• Title/Summary/Keyword: Separation Process

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Application of Pervaporation Membrane Process in Petrochemical Industry (석유화학공업에서의 투과증발막의 응용)

  • Nam, Sang-Yong
    • Membrane Journal
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    • v.17 no.1
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    • pp.1-13
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    • 2007
  • Pervaporation process using membrane is newly emerging energy saying and cost effect process instead of distillation process. Especially, in pertrochemical industry, pervaporation process is a strong candidate to substitute the conventional energy consuming processes because that petrochemical industry has much energy consuming separation processes, many azeotrope mixtures to separate and needs to compact space to install new process units. Aromatic/aliphatic separation including benzene/cyclohexane mixture, olefin/paraffin separation, xylene isomer separation, reactive monomer recovery and sulfur compound removal from gasoline have been inversitigated for the application of pervaporation membrane process by many researchers and are under commercializing.

Solid Separation and Flotation Characteristics of Livestock Wastewater Using DAF Process (DAF 공정을 이용한 축산폐수의 고형물 분리와 부상특성)

  • Kang, Byong-Jun;Yoo, Seung-Joon;Lee, Se-il;Kwak, Dong-Heui
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.359-366
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    • 2008
  • The series of experiments under the various conditions were carried out to evaluate the feasibility of dissolved air flotation (DAF) as an alternative of conventional gravity sedimentation (CGS) and to investigate the decrease of the loadings following to biological wastewater treatment processes in livestock wastewater system. On the basis of the experiment result between CGS and DAF processes, for the other water quality criteria as well as suspended solid the removal efficiency of DAF process was about 20~25 % better than CGS process on average. In addition, the particle removal efficiency of DAF process became higher in proportion as the increase of air to solid (A/S) ratio and the general wastewater treatment efficiency of DAF process was enough to meet the requirement of loading decrease to following biological process even at low A/S ratio range. Though DAF process is widely known as an solid separation unit, there was not the notable relationship between particle separation efficiency and several pollutant removal efficiencies like $COD_{Cr}$ and nutrients (T-N, T-P). Assume that the $COD_{Cr}$ was removed as the fraction of particle separation in this experiment, the removal efficiency of T-N and T-P were sensitive to removal efficiency of $COD_{Cr}$, especially.

Fundamental study on sustainable treatment system of mine water using magnetized solid catalyst

  • Mukuta, Chisato;Akiyama, Yoko
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.15-21
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    • 2019
  • In the mine exploration sites, sustainable treatment system of mine water with energy saving and minimized chemical additives is required. Since most of the mine water contains highly-concentrated ferrous ion, it is necessary to study on the removal method of iron ions. We propose the system consisting of two processes; precipitation process by air oxidation using solid catalyst-modified magnetite and separation process combining gravitational sedimentation and magnetic separation using a permanent magnet. Firstly, in the precipitation process (a former process of the system), we succeeded to prepare solid catalyst-modified magnetite. Air oxidation using solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material showed high iron removal capability. Secondly, in the separation process (latter process of the system), solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material can be separated by a superconducting bulk magnet and a permanent magnet.

Membrane Processes for Energy Saving in Japan

  • Nakao, Shin-ichi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.06a
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    • pp.45-58
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    • 1994
  • Over the last 20 years, membrane separation processes, such as reverse osmosis, ultrafiltration and microfiltration, have been widely adopted by different industries. Commercial uses of membrane have displaced conventional separation processes, such as distillation, evaporation, precoat filter and so on. Membrane separation processes are often more capital and energy efficient when compared with conventional separation processes. Membrane devices and systems are almost always compact and modular. These are the well-known advantages of membrane separation processes. The disadvantage of the membrane process is that the process does not have scale merit and thus the membrane process is suitable for the small and middle size applications. Energy saving is, of course, the biggest advantage of the membrane process, and in many industries the membrane processes are employed because of this reason. Membrane process has other big advantage. In many applications membrane processes provide much higher quality of product than conventional processes. The example is ultrapure water production by membrane processes in semiconductor industry. Conventional technologies never offer such good quality of pure water. If you can obtain both energy saving and higher quality of product at the same time by membrane processes, this is the best application of membrane processes. One example is the concentration of orange juice by membrane, which has already been commercialized in Japan. Comparing with the conventional vacuum evaporation process, juice concentrated by the membrane process has much better taste and flavor and the energy consumption in the membrane process is much less than the evaporation process. In this paper, first membrane separation technology will be classified and then Japanese membrane manufacturers and new modules and devices under development in Japan will be introduced. Fourth energy saving in membrane process will be discussed and finally practical applications of membrane processes in Japan will be shown.

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A high-effective method to separate nicotine from the tobacco-specific carcinogen 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) mixtures using electrodialysis

  • Ge, Shaolin;Li, Wei;Zhang, Zhao;Li, Chuanrun;Wang, Yaoming
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.245-257
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    • 2017
  • The separation of nicotine and tobacco-specific N-nitrosamines is a tough problem in tobacco industry. In this study, separation of nicotine from 4-(methylnitrosamino) -1-(3-pyridyl)-1-butanone (NNK) mixtures was investigated using electrodialysis by taking the principle of the protonation status difference between these two components. The results indicated that the solution pH has a dominant impact on the separation process. In a pH range of 5-7, nicotine molecules are existed as mono- and di-protonated ions and can be separated from the uncharged NNK molecules. The acidic electrolyte is conducive to the separation process from the point of flux and energy consumption; while the alkaline electrolyte has negative impact on the separation process. A current density of $10mA/cm^2$ is an appropriate value for the separation process. The lowest energy consumption of the separation process is 0.58 kWh/kg nicotine with the process cost to be estimated at only $0.208 /kg nicotine. Naturally, electrodialysis is a high-efficiency, cost-effective, and environmentally friendly process to separate and purify nicotine from tobacco juice.

A Continuous Cell Separation Chip Using Hydrodynamic Dielectrophoresis Process (유체동역학적 유전영동법을 이용한 극소형 연속 세포분리기)

  • Doh Il;Cho Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.1 s.232
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    • pp.53-58
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    • 2005
  • We present a high-throughput continuous cell separation chip using hydrodynamic dielectrophoresis (DEP) process. The continuous cell separation chip uses three planar electrodes in a separation channel, where the positive DEP cells are moved away from the central streamline while the negative DEP cells remain in the central streamline. In the experimental study, we use the mixture of viable (live) and nonviable (dead) yeast cells in order to obtain the continuous cell separation conditions. For the conditions of the electric fields frequency of 5MHz and the medium conductivity of $5{\mu}S/cm$, the fabricated chip performs a continuous separation of the yeast cell mixture at the varying flow-rate in the range of $0.1{\sim}{\mu{\ell}/min$.; thereby, resulting in the purity ranges of $95.9{\sim}97.3\%\;and\;64.5{\sim}74.3\%$ respectively for the viable and nonviable yeast cells. present chip demonstrates the constant cell separation performance for varying mixture flow-rates.

Concept of Synchronized Individuation Based on the Characters in a Movie and a Fairy Tale

  • Moon, Duk-Soo;Bahn, Geon Ho
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.33 no.2
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    • pp.48-54
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    • 2022
  • Objectives: Among adolescent development tasks, being independent of parents is an essential process for emotional and physical separation. There are many conflicts of separation and individuation between parents and adolescents; however, most clinicians explore the process of separation and individuation only from adolescents' perspective. Whether simultaneously or sequentially, separation-individuation occurs between adolescents and parents, respectively. The authors have already introduced the theory of synchronized individuation in a clinical case to explain the concept of this intersubjective phenomena. This study also attempts to prove the synchronized individuation theory through the interaction of characters in a movie and a fairy tale. Methods: The authors present the basis for the theory of synchronized individuation of adolescence through the growing process of Mason Junior, the main character of the movie "Boyhood," and from the process of the separation of a hen, Sprout, and an orphaned duckling in "The hen who dreamed she could fly." Results: Synchronized individuation was developed and observed from Mason, the son's perspective in "Boyhood," and Sprout, the mother's subjective perspective in the story of the hen. Conclusion: Increasing conflict and mutual impact in the relationship between adolescents and parents, ambivalent feelings for separation, selective identification of each other, mutual respect through mutual recognition, and role changes in relationship position were confirmed. Sons and mothers were individualized with synchronization.

Mathematical Modelling and Simulation of CO2 Removal from Natural Gas Using Hollow Fibre Membrane Modules

  • Gu, Boram
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.51-61
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    • 2022
  • Gas separation via hollow fibre membrane modules (HFMM) is deemed to be a promising technology for natural gas sweetening, particularly for lowering the level of carbon dioxide (CO2) in natural gas, which can cause various problems during transportation and process operation. Separation performance via HFMM is affected by membrane properties, module specifications and operating conditions. In this study, a mathematical model for HFMM is developed, which can be used to assess the effects of the aforementioned variables on separation performance. Appropriate boundary conditions are imposed to resolve steady-state values of permeate variables and incorporated in the model equations via an iterative numerical procedure. The developed model is proven to be reliable via model validation against experimental data in the literature. Also, the model is capable of capturing axial variations of process variables as well as predicting key performance indicators. It can be extended to simulate a large-scale plant and identify an optimal process design and operating conditions for improved separation efficiency and reduced cost.

A Study of Cadmium Recovery from LCC Crucible Using Solid-liquid Separation Method (고-액 분리법을 이용한 LCC 도가니에서의 카드뮴 회수에 관한 연구)

  • Park, Dae-Yeob;Kim, Tack-Jin;Kim, Jiyong;Kim, Kyung-Ryang;Kim, Si-Hyung;Shim, Joon-Bo;Peak, Seungwoo;Ahn, Do-Hee
    • Journal of Advanced Engineering and Technology
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    • v.4 no.4
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    • pp.431-436
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    • 2011
  • This study was carried out to reduce the problem during distillation process, which separate U, TRU (TRans Uranium) metal electro deposit, Cd and LiCl-KCl eutectic salt generating from LCC (Liquid Cadmium Cathode) electro winning process. The cadmium recovering apparatus was manufactured to separate for each metal using solid-liquid separation method. The apparatus consists of the first sieve for the separation of U and TRU metal electrodeposit, the second sieve for the separation of LiCl-KCl eutectic salt, cadmium collection basket, and a heating furnace. In addition, the size of each sieve is 2 mm to 3 mm. In this experiment, a metal wire was employed to replace TRU metal electrodeposit and U, which exist actually in a LCC crucible. In the solid state, The LiCl-KCl is separated at 340℃ at which the solid and the liquid of the remaining cadmium and LiCl-KCl eutectic salt coexists in each, after the metal wire separated at 500℃. As a result, it seems that it would be beneficial to set the processing condition in the distillation process with the additional treatment process of cadmium and LiCl-KCl eutectic salt.

Gaussian Processes for Source Separation: Pseudo-likelihood Maximization (유사-가능도 최대화를 통한 가우시안 프로세스 기반 음원분리)

  • Park, Sun-Ho;Choi, Seung-Jin
    • Journal of KIISE:Software and Applications
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    • v.35 no.7
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    • pp.417-423
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    • 2008
  • In this paper we present a probabilistic method for source separation in the case here each source has a certain temporal structure. We tackle the problem of source separation by maximum pseudo-likelihood estimation, representing the latent function which characterizes the temporal structure of each source by a random process with a Gaussian prior. The resulting pseudo-likelihood of the data is Gaussian, determined by a mixing matrix as well as by the predictive mean and covariance matrix that can easily be computed by Gaussian process (GP) regression. Gradient-based optimization is applied to estimate the demixing matrix through maximizing the log-pseudo-likelihood of the data. umerical experiments confirm the useful behavior of our method, compared to existing source separation methods.