• Title/Summary/Keyword: Separation Coefficient

Search Result 432, Processing Time 0.025 seconds

Synchrotron SAXS Study on the Micro-Phase Separation Kinetics of Segmented Block Copolymer

  • Lee, Han-Sup;Yoo, So-Ra;Seo, Seung-Won
    • Fibers and Polymers
    • /
    • v.2 no.2
    • /
    • pp.98-107
    • /
    • 2001
  • The phase transition behavior isothermal micro-phase separation kinetics of polyester-based thermoplastic elastomer were studied using the synchrotron X-ray scattering(SAXS) method. The structural changes occurring during heating period were investigated by determining the changes of the one-dimensional correlation function, interfacial thickness and Porod constant. Based on the abrupt increases of the domain spacing and interfacial thickness, a major structural change occurring well below the melting transition temperature is suggested. Those changes are explained in terms of melting of the thermodynamically unstable hard domains or/and the interdiffusion of the hard and soft segments in the interfacial regions. SAXS profile changes during the micro-phase separation process were also clearly observed at various temperatures and the separation rate was found to be sensitively affected by the temperature. The peak position of maximum scattering intensity stayed constant during the entire course of the phase separation process. The scattering data during the isothermal phase separation process was interpreted with the Cahn-Hilliard diffusion equation. The experimental data obtained during the early stage of the phase separation seems to satisfy the Cahn-Hilliard spinodal mechanism. The transition temperature obtained from the extrapolation of the diffusion coefficient to zero value turned out to be about 147$\pm$$2^{\circ}$, which is close to the order-disorder transition temperature obtained from the Porod analysis. The transition temperature was also estimated from the inveriant growth rate. By extrapolating the inveriant growth rate to zero, a transition temperature of about 145$\pm$$\pm$$2^{\circ}$ was obtained.

  • PDF

An Analysis of Hot-Rolling in the Twin-Roll Strip Casting Process by using the Slab Method (슬랩법을 이용한 쌍롤식 박판주조 공정의 열간 압연 해석)

  • Shim, Hyun-Bo
    • Transactions of Materials Processing
    • /
    • v.3 no.1
    • /
    • pp.63-83
    • /
    • 1994
  • In this paper, the slab method have been applied to investigate the strip casting process in which hot coil is produced from molten steel directly. In the twin roll strip casting process, molten steel supplied by the nozzle cools and solidifies due to the heat extraction effect of the rolls and hot rolling of the solidified shell takes place simultaneously. The analysis of hot rolling has been carried out by using the existing results of solidification analysis for the twin roll strip casting process. The current slab method provides basic design data such as roll separation force, rolling torque, rolling power as well as end dam separation force which are required to design strip caster. The effect of friction on the basic process parameters are investigated also. It is shown that the use of appropriate friction coefficient is important and that the characteristics of hot rolling in the twin-roll strip casting process is quite different from the conventional hot rolling processes.

  • PDF

FLOW CHARACTERISTICS AROUND A RUDDER IN OPEN LATER CONDITION (단독 타 주위의 유동 특성에 대한 연구)

  • Choi, J.E.;Kim, J.H.
    • Journal of computational fluids engineering
    • /
    • v.13 no.1
    • /
    • pp.14-20
    • /
    • 2008
  • The flow characteristics around a rudder in open water condition is analyzed by the computational method. Reynolds averaged Navier-Stoke's equation is utilized for the computation. The computational hydrodynamic force coefficients are verified through comparing with the experimental results. The information of these flow characteristics is necessary to predict cavitation and maneuvering performances, to estimate steering gear capacitance, and to get the bending moment which is useful for the structural analysis. The pressure distribution, the three-dimensional flow separation, and the tip vortices are investigated. The pattern of the three-dimensional flow separation is analyzed utilizing a topological rule. The tip vortices are also investigated through a visualization technique.

Adsorption Property of Heavy Metal ion, $Cd^{2+}$-$Cl^{3+}$-$Pb^{2+}$+ in HCI Solution (HCl 용액에서의 중금속 이온, $Cd^{2+}$-$Cl^{3+}$-$Pb^{2+}$의 흡착 특성)

  • 박원우;이봉헌
    • Journal of Environmental Science International
    • /
    • v.5 no.6
    • /
    • pp.779-783
    • /
    • 1996
  • Cation exchange distribution coefficients of poly(dithiocarbamate) were presented for $Cd^{2+}$, $Cr^{3+}$, and $Pb^{2+}$ in HCI. The distribution coefficients were determined tv using the batch method. Based on these distribution data, the separation possibilities of the heavy metal ions were discussed. The distribution coefficients of three heavy metal ions on dithiocarbamate resin were decreased as HCI concentrations were increased. The selective separation of $Cr^{3+}$ and $Cd^{2+}$ was possible by using 0.1M HCl in dithiocarbamate resin and the reproducibility test showed that the average absorptivity of resin was 90% in the case of $Cd^{2+}$ ion by the column method.

  • PDF

LED module for a desk lamp (탁상 스탠드용 LED모듈)

  • Kang, Seok-Hoon;Shin, Kyung-Ho;Yeo, In-Seon
    • Proceedings of the KIEE Conference
    • /
    • 2003.07c
    • /
    • pp.1713-1715
    • /
    • 2003
  • This paper describes an LED module for a desk lamp using 1[W] high flux while LEDs. The optimum length of the module is obtained from the lighting simulation of the target area of $500{\times}500[mm]$ on the desk, which in turn determines an optimum separation between LEDs. The main issue is to find the optimum separation which gives good illuminance uniformity and high coefficient of utilization at at various reflector structures. Two module configuations of linear and ring types are compared. As a result, good illuminance uniformity is obtained in the case of the ring module. The mofied twin type, however, gives better performance than the ring module, and shows the most performance at an separation angle of around $30^{\circ}$.

  • PDF

Spectrophotometric Determination of Scandium(III) in Monazite after Separation Using Amberlite IRC 718 Chelating Resin

  • 박찬일;차기원
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.12
    • /
    • pp.1409-1412
    • /
    • 1999
  • The spectrophotometric determination method of scandium with eriochrome cyanine R (ECR) and the composition ratio of the complex were investigated in the presence of surfactants. A volume of 5 mL of 1.0×$10^{-3}$ M ECR and 10 mL of 2.0×$10^{-4}$ M CTMAB are necessary for the determination of 1.0×$10 ^{-7}$ ~ 3.0×$10^{-6}$ M Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, ternary complex at 610 nm is 5.6×$10^5$ $mol^{-1}cm{-1}$L and its detection limit is 1.0×$10^{-7}$ M. Separation studies were conducted by the column method. The effect of pH, elution solution and the influence of rare earth elements as interferents was discussed. Their separation was carried out in 0.1 M HCl-50% methanol solution and 1.0 M HCl media. The method was applied for the determination of Sc(III) in monazite.

Numerical Analysis for Flowfield of a Circular Arc Type Sea Anchor by Discrete Vortex Method (이산와법에 의한 원호형 Sea Anchor의 유동장 수치해석)

  • Ro, Ki-Deok;Kwon, Byeong-Guk;An, Heui-Chun
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.22 no.8
    • /
    • pp.1041-1051
    • /
    • 1998
  • The fluid dynamic properties of a circular arc type sea anchor were calculated by a discrete vortex method. The flow for the surface of the sea anchor was represented by arranging bound vortices at adequate intervals. The simulations were performed by assuming that the separations occur at edges. With time, the drag coefficient was almost constant but the lift coefficient oscillated in a cycle by von Karman's vortex street. As the camber ratios increase, the drag coefficient and Strouhal number were almost constant but the oscillating amplitude of the lift coefficient increased largely.

Numerical Calculation of Flow Pattern and Fluid Force on a Circular Arc-type Sea Anchor

  • Ro, Ki-Deok;Oh, Se-Kyung
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.28 no.8
    • /
    • pp.1258-1269
    • /
    • 2004
  • The fluid dynamic characteristics of a circular arc type sea anchor were calculated by a discrete vortex method. The flow for the surface of the sea anchor was represented by arranging bound vortices at adequate intervals. The simulations were performed by assuming that the separations occur at edges. With time, the drag coefficient was almost constant but the lift coefficient oscillated in a cycle due to von Karman's vortex street. As the camber ratios increase, the drag coefficient and Strouhal number were almost constant but the oscillating amplitude of the lift coefficient increased largely.

Numerical Study on Reverse Flow Charcteristics in an Axial Compressor Cascade (축류압축기 익렬에서의 역류 유동 특성에 대한 수치적 연구)

  • Sohn, Chang-Hyun;Longley, John Peter
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.24 no.5
    • /
    • pp.615-622
    • /
    • 2000
  • Numerical simulation is performed with Denton's code to get pressure loss coefficients in wide range of reverse flow incidence(from -90 degree to +85 degree) for an axial compressor cascade. As a results, it is found that the pressure loss coefficient is increased with incidence and there exist critical incidence which corresponds to the maximum pressure loss coefficient. Pressure loss coefficient with bigger incidence than its critical value is decreased. The effect of increasing incidence in a cascade extremely reduce the mass flow rate by the large flow separation region. Consequently this effect reduce the portion of dynamic pressure in the total pressure loss and beyond the critical incidence the pressure loss coefficient decrease.

Acoustic Echo Cancellation Based on Convolutive Blind Signal Separation Method (Convolutive 암묵신호분리방법에 기반한 음향반향 제거)

  • Lee, Haeng-Woo
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.13 no.5
    • /
    • pp.979-986
    • /
    • 2018
  • This paper deals with acoustic echo cancellation using blind signal separation method. This method does not degrade the echo cancellation performance even during double-talk. In the closed echo environment, the mixing model of acoustic signals is multi-channel, so the convolutive blind signal separation method is applied and the mixing coefficients are calculated by using the feedback model without directly calculating the separation coefficients for signal separation. The coefficient update is performed by iterative calculations based on the second-order statistical properties, thus estimates the near-end speech. A number of simulations have been performed to verify the performance of the proposed blind signal separation method. The simulation results show that the acoustic echo canceller using this method operates safely regardless of the presence of double-talk, and the PESQ is improved by 0.6 point compared with the general adaptive FIR filter structure.