications (변위센서응용을 위한 피라미드형 실리콘 턴널링소자의 제조)

  • Ma, Tae-Young;Park, Ki-Cheol;Kim, Jeong-Gyoo
    • Journal of Sensor Science and Technology
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    • v.9 no.3
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    • pp.177-181
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    • 2000
  • The tunneling current is exponentially dependent on the separation gap between a pair of conductors. The detection of displacement can be, therefore, carried out by measurment of a variation in the tunneling current. In this experiment, we fabricated pyramid-type silicon tunneling devices in which a tunneling current flow between a micro-tip and $Si_3N_4$ thin film membrane. A MEMS process was used for the fabrication of the tunneling devices. The micro-tips were formed on Si wafers by undercutting a differently oriented square of $SiO_2$ with KOH. The stiffness of the $Si_3N_4$ films were observed and the model for the stiffness calculation, which is useful in predicting the stiffness even when the stiffness ranges beyond the scope of the normal experimental condition, was suggested.

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Quantitative Analysis of the Fifteen Constituents in Hyangso-San by LC-MS/MS (LC-MS/MS를 이용한 향소산 중 15종 성분의 정량분석)

  • Seo, Chang-Seob;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.47 no.4
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    • pp.381-388
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    • 2016
  • Hyangso-san is a traditional herbal medicine that consists of the seven herbal medicines, Cyperi Rhizoma, Perillae Folium, Atractylodis Rhizoma, Citri Unshius Pericarpium, Glycyrrhizae Radix et Rhizoma, Zingiberis Rhizoma Crudus, and Allii Fistulosi Bulbus. Hyangso-san has long been clinically used to treat the influenza, including headache, ferver, chills, and pantalgia. In this study, we were performed the simultaneous analysis of the 15 marker compounds (liquiritin apioside, liquiritin, ferulic acid, naringin, hesperidin, rosmarinic acid, liquiritigenin, kaempferol, glycyrrhizin, nobiletin, 6-gingerol, elemicin, atractylenolide III, nootkatone, and atractylenolide I) in Hyangso-san using liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS/MS). Column for the separation of the 15 ingredients was used a Waters Acquity UPLC BEH $C_{18}$ analytical column ($2.1{\times}100mm$, $1.7{\mu}m$) at $45^{\circ}C$ by using a mobile phase of 0.1% (v/v) formic acid in water and acetonitrile with gradient condition. Identifications of all analytes were performed using a Waters ACQUITY TQD LC-MS/MS system. The flow rate and injection volume were 0.3 mL/min and $2.0{\mu}L$, respectively. Correlation coefficient of the calibration curve was ${\geq}0.9958$. The values of limits of detection and quantification of the 15 components were 0.002-4.29 and 0.01-12.88 ng/mL, respectively. The result of an analysis using the established LC-MS/MS method, kaempferol and atractylenolide I were not detected, while other 13 compounds were 0.08-56.87 mg/g in lyophilized Hyangso-san sample.

Desorption of Adsorbed Humic Acid on Carbon nano Tubes (카본나노튜브에 흡착된 휴믹산의 탈착에 관한 연구)

  • Jo, Mihyun;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.7
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    • pp.81-89
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    • 2013
  • Concerns have been raised over the impact of nano materials on soil and groundwater environment with the increasing attention to the potential applications of carbon nano materials in various fields. Particularly, carbon nano materials introduced into water environment readily make complexes with humic acid (HA) due to their hydrophobic nature, so there have been increasing numbers of studies on the interaction between HA and carbon nano materials. In this study, we investigated the solubility of HA and multiwalled carbon nanotubes (MWCNT) in three different surfactant solutions of sodium dodecyl sulfate (SDS), Brij 30 and Triton X-100, and evaluated whether the HA can be effectively desorbed from the surface of MWCNT by surfactant. The objective of this study was to determine the optimal adsorption condition for HA to MWCNT. Futhermore, sodium dodecyl sulfate (SDS), Brij 30, Triton X-100 were used to elucidate the effect of desorption and separation on adsorbed HA on MWCNT. As a result, HA solution with 12.7 mg of total organic carbon (TOC) and 5 mg of MWCNT showed the highest adsorption capacity at pH 3 reacted for 72 hrs. Weight solubilizing ratio (WSR) of surfactants on HA and MWCNT was calculated. HA had approximately 2 times lower adsorption capacity for the applied three surfactants compared to those of MWCNT, implying that the desorption of HA may occur from the HA/MWCNT complex. According to the results of adsorption isotherm and weight solubilizing ratio (WSR), the most effective surfactants was the SDS 1% soluiton, showing 53.63% desorption of HA at pH 3.

Conditioning and Characteristics of the Sea Water containing Heavy Oil (유독해수(油獨海水)의 조정(調整)과 성장(性狀)에 관한 연구(硏究))

  • Cho, Bong-Yeon;Hwang, Yong-Woo;Kim, Jong-Guk
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.31-41
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    • 1998
  • As the leakage of crude oil from tankers breaks out frequently, it caused a serious problem for ocean pollution and calls for developing treatments to handle the leaked crude oil and mitigate the pollution. Thus it is required to develop new purification technolgies and appropriate treatment systems which have sufficient treatment capability in order to cope with the anticipated ocean pollution. In this experiment, A and B type heavy oils were used to make the emulsion of both water containing heavy oil and sea-water containing heavy oil. The following are the main results from this study ; 1. When A and B type heavy oils were added to the original sea-water and treatedin the homogrenizer respectively, the particle of oil beacame smaller in both cases. Under the same condition, while the initial oil density of sea-water containing B-heavy oil is higher than of emulsion with A-heavy oil, the particle of A-heavy oil is finer than that of B-heavy oil. 2. When A and B type heavy oils were added to distilled water and treated in the homogenizer respectively, the particle was more dispersed and finer than that in the case of sea-water in both cases. In this result, the water containing oil formed more stable emulsion than the sea-water containing oil. 3. In this experiment, all emulsions showed oil in water types. 4. Since the oil particle is larger in the sea-water than in the distillated water, interms of elimination of oil, it is thought to be more important to give Membrane treatment after implementing sandfilter, activity carbon, coagulation-sedimentation and floating separation as pre-treatment.

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Production of Portopectinase from Bacillus subtilis EK11 (Bacillus subtilis EK11로부터 Protopectinase 생산)

  • 문철환;최종수;이승철;황용일
    • Microbiology and Biotechnology Letters
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    • v.29 no.3
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    • pp.176-180
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    • 2001
  • In plant tissues intercellular cementing portion called as middle lamella consists of high proportion of protopectin that is water insoluble form of pectin on their backbone Protopectinase (PPase) a heterogeneous group of enzymes that hydrolyze or dissolve the insoluble protopectin in plant tissues by restricted depolymerization liberates water solu- ble pectin with the resultant separation of plant tissues that have been protected against environmental shock by rigid cel wall . Bacillus subtilis EKll was most effective for PPase Production For increasing of PPase productivity effects of glucose concentrations, pHs and aeration rates were studied in batch culture The most proper concentra- tion of glucose pH and air condition for PPase Production were 1% 8.0 and lvvm respectively In these condi- tion PPase productivity was $84,364 UL^{-1}$ $h^{-1}$ and increased about 15.6 times than flask fermentation.

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Identification on Fatigue Failure of Impeller at Single Stage Feedwater Pumps During Commissioning Operation (단단 주 급수 펌프 임펠러에서 시운전 중 발생한 피로 절손에 관한 규명 연구)

  • Kim, Yeon-Whan;Kim, Kye-Yean;Bae, Chun-Hee;Lee, Young-Shin
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.18 no.9
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    • pp.937-942
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    • 2008
  • This paper presents a case history on failures of impeller and shaft due to pressure pulsation at single stage feed water pumps in 700 MW nuclear power plant during commissioning operation. The pumps had been service and had run for approximately $40{\sim}50$ hours. For the most part, the failures of impeller occurred with the presence of a number of fatigue cracks. All cracks were associated with the deleterious surface layer of impeller by visual and metallurgical examination. On-site testing and analytical approach was performed on the systems to diagnose the problem and develop a solution to reduce the effect of exciting sources. A major concern at high-energy centrifugal pump is the pressure pulsation created from trailing edge of the Impeller blade, flow separation and recirculation at centrifugal pumps of partial load. Pressure pulsation due to the interaction generating between impeller and casing coincided with natural frequencies of the impeller and shaft system during 1ow load operation. It was identified that dynamic stress exceeding the fatigue strength of the material at the thin shroud section due to the hydraulic instability at running condition below BEP.

A Comparison of Sampling and Analytical Methods for Airborne Isocyanates (공기중 이소시아네이트류의 측정 및 분석방법에 관한 비교연구)

  • 변혜정;윤충식;백남원
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.32-42
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    • 1996
  • This study was performed to evaluate accuracy and precision of filter method and impinger method for analyzin airborne isocyanates in mixture (2, 6-TDI, HDI, 2, 4-TDI, MDI). Filter method was performed using the OSHA Method 42 and impinger method using the NIOSH Method 5521. The samples were analyzed by high performance liquid chromatography-ultraviolet detector (HPLC-UVD). After the optimum operating conditions for each method were investigated, samples with various concentration levels were quantified at the conditions. The precision was expressed by the pooled coefficient of variation(C.V.) and the accuracy by overall accuracy. The results are summarized as follows: 1. The optimum condition of filter method was determined at 35/65 ACN/buffer (0.01 M ammonium acetate) in mobile phase. And in case of impinger method, it was at 30/70 ACN/buffer(0.2 M sodium acetate). The effect of concentrations of acetate on the separation of the peaks was not significant, but, the effect of ACN/buffer ratio was significant. 2. The correlation coefficients for the two methods were above 0.9 in all isocyanate compounds. Average recovery efficiencies for 2, 6-TDI, HDI, 2, 4-TDI and MDI in filter method were 92.4%, 102.6%, 87.3% and 101.0%, respectively. Those in impinger method were 106.6%, 106.7%, 99.0% and 103.6%, respectively. As a result, the recovery efficiency of impinger method was higher than those of filter method in analyzing isocyanate compounds. 3. The pooled coefficients of variations of the methods were slightly higher than expected. The overall accuracies of the methods were within $\pm 25%$ for each isocyanate compound. Since these results satisfy NIOSH criteria, the accuracy of the experiment is appropriate. 4. As seen above, impinger method is more efficient than filter method. But, there are many disadvantages in impinger method. Therefore, solid sorbent such as a glass fiber filter must be developed in order to have the high efficiency not less than that of impinger method in the future.

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A Planning Study on the Improvement of Public Hospital Patient Room based on the Understanding of User - Focused on the Case Study of District-Based Public Hospital in Korea (사용자 이해에 기반한 공공병원 병실환경 개선에 관한 계획적 연구 - 지역 거점 공공병원의 사례연구를 중심으로)

  • Oh, Kyoung Mi;Park, Jae Seung
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.20 no.4
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    • pp.49-56
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    • 2014
  • Purpose : This purpose of this study is to make a better public hospital patient room to reflect the views of the patient. Methods: Survey to examine patient experience on healing environment in public hospital have been conducted for the data collection. 229 open-ended answers have been analysed statistically by MS Excel program. Results : 1) If there is no toilet space in the six-patient room, installation of toilet in the patient room is necessary. 2) The most Frequently used patient furnitures are necessary to accomodate the patients needs. Depending on the patient condition, installation of a portable or fixed the room furniture for the convenience to the using furniture. 3) According to the flow of modern times, wireless internet access is required to install of expand the space. Also be used to establish a regulations of internet space. 4) To create healing environment infection free environment should be provided. 5) Need for improvements of patient room for relatives of patient. It is necessary to secure a comfortable space to stay. 6) Separation is needed among the patients through therapeutic classification. Implication : In order to provide a better patient room environment, it is necessary to reflect the patient's opinion.

Numerical Study of Normal Start and Unstart Processes In a Superdetonative Speed Ram Accelerator (초폭굉속도 램가속기의 정상발진과 불발과정에 대한 수치해석)

  • Moon, Guee-Won;Jeung, In-Seuck;Choi, Jeong-Yeol;Seiler, Friedrich;Patz, Gunther;Smeets, Gunter;Srulijes, Julio
    • 한국연소학회:학술대회논문집
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    • 2002.06a
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    • pp.123-132
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    • 2002
  • A numerical study was conducted to investigate the combustion phenomena of normal start and unstart processes based on ISL's RAMAC 30 experiments with different diluent amounts and fill pressures in a ram accelerator. The initial projectile launching speed was 1.8 km/s which corresponded to the superdetonative speed of the stoichiometric $H_2/O_2$ mixture diluted with 5 $CO_2$ or 4 $CO_2$. Experiments with same condition except for projectile surface material demonstrated that ignition was successful with an aluminum projectile, but no combustion was observed in case of a steel projectile. In this study, it was found that neither shock nor viscous heating was sufficient to ignite the mixture at a low speed of 1.8 km/s, as was found in the experiments using a steel projectile. However, we could succeed in igniting the mixtures by imposing a minimal amount of additional heat to the combustor section and simulate the normal start and unstart processes found in the experiments with an aluminum projectile. For the numerical simulation of supersonic combustion, multi-species Navier-Stokes equations coupled with a Baldwin-Lomax turbulence model and detailed chemistry reaction equations of $H_2/O_2/CO_2$ suitable for high-pressure gaseous combustion were considered. The governing equations were discretized by a high order accurate upwind scheme and solved in a fully coupled manner with a fully implicit, time accurate integration method. The numerical results matched almost exactly to the experimental results. As a result, it was found that the normal start and unstart processes depended on the strength of gas mixture, development of shock-induced combustion wave stabilized by the first separation bubble, and its size and location.

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Formation Mechanism of Chlorate ($ClO_3\;^-$) by Electrochemical Process (전기화학적 공정에 의한 클로레이트의 생성메커니즘)

  • Baek, Ko-Woon;Jung, Yeon-Jung;Kang, Joon-Wun;Oh, Byung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.627-634
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    • 2009
  • This study was done to find out the formation mechanism of chlorate by electrochemical process using chloride ion ($Cl^-$) as an electrolyte. Firstly, the effective factors such as pH and initial chloride concentration were figured out to see the formation property of chlorate during electrolysis. And the relation of free chlorine, and mixed oxidants such as OH radical and ozone with chlorate were estimated to concretize the formation mechanism. As a result, it was found that the major reaction of chlorate formation would be electrochemical reaction with free chlorine, and also the direct oxidation of chloride ion and the reaction by OH radical were participated in the formation of chlorate. Moreover, it was observed that formed chlorate was oxidized to perchlorate. Lastly, the optimum condition was recommended by comparing free chlorine with chlorate concentration during the electrochemical process with the different electrode separation.