• Title/Summary/Keyword: Separation Layer

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Synthesis of Silica/Alumina Composite Membrane Using Sol-Gel and CVD Method for Hydrogen Purification at High Temperature (Sol-gel 및 CVD법을 이용한 고온 수소 분리용 silica/alumina 복합막의 합성)

  • 서봉국;이동욱;이규호
    • Membrane Journal
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    • v.11 no.3
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    • pp.124-132
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    • 2001
  • Silica membranes were prepared on a porous ${\alpha}$-alumina tube with pore size of 150nm by sol-gel and chemical vapor deposition(CVD) method for hydrogen separation at high temperatures. Silica and ${\gamma}$-lumina membranes formed by the sol-gel method possessed a large amount of mesopores of a Knudsen diffusion regime. In order to improve the $H_2$ selectivity, silica was deposited in the sol-gel derived silica/${\gamma}$-alumina layer by thermal decomposition of tetraethyl orthosilicate(TEOS) at $600^{\circ}C$. The CVD with forced cross flow through the porous wall of the support was very effective in plugging mesopores that were left unplugged in the membranes. The CVD modified silica/alumina composite membrane completely rejected nitrogen permeation and thus showed a high $H_2$ selectivity by molecular sieve effect. the permeation of hydrogen was explained by activated diffusion and the activation energy was 9.52kJ/mol.

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Influence of Pretreatment of Substrate on the Formation of Diamond Thin Film by Hot Filament CVD (열 필라멘트 CVD법에 의한 다이아몬드 박막합성과 기판 사전처리의 영향)

  • Im, Gyeong-Su;Wi, Myeong-Yong;Hwang, Nong-Mun
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.732-742
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    • 1995
  • Effects of the substrate pretreatment on uncleation density of the diamond thin films have been investigated. The film was prepared using the hot-filament CVD reactor with the mixture of methane and hydrogen. The substrate pretreatment was done in three different ways: predeposition of carbon on the substrate, soot on the substrate, and graphite on the substrate. All three cases enhanced the nucleation density of diamond. And the effect was more marked in the first and the second cases than in the third one. In the first case where the substrate was predeposited by the carbon phase, a very smooth and uniform film of diamond could be obtained. Since the bound strength between the substrate and the predeposited carbon phase is relatively weak, separation of the diamond film layer from the substrate was found to be easy.

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The Origin of the Southeastern United States Continental Margin: Is it Volcanic or Non-Volcanic? (미국남동부 대륙주변부의 기원 : 화산성 혹은 비화산성?)

  • Oh, Jinyong
    • Economic and Environmental Geology
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    • v.27 no.6
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    • pp.571-577
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    • 1994
  • It has been controversial whether the United States Atlantic margin, which developed during Mesozoic separation of Africa and North America, is a volcanic or non-volcanic rifted margin. To understand its nature, the basement images of multi-channel seismic profiles off the southeastern United States continental margin have been examined. One of prominent results is the presence of seaward-dipping reflector (SDR) wedges, the most diagnostic feature of volcanic rifted margins. Two sets of SDR wedges appear to exist here; one along the basement hinge zone ('the hinge SDR wedge') and another seaward of the East Coast magnetic anomaly ('the outer SDR wedge'). Seaward of the basement hinge zone, the lower crustal high-velocity body previously known as the 7.2 km/s layer and the underlying smooth Moho configuration are also observed. Based on the comparison of these basement images with the crustal structures of the well-known volcanic rifted margin, the southeastern United States Atlantic margin can now be characterized as a typical volcanic rifted margin.

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A Study on the Application of Aluminosilicate Sols in Shell Mold for Investment Casting ( I ) (정밀주조용 쉘 몰드에 알루미노실리케이트계 졸의 응용에 관한 연구 ( I ))

  • Kim, Jae-Won;Kim, Du-Hyeon;Seo, Seong-Mun;Jo, Chang-Yong;Choe, Seung-Ju;Kim, Jae-Cheol;Park, Yeong-Gyu
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1188-1195
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    • 1999
  • The effect of aluminosilicate sol on the formation of mullite layer in zircon shell mold was investigated. Aluminosilicate sol was prepared by mixing of colloidal silica(NALCO(R) 1130) and an aqueous solution of aluminium nitrate at room temperature. The sol gelled at 50$^{\circ}C$ for 48 hrs. It was identified that the gel consists of aluminosilicate complexes and gibbsite. The coordination number of all aluminium ion bonded with silicon ion was four. Mullite phase formed by sintering above 1300$^{\circ}C$. XRD peak of mullite sharpened with increasing sintering temperature and the content of aluminium nitrate. Mullite phase displayed whisker-like 0.5~5${\mu}m $ particles. Separation between 1st and 3rd layers during sintering and the difference in thermal expansion coefficient between residual silica and mullite.

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Control Effect of Hydro-kinetic Force of a Special Rudder attached Flap (플랩이 부착된 특수타의 동유체력 제어효과에 관한 연구)

  • Gim, Ok-Sok;Lee, Gyoung-Woo;Ahn, Young-Kyu
    • Journal of Navigation and Port Research
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    • v.32 no.10
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    • pp.771-776
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    • 2008
  • The main purpose in having a control surface on a ship is to control the motion of it. It is the important element to determine the maneuvering characteristics of the ship. In this paper, the measured results has been compared with each other to predict the performance characteristics of flapped rudder's 2-dimensional section at $Re=3.0{\times}10^4$ using 2-frame grey level cross correlation PIV method. The side force of the rudder could be mainly improved by the lift force at 10 degrees angle of attack and the drag force at 20 degrees angle of attack. The separation point and boundary layer could be controlled by the change of the only flap's angle at 10 degrees angle of attack.

A hybrid RANS/LES Investigation of Backward-facing Step Flow (후방계단흐름의 하이브리드 RANS/LES 연구)

  • Yoo, Donggeun;Paik, Joongcheol
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.105-105
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    • 2019
  • 보나 여수로와 같은 수공구조물의 주변에서 발생하는 흐름 거동은 구조물 모서리에서 발생하는 흐름분리(flow separation)와 이에 따른 전단층(shear layer)과 재순환(recirculation) 흐름 영역의 발달 그리고 분리된 흐름의 재부착(reattachment)이 특징이다. 공학적으로 난류의 해석에 있어서 이러한 흐름 거동들을 정확하게 예측하는 것은 수공구조물 설계에 있어서 중요하다. 이 연구에서는 흐름 분리와 재순환 영역의 발달 그리고 흐름 재부착을 포함하는 후방계단(backward-facing step) 흐름을 155,000의 레이놀즈수 조건에서 하이브리드 RANS/LES 모델을 적용하여 해석결과를 평가한다. 하이브리드 모델로는 벽에 인접한 격자의 해상도에 상대적으로 민감하지 않은 SST(shear-stress transport) 난류 모델을 이용하는 DES(detached-eddy simulation) 기법을 적용하였다. 계단 높이가 h인 계산영역은 흐름방향 길이가 34h, 높이는 계단 상류와 하류에서 각각 1h와 2h 그리고 폭은 $2{\pi}$이다. 계단은 상류단으로부터 10h 하류부 지점에 위치한다. 경계조건으로 상부와 하부 벽면에 대해서는 비활조건을 적용한다. 상류부 수로에서 완전 발달한 흐름을 재현하기 위해서 유입경계조건은 유입부 하류 $2{\pi}h$ 지점에서 계산된 유속과 난류량을 매핑(mapping)기법을 이용하여 반복적으로 적용한다. 총 3.1백만개와 7.3백만개의 셀로 계산영역을 구현한 두 개의 계산격자 그리고 약 3.1백만개의 셀을 이용했지만 벽면 근처에서의 격자 구성을 다른 방식으로 설정한 두 가지 격자를 이용하여 격자 해상도가 DES 수치해석 결과에 미치는 영향을 분석하였다. 수치해석결과는 본 연구에서 상류단 조건으로 적용한 매핑기법이 대상 수로에서 완전 발달한 흐름을 잘 재현함을 보여주며, 합리적인 DES 해석 결과를 얻기 위해서는 벽에 수직한 방향으로 적절한 격자의 해상도와 분포가 필요함을 보여준다.

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A Study of the Thrust Vectoring Control Using Secondary Co- and Counter-Streams (2차 순유동과 역유동을 이용한 추력벡터 제어법에 관한 연구)

  • Lim Chae-Min;Kim Heuy-Dong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.10a
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    • pp.109-112
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    • 2004
  • Of late, the thrust vectoring control, using fluidic co-flow and counter-flow concepts, has been received much attention since it not only improves the maneuverability of propulsive engine but also reduces an additional material load due to the trailing control wings, which in turn reduce the aerodynamic drag. However, the control effects are not understood well since the flow field involves very complicated non: physics such as shock wave/boundary layer interaction, separation and significant unsteadiness. Existing data are not enough to achieve the effectiveness and usefulness of the thrust vectoring control, and systematic work is required for the purpose of practical applications In the present study, computational study has been performed to investigate the effects of the thrust vector control using the fluidic co-and counter-flow concepts. The results obtained show that, for a given pressure ratio, the thrust deflection angle has a maximum value at a certain suction flow rate, which is at less than $5\%$ of the mass flow rate of the primary jet. With a longer collar, the same vector angle is achievable with smaller mass flow rate.

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Fabrication and Photoelectrochemical Properties of an Oxide Photoanode with Zinc Oxide Nanorod Array Embedded in Cuprous Oxide Thin Film (산화아연 나노막대가 내장된 아산화구리 박막 구조를 이용한 산화물 광양극 제작 및 광전기화학적 특성)

  • Min, Byeongguk;Kim, Hyojin
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.196-203
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    • 2019
  • We report on the fabrication and characterization of an oxide photoanode with a zinc oxide (ZnO) nanorod array embedded in cuprous oxide ($Cu_2O$) thin film, namely a $ZnO/Cu_2O$ oxide p-n heterostructure photoanode, for enhanced efficiency of visible light driven photoelectrochemical (PEC) water splitting. A vertically oriented n-type ZnO nanorod array is first prepared on an indium-tin-oxide-coated glass substrate via a seed-mediated hydrothermal synthesis method and then a p-type $Cu_2O$ thin film is directly electrodeposited onto the vertically oriented ZnO nanorod array to form an oxide p-n heterostructure. The introduction of $Cu_2O$ layer produces a noticeable enhancement in the visible light absorption. From the observed PEC current density versus voltage (J-V) behavior under visible light illumination, the photoconversion efficiency of this $ZnO/Cu_2O$ p-n heterostructure photoanode is found to reach 0.39 %, which is seven times that of a pristine ZnO nanorod photoanode. In particular, a significant PEC performance is observed even at an applied bias of 0 V vs $Hg/Hg_2Cl_2$, which makes the device self-powered. The observed improvement in the PEC performance is attributed to some synergistic effect of the p-n bilayer heterostructure on the formation of a built-in potential including the light absorption and separation processes of photoinduced charge carriers, which provides a new avenue for preparing efficient photoanodes for PEC water splitting.

Characteristics of Electrical Properties, Ozone Generation and Decomposition of Volatile Organic Compounds by Nonthermal Plasma Reactor Packed with SBT Ferroelectric (SBT 강유전체 충전층 저온 플라즈마 반응기의 전기적 특성, 오존생성 및 휘발성유기화합물의 분해)

  • Eo, Joon;Kim, Il Won;Park, Jin Do;Lee, Joo Young;Lee, Hak Sung
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.249-254
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    • 2011
  • A nonthermal plasma reactor in conjunction with a tubular type with a ferroelectric (high-dielectric ceramic) pellet layer was designed and constructed. $SrBiTaO_9$ (SBT) pellets with 2.0 mm in diameter were held within the tube arrangement by two metal mesh electrodes (20 mm separation) connected to a high-voltage AC power supply. The dielectric constant of SBT pellets was 150 at room temperature and 500 at curie temperature ($335^{\circ}C$). The generation rate of ozone in the plasma reactor almost linearly increased with increasing applied voltage. In the case of the plasma reactor packed with SBT pellets the generation rate of ozone sharply increased at the applied voltage more than 20 kV. The ozone generation rate at the negative corona discharge was higher than that of the positive corona discharge. However, the destruction efficiency of toluene and methylene chloride was not increased in proportion to ozone concentration.

Application and optimal design of the bionic guide vane to improve the safety serve performances of the reactor coolant pump

  • Liu, Haoran;Wang, Xiaofang;Lu, Yeming;Yan, Yongqi;Zhao, Wei;Wu, Xiaocui;Zhang, Zhigang
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2491-2509
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    • 2022
  • As an important device in the nuclear island, the nuclear coolant pump can continuously provide power for medium circulation. The vane is one of the stationary parts in the nuclear coolant pump, which is installed between the impeller and the casing. The shape of the vane plays a significant role in the pump's overall performance and stability which are the important indicators during the safety serve process. Hence, the bionic concept is firstly applied into the design process of the vane to improve the performance of the nuclear coolant pump. Taking the scaled high-performance hydraulic model (on a scale of 1:2.5) of the coolant pump as the reference, a united bionic design approach is proposed for the unique structure of the guide vane of the nuclear coolant pump. Then, a new optimization design platform is established to output the optimal bionic vane. Finally, the comparative results and the corresponding mechanism are analyzed. The conclusions can be gotten as: (1) four parameters are introduced to configure the shape of the bionic blade, the significance of each parameter is herein demonstrated; (2) the optimal bionic vane is successfully obtained by the optimization design platform, the efficiency performance and the head performance of which can be improved by 1.6% and 1.27% respectively; (3) when compared to the original vane, the optimized bionic vane can improve the inner flow characteristics, namely, it can reduce the flow loss and decrease the pressure pulsation amplitude; (4) through the mechanism analysis, it can be found out that the bionic structure can induce the spanwise velocity and the vortices, which can reduce drag and suppress the boundary layer separation.