• Fibers and Polymers
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• 제3권4호
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• pp.159-168
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• 2002

Polyurethane foams were produced by using a homogenizer as a mixing equipment. Effects of stirring speed on the foam structure were investigated with SEM observations. Variation of the bubble size, density of the foam, compressive strength, and thermal conductivity were studied. A hybrid foam consisting of polyurethane foam and commercial polystyrene foam is produced. Mechanical and thermal properties of the hybrid foam were compared with those of pure polyurethane foam. Advancement of flow front during mold filling was observed by using a digital camcorder. Four types of mold geometry were used for mold filling experiments. Flow during mold filling was analyzed by using a two-dimensional control volume finite element method. Variation of foam density with respect to time was experimentally measured. Creeping flow, uniform density, uniform conversion, and uniform temperature were assumed for the numerical simulation. It was assumed for the numerical analysis that the cavity has thin planar geometry and the viscosity is constant. The theoretical predictions were compared with the experimental results and showed good agreement.

• 한국생산제조학회지
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• 제23권1호
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• pp.32-37
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• 2014

Open-cell silicon foam is difficult to cut using conventional machining processes because of its low stiffness. That is, open-cell silicon foam is easily pressed down when the tool is engaged, which makes it difficult to remove the material in the form of chip. This study proposes an advanced method of machining open-cell silicon foam by freezing the material using liquid nitrogen. Furthermore, the machining conditions are optimized to maximize the efficiency of material removal and minimize the usage of liquid nitrogen by conducting experiments under various machining conditions. The results show that open-cell silicone foam products with free surface can be successfully machined by employing the proposed method.

• 한국재료학회지
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• 제24권8호
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• pp.393-400
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• 2014

NiO catalysts were successfully coated onto FeCrAl metal alloy foam as a catalyst support via a dip-coating method. To demonstrate the optimum amount of NiO catalyst on the FeCrAl metal alloy foam, the molar concentration of the Ni precursor in a coating solution was controlled, with five different amounts of 0.4 M, 0.6 M, 0.8 M, 1.0 M, and 1.2 M for a dip-coating process. The structural, morphological, and chemical bonding properties of the NiO-catalyst-coated FeCrAl metal alloy foam samples were assessed by means of field-emission scanning electron microscopy(FESEM), scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS). In particular, when the FeCrAl metal alloy foam samples were coated using a coating solution with a 0.8 M Ni precursor, well-dispersed NiO catalysts on the FeCrAl metal alloy foam compared to the other samples were confirmed. Also, the XPS results exhibited the chemical bonding states of the NiO phases and the FeCrAl metal alloy foam. The results showed that a dip-coating method is one of best ways to coat well-dispersed NiO catalysts onto FeCrAl metal alloy foam.

• 한국재료학회지
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• 제27권7호
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• pp.392-397
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• 2017

Fluorine-doped tin oxide (FTO) coated NiCrAl alloy foam is fabricated using ultrasonic spray pyrolysis deposition (USPD). To confirm the influence of the FTO layer on the NiCrAl alloy foam, we investigated the structural, chemical, and morphological properties and chemical resistance by using USPD to adjust the FTO coating time (12, 18, and 24 min). As a result, when an FTO layer was coated for 24 min on NiCrAl alloy foam, it was found to have an enhanced chemical resistance compared to those of the other samples. This improvement in the chemical resistance of using USPD NiAlCr alloy foam can be the result of the existence of an FTO layer, which can act as a protection layer between the NiAlCr alloy foam and the electrolyte and also the result of the increased thickness of the FTO layer, which enhances the diffusion length of the metal ion.

• Macromolecular Research
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• 제17권12호
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• pp.950-955
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• 2009

The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

• 한국재료학회지
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• 제28권6호
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• pp.324-329
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• 2018

Needle-like NiO protecting layers on NiCrAl alloy foam, used as support for hydrogen production, are introduced through electroplated Ni and subsequent microwave annealing. To improve the stability of the NiCrAl alloy foam, oxygen concentration of microwave annealing to form a needle-like NiO layer with good chemical stability and corrosion resistance is controlled in a range of 20 and 50 %. As the oxygen concentration increases to 50 %, needle-like NiO forms a dense coating layer on the NiCrAl alloy foam; this layer formation can be attributed to accelerated growth of the (200) plane. In addition, the increased oxygen concentration causes increased NiO/Ni ratio of the resultant coating layer on NiCrAl alloy foam due to improved rate of the oxidation reaction. As a result, the introduction of dense needle-like NiO layers formed at 50 % oxygen concentration improves the chemical stability of the NiCrAl alloy foam by protecting the direct electrochemical reaction between the electrolyte and the foam. Thus, needle-like NiO can be proposed as a superb protecting layer to improve the chemical stability of NiCrAl alloy form.

• 한국재료학회지
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• 제29권5호
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• pp.328-335
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• 2019

Nb-doped $TiO_2$(NTO) coated NiCrAl alloy foam for hydrogen production is prepared using ultrasonic spray pyrolysis deposition(USPD) method. To optimize the size and distribution of NTO particles based on good physical and chemical stability, we synthesize particles by adjusting the weight ratio of the Nb precursor solution(5 wt%, 10 wt% and 15 wt%). The morphological, chemical bonding, and structural properties of the NTO coated NiCrAl alloy foam are investigated by X-ray diffraction(XRD), X-ray photo-electron spectroscopy(XPS), and Field-Emission Scanning Electron Microscopy(FESEM). As a result, the samples of controlled Nb weight ratio exhibit a common diffraction pattern at ${\sim}25.3^{\circ}$, corresponding to the(101) plane, and have chemical bonding(O-Nb=O) at 534 eV. The NTO particles with the optimum weight ratio of N (10 wt%) show a uniform distribution with a size of ~18.2-21.0 nm. In addition, they exhibit the highest corrosion resistance even in the electrochemical stability estimation. As a result, the introduction of NTO coated NiCrAl alloy foam by USPD improves the chemical stability of the NiCrAl alloy foam by protecting the direct electrochemical reaction between the foam and the electrolyte. Thus, the optimized NTO coating can be proposed for excellent protection of NiCrAl alloy foam for hydrocarbon-based steam methane reforming(SMR).

• 한국유변학회:학술대회논문집
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• 한국유변학회 2001년도 Australian-Korean Rheology Conference 2001
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• pp.155.3-155
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• 2001

(No abstract, see full-text)

• 한국해안·해양공학회논문집
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• 제33권4호
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• pp.168-178
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• 2021

방파제 형식에 따른 반사율 변화가 해저지형에 미치는 영향을 살펴보기 위한 수치 모의를 수행하였다. 수치 모형은 OpenFoam 기반 tool box인 OlaFlow와 물리기반 지형모형[SeoulFoam]으로 구성하였으며, 이 과정에서 침·퇴적으로 인해 변형을 겪는 해저지형과 내습하는 파랑 간의 상호작용은 Dynamic Mesh를 활용하여 기술하였다. 다양한 반사 특성을 보이는 사석 경사제, 직립제, 곡면 슬릿 케이슨 방파제는 서로 다른 정상파를 결과하였으며, 이는 해저지형에 상당한 영향을 미치는 것을 확인하였다. 이러한 결과는 저면 유속이 상대적으로 큰 정상파 마디[node]에서 연행된 모래가 경계층 drift에 의해 배[antinode]로 이송된다는 Nielsen(1993)의 연구 결과와도 일치한다. 이렇게 재배치되는 모래로 정상파의 배[antinode]에는 sand wave의 마루, 마디[antinode] 인근에는 sand wave의 곡이 형성되었으며, sand wave 진폭은 반사계수가 우월한 곡면 슬릿 케이슨에서 가장 크게 관측되었다. 이러한 현상은 반사계수가 큰 경우 마디에서의 저면 유속 증가로 상대적으로 많은 모래가 연행되어 발생하는 것으로 판단된다.

• 한국재료학회지
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• 제26권7호
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• pp.393-399
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• 2016

Flower-like nickel oxide (NiO) catalysts were coated on NiCrAl alloy foam using a hydrothermal method. The structural, morphological, and chemical bonding properties of the NiO catalysts coated on the NiCrAl alloy foam were investigated by field-emission scanning electron microscopy, scanning electron microscopy-energy dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, respectively. To obtain flower-like morphology of NiO catalysts on the NiCrAl alloy foam, we prepared three different levels of pH of the hydrothermal solution: pH-7.0, pH-10.0, and pH-11.5. The NiO morphology of the pH-7.0 and pH-10.0 samples exhibited a large size plate owing to the slow reaction of the hydroxide ($OH^-$) and nickel ions ($Ni^+$) in lower pH than pH-11.5. Flower-like NiO catalysts (${\sim}4.7{\mu}m-6.6{\mu}m$) were formed owing to the fast reaction of $OH^-$ and $Ni^{2+}$ by increased $OH^-$ concentration at high pH. Thus, the flower-like morphology of NiO catalysts on NiCrAl alloy foam depends strongly on the pH of the hydrothermal solution.