• Corrosion Science and Technology
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• 제17권1호
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• pp.6-11
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• 2018

Outdoor exposure tests using of 7B04 aluminium alloy samples including plate, tensile and various SCC samples were carried out in Tuandao station, Shandong province (East of China) and Wanning station, Hainan province (South of China). Corrosion characteristics including weight loss, microstructure, tensile strength and SCC susceptibility were investigated. The corrosion rates in Tuandao and Wanning showed high to low and the corrosion rates changed to the following equation of $w=at^b$ (b<1). The corrosion of 7B04 aluminium alloy in Wanning was more serious than that in Tuandao. Pitting appeared at early stage of expose test, and it can be changed to general corrosion with test time extension. The 7B04 aluminium alloy of which specimen shapes are forging and thick plate also showed SCC (Stress corrosion cracking) in the marine atmosphere. The higher SCC sensitivity was observed in Wanning station than in Tuandao station. The 7B04 aluminium alloy with a high stress level was more sensitive to SCC. Intergranular and transgranular or a mixed mode of cracking can be observed in different marine exposure.

• 한국압력기기공학회 논문집
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• 제13권1호
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• pp.61-68
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• 2017

Reactor pressure vessel (RPV) under severe accident conditions accompanied by core melting is exposed to direct high-temperature thermal loads. Understanding the creep behavior of the material is one of the most important factors for evaluating the structural integrity at these conditions. While damage evaluation studies have been conducted on critical structures of nuclear power plants through finite element (FE) analyses considering creep behavior, for accurate creep damage evaluation, constitutive equations considered in the FE analyses may have different results depending on the time hardening and strain hardening models as well as the tertiary creep consideration. The purpose of this study is to evaluate the creep damage under severe accident conditions by using FE method for a representative domestic RPV material, SA508 Gr.3. The effect of material hardening models and constitutive equations which are the main variables were also investigated.

• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.383-388
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• 2009

Rates of solvolyses of diphenyl thiophosphorochloridate ($(PhO)_2$PSCl, 1) in ethanol, methanol, and aqueous binary mixtures incorporating ethanol, methanol, acetone and 2,2,2-trifluoroethanol (TFE) are reported. For four representative solvents, studies were made at several temperatures and activation parameters were determined. The 30 solvents gave a reasonably precise extended Grunwald-Winstein plot, correlation coefficient (R) of 0.989. The sensitivity values (l = 1.29 and m = 0.64) of diphenyl thiophosphorochloridate ($(PhO)_2$PSCl, 1) were similar to those obtained for diphenyl phosphorochloridate ($(PhO)_2$POCl, 2), diphenylphosphinyl chloride ($Ph_2$POCl, 3) and diphenylthiophosphinyl chloride ($Ph_2$PSCl, 4). As with the previously studied of 3~4 solvolyses, an $S_N$ pathway is proposed for the solvolyses of diphenyl thiophosphorochloridate (1). The activation parameters, ${\Delta}H^{\neq}\;(=11.6{\sim}13.9\;kcal{\cdot}mol^{-1})\;and\;{\Delta}S^{\neq}\; (=\;-32.1\;{\sim}\;-42.7\;cal{\cdot}mol^{-1}{\cdot}K^{-1})$, were determined, and they were in line with values expected for an $S_N$2 reaction. The large kinetic solvent isotope effects (KSIE, 2.44 in MeOH/MeOD and 3.46 in $H_2O/D_2$O) are also well explained by the proposed $S_N$2 mechanism.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2791-2796
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• 2010

In the present study, we constructed a membrane inlet assembly for selective permeation of volatile airborne organic compounds for subsequent analysis by time-of-flight mass spectrometry. The time-dependent diffusion of analytes through a $75\;{\mu}m$ thick polydimethylsiloxane membrane was measured by monitoring the ion signal after a step change in the sample concentration. The results fit well to a non-steady-state permeation equation. The diffusion coefficient, response time, and sensitivity were determined experimentally for a range of polar (halogenated) and nonpolar (aromatic) compounds. We found that the response times for several volatile organic compounds were greatly influenced by the alkyl chain length as well as the size of the substituted halogen atoms. The detection limits for benzene, ethylbenzene, and 2-propanol were 0.2 ppm, 0.1 ppm, and 3.0 ppm by volume, respectively, with a linear dynamic range greater than three orders of magnitude. These results indicate that the membrane inlet/time-of-flight mass spectrometry technique will be useful for a wide range of applications, particularly for in situ environmental monitoring.

• 산업경영시스템학회지
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• 제37권1호
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• pp.50-59
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• 2014

In this paper, we develop an efficient approach to solve a multiple-item budget-constraint newsboy problem with a reservation policy. A conventional approach for solving such problem utilizes an approximation for the evaluation of an inverse of a Gaussian cumulative density function when the argument of the function is small, and a heuristic method for finding an optimal Lagrangian multiplier. In contrast to the conventional approach, this paper proposes more accurate method of evaluating the function by using the normalization and an effective numerical integration method. We also propose an efficient way to find an optimal Lagrangian multiplier by proving that the equation for the budget-constraint is in fact a monotonically increasing function in the Lagrangian multiplier. Numerical examples are tested to show the performance of the proposed approach with emphases on the behaviors of the inverse of a Gaussian cumulative density function and the Lagrangian multiplier. By using sensitivity analysis of different budget constraints, we show that the reservation policy indeed provides greater expected profit than the classical model of not having the reservation policy.

• 약학회지
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• 제22권4호
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• pp.201-206
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• 1978

The analysis of elemental sulfur by polarography has already been reported in the literature. Only a discussion of the more important factors influencing the analysis is here presented. (1) The effects of pH on the reduction of elemental sulfur are pronounced and the use of buffered solutions for the analysis of elemental sulfur is necessary. The authors found that a pH of 4-6 was found to be reproducible polarograms by use of D.C. polarograph. However, in alkali solvents the plateau of elemental sulfur has a pronounced dip if the concentration of sulfur is as much as 30ppm. (2) A.C. polarographic method shows a very high sensitivity in the case of sulfur reduction, so that the very low concentration of sulfur can easily be determined (about 1ppm). (3) The characteristics of sulfur wave can be formulated according to Stackelberg-Hauck-Hans equation. It was found that the curve of the peak potential of elemental sulfur in A.C. polarography versus logarithm of sulfur concentration was obtained to be straight line with the slope of 29.6 millivolts. This result was well agreed with theoretical consideration. (4) It was assumed that this polarographical methods were applicable to micro-analysis of elemental sulfur in crude oil and its petrochemical products, precipitated sulfur, and sulfur ointments with accuracy and rapidity.

• 한국농공학회논문집
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• 제52권6호
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• pp.19-26
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• 2010

Batch experiments were conducted to investigate growth and nutrient removal performance of microalgae Chlorella vulgaris by using piggery wastewater in different concentration of pollutants and the common growth models (logistic, Gompertz and Richards) were applied to compare microalgal growth parameters. Removal of nitrogen (N) and phosphorus (P) by Chlorella vulgaris showed correlation with biomass increase, implying nutrient uptake coupled with microalgae growth. The higher the levels of suspended solids (SS), COD and ammonia nitrogen were in the wastewater, the worse growth of Chlorella vulgaris was observed, showing the occurrence of growth inhibition in higher concentration of those pollutants. The growth parameters were estimated by non-linear regression of three growth curves for comparative analyses. Determination of growth parameters were more accurate with population as a variable than the logarithm of population in terms of R square. Richards model represented better fit comparing with logistic and Gompertz model. However, Richards model showed some complexity and sensitivity in calculation. In the cases tested, both logistic and Gompertz equation were proper to describe the growth of microalgae on piggery wastewater as well as easy to application.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2001년도 추계학술대회논문집 II
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• pp.1235-1241
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• 2001

Pantograph design process must be considered in terms of stability of aerodynamics and reduction of aeroacoustics. Furthermore Pantograph needs to be insensible to severe circumstance condition like typhoon, tunnel, a change of season. In this paper, robust design of panhead sections is conducted based on the Taguchi's design of experiment method. In the aeroacoustic noise analysis, an acoustic analogy using the Ffowcs Williams and Hawkings (FW-H) equation is used to calculate the flow induced sound pressure level. From the near-field CFD analysis data, the far-field noise is predicted at the positions of 25m away from panhead contact strips. Based on aerodynamic (CFD) and aeroacoustic (FW-H) analysis data, the optimal sizing and positioning ofpanhead elements are determined using robust design optimization method. Design parameters such as thickness, length and radius are controllable factors, while outdoor air temperature and atmospheric pressure are considered as uncontrollable factors in the context of Taguchi's approach. A number of CFD simulation and aeroacoustic analysis are performed based on orthogonal arrays. Using a parameter design procedure associated with signal-to-noise (SIN) ratio and sensitivity analysis, an optimal level of design parameters are extracted to minimize the disconnection ratio between contact strips and catenary system, and reduce the far-field aeroacoustic noise.

• 한국소음진동공학회논문집
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• 제17권3호
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• pp.257-263
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• 2007

Detection of structural damage is an inverse problem in structural engineering. There are three main questions in the damage detection: existence, location and extent of the damage. In concept, the natural frequency and mode shapes of any structure must satisfy an eigenvalue problem. But, if a potential damage exists in a structure, an error resulting from the substitution of the refined analytical finite element model and measured modal data into the structural eigenvalue equation will occur, which is called the residual modal forces, and can be used as an indicator of potential damage in a structure. In this study, a useful damage detection method is proposed and compared with other two methods. Two degree-of-freedom system and Cantilever beam are used to demonstrate the approach. And the results of three introduced method are compared.

• 한국기계가공학회지
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• 제18권11호
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• pp.57-62
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• 2019

This paper describes the prediction of eigenfrequencies due to changes in stiffness and mass in the connection area of the lap joint beam in terms of linear and torsional stiffness as well as connection length. The sensitivities of mass and stiffness in the finite element model were derived by using the first-order differential and algebraic equation and were thereafter applied to obtain new natural frequencies that were compared with theoretical exact solutions. Newly predicted natural frequencies due to only a change in stiffness were in relatively good agreement with those in lower modes for rigid joints, while further investigation was needed for flexible joints. On the other hand, only the change in mass resulted in a large discrepancy in the flexible joint case. It may be strongly anticipated that this study will provide a useful tool for estimating modal parameters by change in any design variable, such as the structural dimension, material property, or connection type for a large-scale structure, even though the proposed methodology is currently limited to a jointed beam.