• Title/Summary/Keyword: Separation condition

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study of the character and condition of Cr in the korea cement (국내 시멘트 중의 크로뮴 성상에 관한 연구)

  • Min, Kyung-San;Lee, Seung-Heun;Lee, Se-Jin;Lee, Seung-Hoon;Moon, Se-Heum;Jeong, Jae-Hong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.521-524
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    • 2008
  • The purpose of this study is to identify the character and condition of Cr in the clinker and thereby contribute to the research for reduction in utilizing Cr in the cement manufacturing process. The concentration of chromium by cement particle size and the distribution of chromium by clinker mineral were measured. Next, correlation was considered between chromium and the soluble components in cement. As a result, in the range that cement particles were 20${\mu}$m or less, highest soluble hexavalent chromium was found. When the concentration of chromium was measured through mineral separation, belite and the interstitial phase were higher in chromium than in alite. soluble hexavalent chromium was contained in domestic cement less than 20ppm, and its conversion ratio was somewhat high as 10 to 40% or so.

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A Study on failure mechanism and load-bearing capacity of single-shell tunnel lining (싱글쉘 터널 라이닝의 파괴 메카니즘 및 지보성능에 관한 연구)

  • Shin, Hyu-Soung;Kim, Dong-Gyou;Chang, Soo-Ho;Bae, Gyu-jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.8 no.3
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    • pp.273-287
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    • 2006
  • This study investigates the failure mechanism and load-carrying capacity of a single-shell lining which has no disturbance in transfer of shear force, with respect to a conventional double-shell lining which has separation between layers of shotcrete lining and secondary concrete lining by water-proof membrane. In order to evaluate the capacity, a 2-D numerical investigation is preliminarily carried out and then real-scale loading tests with tunnel lining section specimens are performed on the condition given by the numerical investigation. In the test, a concentrated load is applied for considering a released ground load or rock wedge load. Through this study, it appears that the single-shell lining takes the load-bearing capacity 20% higher than in case of the double-shell lining. In addition, a possibility of a composite single-shell shotcrete layer composed by multiple bonded layers partly involving different contents of high-capacity additives is shown thereby leading to use of less amount of the high-capacity additives on the condition of taking a similar load-bearing capacity.

Determination of Dibutyltin in Sediments Using Isotope Dilution Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry

  • Yim, Yong-Hyeon;Park, Ji-Youn;Han, Myung-Sub;Park, Mi-Kyung;Kim, Byung-Joo;Lim, Young-Ran;Hwang, Eui-Jin;So, Hun-Young
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.440-446
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    • 2005
  • A method is described for the determination of dibutyltin (DBT) in sediment by isotope dilution using liquid chromatography inductively-coupled plasma/mass spectrometry (LC-ICP/MS). To achieve the highest accuracy and precision, special attentions are paid in optimization and evaluation of overall processes of the analysis including extraction of analytes, characterization of the standards used for calibration and LC-ICP/MS conditions. An approach for characterization of natural abundance DBT standard has been developed by combining inductively-coupled plasma/optical emission spectrometry (ICP/OES) and LC-ICP/MS for the total Sn assay and the analysis of Sn species present as impurities, respectively. An excellent LC condition for separation of organotin species was found, which is suitable for simultaneous DBT and tributyltin (TBT) analysis as well as impurity analysis of DBT standards. Microwave extraction condition was also optimized for high efficiency while preventing species transformation. The present method determines the amount contents of DBT in sediments with expanded uncertainty of less than 5% and its result shows high degree of equivalence with reference values of an international inter-comparison and a certified reference material (CRM) within stated uncertainties.

An Influence of Groundwater Flow on Performance of Closed Borehole Heat Exchangers (Part-1) (지하수류가 밀폐형 천공 지중열교환기 성능에 미치는 영향(1))

  • Hahn, Jeong Sang;Hahn, Chan;Yoon, Yun Sang;Kiem, Young Seek
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.64-81
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    • 2016
  • To analyze the influence of various groundwater flow rates (specific discharge) on BHE system with balanced and unbalanced energy loads under assuming same initial temperature (15℃) of ground and groundwater, numerical modeling using FEFLOW was used for this study. When groundwater flow is increased from 1 × 10−7 to 4 × 10−7m/s under balanced energy load, the performance of BHE system is improved about 26.7% in summer and 22.7% at winter time in a single BHE case as well as about 12.0~18.6% in summer and 7.6~8.7% in winter time depending on the number of boreholes in the grid, their array type, and bore hole separation in multiple BHE system case. In other words, the performance of BHE system is improved due to lower avT in summer and higher avT in winter time when groundwater flow becomes larger. On the contrary it is decreased owing to higher avT in summer and lower avT in winter time when the numbers of BHEs in an array are increased, Geothermal plume created at down-gradient area by groundwater flow is relatively small in balanced load condition while quite large in unbalanced load condition. Groundwater flow enhances in general the thermal efficiency by transferring heat away from the BHEs. Therefore it is highly required to obtain and to use adequate informations on hydrogeologic characterristics (K, S, hydraulic gradient, seasonal variation of groundwater temperature and water level) along with integrating groundwater flow and also hydrogeothermal properties (thermal conductivity, seasonal variation of ground temperatures etc.) of the relevant area for achieving the optimal design of BHE system.

High-Gain Fabry-Pérot Cavity Antenna with Planar Metamaterial Superstrate for Wibro Base Station Antennas (평판형 메타 물질로 구성된 상부 덮개를 갖는 와이브로 기지국용 고 이득 Fabry-Pérot 공진기 안테나)

  • Kim, Dong-Ho;Choi, Jae-Ick
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.12
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    • pp.1367-1374
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    • 2008
  • A new high-gain Fabry-$P{\acute{e}}rot$ cavity antenna for wireless broadband internet(Wibro) base station antennas, which is covered with metamaterial superstrate presenting simultaneous negative values of permittivity and permeability, is proposed. To facilitate the fabrication process using the printed circuit board(PCB) technology of today, a new planar-type metamaterial superstrate is designed, which shows negative and low positive values of a refractive index near the Wibro service frequency band. And the principle of antenna gain enhancement is analyzed from the two different view points of effectively low refractive index and of the Fabry-$P{\acute{e}}rot$ resonance condition. Single square patch antenna is used as a feeder. The separation distance is determined by considering the reflection phases of the metamaterial superstrate and the substrate satisfying Fabry-$P{\acute{e}}rot$ resonance condition, respectively. Comparison between the prediction and the measurement shows good agreement, which verifies the validity of our design approach.

Design and static structural analysis of KSLV-I upper stage cowls (KSLV-I 상단부 카울 설계 및 구조 해석)

  • An, Jae-Mo;Kim, Kwang-Soo;Jang, Young-Soon
    • Aerospace Engineering and Technology
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    • v.6 no.2
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    • pp.111-118
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    • 2007
  • KSLV-I which is being developed in KARI is composed with two stages, and adaptor ring is used for coupling stage. Cables for interconnecting between stage is exposed on the outside. Also 8 pyro bolts which are installed in adaptor ring are used for separation of stage. In general, cowl is used for protecting exposed parts or structure which are anxious about damage from outer environment. In KSLV-I, two kind of cowls are designed. The one is umbilical cowl, and the other is pyro bolt cowl. Because cowl is exposed on the outside, heat and pressure load developed from air have effect on cowls. Therefore verification of structural strength through static analysis is required. In this study, static analysis in load condition except heat load is accomplished. In result of analysis, structural strength of pyro bolt cowl is verified. But breakage of umbilical cowl is confirmed in pressure load condition. So design of umbilical cowl is modified for satisfying required structural strength. And structural strength of umbilical cowl through analysis is verified.

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Purification of Fructooligosaccharides Using Simulated Moving Bed Chromatography (Simulated Moving Bed 크로마토그래피를 이용한 프럭토 올리고당의 정제)

  • Oh, Nan-Suk;Lee, Chong-Ho;Koo, Yoon-Mo
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.715-721
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    • 2005
  • The SMB chromatography is used to obtain high purification of fructooligosaccharides (FOS), the mixture of kestose and nystose. SMB operation condition is usually determined by triangle theory or standing wave design when reactions do not occur within columns during experiment. Some of the reactions in columns may considerably affect experimental results. FOS can be hydrolyzed and converted into glucose and fructose during operation. To include the effect of reaction, the concentrations of each component at steady state after hydrolysis were used in simulation. The obtained simulation values are well matched with experimental results except sucrose. For sucrose, the experimental results were different from expected one due to the existence of an intermediate component. FOS is easily hydrolyzed and converted into glucose and fructose in more acidic condition and at higher temperature. Hydrolysis reaction can be prevented by the pretreatment of separation resin with NaOH as well as operation under lower temperature.

Understanding of Posttraumatic Embitterment Disorder (PTED) (외상후 울분장애의 이해)

  • Ko, Han-Suk;Han, Chang-Su;Chae, Jeong-Ho
    • Anxiety and mood
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    • v.10 no.1
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    • pp.3-10
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    • 2014
  • Reactive disorder is a group of diagnosis with a definitely known etiology and whose etiological factor is essential to the diagnosis. In DSM system, such reactive disorders are listed as adjustment disorder, acute stress disorder, brief psychotic disorder with marked stressor and posttraumatic stress disorder (PTSD). However, a growing number of individuals is suffering from a prolonged feeling of embitterment after exceptional negative life events and this condition could be diagnosed neither PTSD nor adjustment disorder nor depressive disorder in the context of DSM-IV diagnostic system. This clinical condition can be described as 'posttraumatic embitterment disorder' (PTED). PTED is a reactive disorder triggered by exceptional, though normal negative life events such as conflict in the workplace, unemployment, death of a relative, divorce, severe illness, or experience of loss or separation. The common feature of such events is that they are experienced as unjust, as a personal insult, accompanied by psychological violation of basic beliefs and values. The central psychopathological response pattern in PTED is a prolonged feeling of embitterment. In particular, the core emotion of embitterment can lead to the rejection of treatment. Therefore, "wisdom therapy" as a new treatment approach specifically designed for PTED has been developed. It is assumed that many patients suffering from PTED are often misunderstood and misdiagnosed. This review would help to introduce PTED into the clinical field in psychiatry.

Preparation and Physical Properties of Blend Films of Natural Rubber and Chloroprene Rubber Latex (NR/CR 라텍스 블렌드 필름의 제조 및 물리적 특성)

  • Kim, Kong Soo;Park, Jun Ha;Eum, Ju Song
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.691-697
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    • 1996
  • The NR films were prepared with mixing of natural rubber latex(NRL) with various additives, and NR/CR films were prepared by blend ratio of chloroprene rubber latex(CRL). The swelling degree and the mechanical properties of these films were measured according to the procure time. As a result, optimum condition were showed the swelling degree : 80~85%, precure time : 48~60hrs., and tensile strength was reduced but elongation was increased as increasing the blend ratio of CRL. On the mechanical properties of films prepared by different dipping process in these optimum condition, the tensile strength and tear strength of NR/CR films by one dipping process are better than NR-d-CR films by two dipping process. The surface of these films were observed with scanning electron microscopy(SEM). It was found that phase separation was occured as increasing the blend ratio of CRL.

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Synthesis of Aminated PP-g-styrene Fibrous Ion-Exchanger for Separation of Boron from Ground-Water (지하수로부터 붕소이온 분리를 위한 아민화 PP-g-styrene 이온교환체 섬유의 합성과 붕소 음이온 흡착에 관한 연구)

  • Hwang, Taek-Sung;Lee, Jin-Hyok;Lee, Myun-Joo
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.451-459
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    • 2001
  • Fabric ion-exchanger, aminated PP-g-styrene was synthesized with styrene monomer onto PP staple fiber by pre-irradiational grafting with E-beam and subsequent chloromethylation and amination. Degree of grafting was increased with increasing the styrene monomer concentration and the highest degree of grafting was obtained 118% at a monomer concentration of 80% styrene. Optimum condition of Mohr's salt and sulphuric acid were 1.0 ${\times}\;10^{-3}$ M and 0.1 M. Amount of amination was increased with increasing degree of grafting. Swelling ratio of aminated PP-g styrene was higher than that of trunk polymer. Ion-exchange capacity was 6.7 meq/g, which was three times greater than commercial ion-exchanger. Optimum condition of baron ion adsorption was pH 4 and amount of adsorption were increased with increasing the amount of amination.

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