• Title/Summary/Keyword: Self-reaction

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A study on the development of self-healing concrete and repair materials with the resistance to sulfuric acid attack (내황산성 자기치유 콘크리트 및 단면복구재 개발에 관한 연구)

  • Bang, Sin-Young;Kim, Jeong-Mi;Ahn, Tae-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.84-85
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    • 2015
  • The aim of this study is to develop crack self-healing concrete and repair materials with the sulfate resistance using geo-materials and by-products for practical industrial application. Research has been done on the healing of cracks in aged concrete, but it seems that very little is known about the actual healing mechanism and its conditions. In this research, the essential properties of geo-materials with pozzolanic reaction for self-healing were analyzed and discussed.

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Effect of Coflow Air Velocity on Heat-loss-induced Self-excitation in Laminar Lifted Propane Coflow-Jet Flames Diluted with Nitrogen (질소로 희석된 프로판 동축류 층류 제트 부상화염에서 열손실에 의한 자기진동에 대한 동축류 속도 효과)

  • Lee, Won-June;Yoon, Sung-Hwan;Park, Jeong;Kwon, Oh-Boong;Park, Jong-Ho;Kim, Tae-Hyung
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.48-57
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    • 2012
  • Laminar lifted propane coflow-jet flames diluted with nitrogen were experimentally investigated to determine heat-loss-related self-excitation regimes in the flame stability map and elucidate the individual flame characteristics. There exists a critical lift-off height over which flame-stabilizing effect becomes minor, thereby causing a normal heat-loss-induced self-excitation with O(0.01 Hz). Air-coflowing can suppress the normal heat-loss-induced self-excitation through increase of a Peclet number; meanwhile it can enhance the normal heat-lossinduced self-excitation through reducing fuel concentration gradient and thereby decreasing the reaction rate of trailing diffusion flame. Below the critical lift-off height. the effect of flame stabilization is superior, leading to a coflow-modulated heat-loss-induced self-excitation with O(0.001 Hz). Over the critical lift-off height, the effect of reducing fuel concentration gradient is pronounced, so that the normal heat-loss-induced self-excitation is restored. A newly found prompt self-excitation, observed prior to a heat-loss-induced flame blowout, is discussed. Heat-loss-related self-excitations, obtained laminar lifted propane coflow-jet flames diluted with nitrogen, were characterized by the functional dependency of Strouhal number on related parameters. The critical lift-off height was also reasonably characterized by Peclet number and fuel mole fraction.

Curing and Coating Properties of Photo-Curable Self-Photoinitiating Acrylate (광경화형 자가광개시 아크릴레이트의 경화특성 및 도막물성)

  • Han, A-Ram;Hong, Jin-Who;Kim, Hyun-Kyoung
    • Journal of Adhesion and Interface
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    • v.15 no.1
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    • pp.22-30
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    • 2014
  • Self-photoinitiating acrylate (SPIA) which can undergo self-initiation under UV irradiation was synthesized by a Michael addition in the presence of a base catalyst. The SPIA polymerizations were investigated by photo-differential scanning calorimeter (photo-DSC) and surface physical properties such as pendulum hardness and pencil hardness. The results showed that the SPIA can cure upon UV irradiation by itself without a photoinitiator. But we found out that both the curing rate and the conversion were too low for the self-curing reaction of SPIA. In order to improve the SPIA curing properties, we introduced the SPIA/cationic hybrid system and observed the effects of the addition of commercial free radical type monomer and photoinitiator on the curing behaviors. SPIA/cationic hybrid system was the best suitable to improve the SPIA curing properties. The kinetic analysis indicated that the cationic monomer and photoinitiator apparently accelerated the cure reaction and rate of the hybrid SPIA system, mostly due to the synergistic effect of cationic monomer and photoinitiator increasing the mobility of active species and the generation of reactive species (free radical, cation) during the photopolymerization process. The physical properties showed that, unlike typical free radical system, the hybrid systems did not show oxygen inhibition effect because of cationic reaction on the coating surface.

The research regarding the self concept of part dental hygienes students (일부 치위생과 학생의 자아개념에 관한 연구)

  • Jung, Eun-Kyung
    • Journal of Korean society of Dental Hygiene
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    • v.6 no.3
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    • pp.219-228
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    • 2006
  • The research which it sees against the self concept of part dental hygienes students from the hazard which it examines dental hygienes which is located on Kyoung-Buk and students 318 people in the object un-signature it enforced a research with the entry method which it got a same result. 1. From general characteristics of part hygiene students "the employment went well from the motive which selects hygiene" and it appeared most highly. The employment will go well and the social advance will do and ease when seeing specially with characteristics of college, it has an corresponding with the fact that is a possibility of employment.. 2. The average score against the self concept of part hygiene students "me it is an existence which is isolated from this world and nothing to do with the others". It appeared most highly with 3.52. The negation self concept appeared more highly affirmative self concept than. 3. To self concept and grade, religion, health condition, hygiene selection motive, subject record and native high school of part hygiene students the difference which considers statistically did not appear(p>0.05). However it tries to observe the self concept which it follows subject satisfactory degree, it is very unsatisfactorily(3.37) with it is unsatisfactorily(3.16) gaps it was not visible the difference which considers statistically, it is very satisfied(3.37) with the difference which considers statistically it was visible(p<0.05). Students the affirmative reaction is correct phenomenon in order to establish a specialty intuition. 4. When self concept and record and the subject satisfaction sees a interrelation for, Between self concept subject satisfaction is appeare big affirmative interrelation(r=0.331) and the subject record and subject satisfaction just interrelation appeared as well(r=0.282) all they considered statistically and appeared.(p=0.000) but to self concept and subject record for the interrelation did not appear. Negation self concept of part hygiene students appears more strongly than affirmative one, And studying for self concept of the students, it leads through the program which is the possibility to pull affirmatively is demanded.

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Evaluation of Tolerance of Some Elemental Impurities on Performance of Pb-Ca-Sn Positive Pole Grids of Lead-Acid Batteries

  • Abd El-Rahman, H.A.;Gad-Allah, A.G.;Salih, S.A.;Abd El-Wahab, A.M.
    • Journal of Electrochemical Science and Technology
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    • v.3 no.3
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    • pp.123-134
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    • 2012
  • The electrochemical performance of positive pole grids of lead-acid batteries made of Pb-0.08%Ca-1.1%Sn alloys without and with 0.1 wt% of each of Cu, As or Sb and with 0.1 wt% of Cu, As and Sb combined was investigated by electrochemical methods in 4.0 M $H_2SO_4$. The corrodibility of alloys under open-circuit conditions and constant current charging of the positive pole, the positive pole gassing and the self-discharge of the charged positive pole were studied. All impurities (Cu, As, Sb) were found to decrease the corrosion resistance, $R_{corr}$ after 1/2 hour corrosion, but after 24 hours an improvement in $R_{corr}$ was recorded for Sb containing alloy and the alloy with the three impurities combined. While an individual impurity was found to enhance oxygen evolution reaction, the impurities combined significantly inhibition this reaction and the related water loss problem was improved. Impedance results were found helpful in identification of the species involved in the charging/discharging and the self-discharge of the positive pole. Impurities individually or combined were found to increase the self-discharge during polarization (33-68%), where Sb containing alloy was the worst and impurities combined alloy was the least. The corrosion of the positive pole grid in the constant current charging was found to increase in the presence of impurities by 5-10%. Under open-circuit, the self-discharge of the charged positive grids was found to increase significantly (92-212%) in the presence of impurities, with Sb-containing alloy was the worst. The important result of the study is that the harmful effect of the studied impurities combined was not additive but sometimes lesser than any individual impurity.

Microcapsules Containing Self-Healing Agent with Red Dye (빨간 색소를 함유한 자가치료제 마이크로캡슐)

  • Guang, Yang;Lee, Jong Keun
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.356-361
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    • 2013
  • Microcapsules of two different self-healing agents, 5-ethylidene-2-norbornene (ENB) and ENB with a crosslinker, surrounded by a melamine-urea-formaldehyde shell were manufactured. In this work, a red dye was incorporated into the self-healing agents as a tracer for better visual observations. It revealed that the incorporation of a red dye into self-healing agents did not disturb the formation of microcapsules from the examination of thermal resistance, particle size/size distribution and morphology of the resulting microcapsules. Releasing of self-healing liquid into the induced crack from ruptured microcapsules and filling between crack planes were observed using an optical microscope. Also observed was the reaction of filled healing agent with embedded Grubbs' catalyst in an epoxy coating layer.

Evaluation of an Education Program for Public Health Service Workers in Public Hospitals: Learning Achievement and Satisfaction Levels (공공병원 공공보건의료사업 담당자를 위한 교육프로그램이 학습목표 성취도와 교육반응도에 미치는 효과)

  • Hwang, Eun-Jeong;Moon, Jung-Joo
    • Korean Journal of Health Education and Promotion
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    • v.28 no.4
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    • pp.27-37
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    • 2011
  • Objectives: This study aims to evaluate the outcomes of an education program for public health service workers in public hospitals, utilizing the Kirkpatrick model. Methods: The study participants were 118 staff in 48 public hospitals. Of the stages in the Kirkpatrick model(reaction, learning, behavior, and result), reaction and learning stages were analyzed in this study. A 10-item self-evaluation questionnaire was used to measure satisfaction level for the reaction, and achievement of learning purposes for the learning. The education program consisted of general courses and special two tract courses(Tract A: chronic diseases, Tract B: health promotion). Results: The highest score for reaction was for Tract A(score=4.4), whilst the lowest score for reaction was for lecture(score=3.0). Learning achievement was significantly different between pre-education and post-education(p<0.01), except for health technicians. Conclusions: The results of this study could be utilized to develop effective systematic education programs for public health service workers in public hospitals.

A Study on Match and Mismatch DNA Hybridization properties Using DNA Hybridization Detection Sensor (DNA Hybridization 검출 센서를 이용한 매치 및 미스매치 DNA hybridization 특성 연구)

  • Kim, Do-Kyun;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.89-91
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    • 2003
  • The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and other application area. So, the improvement of DNA detection system is very important for the determination of this hybridization reaction. In this study, we report the characterization of the probe and target oligonucleotide hybridization reaction using the evanescent field microscopy. First, we have fabricated DNA chip microarray. The particles which were immobilized oligonucleotides were arranged by the random fluidic self-assembly on the pattern chips, using hydrophobic interaction. Second, we have detected DNA hybridization reaction using evanescent field microscopy. The 5'-biotinylated probe oligonucleotides were immobilized on the surface of DNA chip microarray and the hybridization reaction with the Rhodamine conjugated target oligonucleotide was excited fluorescence generated on the evanescent field microscopy. In the foundation of this result, we could be employed as the basis of a probe olidonucleotide, capable of detecting the target oligonucleotide and monitoring it in a large analyte concentration range and various mismatching condition.

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Real-Time Detection of DNA Hybridization Assay by Using Evanescent Field Microscopy

  • Kim, Do-Kyun;Choi, Yong-Sung;Murakami, Yuji;Tamiya, Eiichi;Kwon, Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.85-90
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    • 2001
  • The determination of DNA hybridization reaction can apply the molecular biology research, clinic diagnostics, bioengineering, environment monitoring, food science and other application area. So, the improvement of DNA detection system is very important for the determination of this hybridization reaction. In this study, we report the characterization of the probe and target oligonucleotide hybridization reaction using the evanescent field microscopy. First, we have fabricated DNA chip microarray. The particles which were immobilized oligonucleotides were arranged by the random fluidic self-assembly on the pattern chips, using hydrophobic interaction. Second, we have detected DNA hybridization reaction using evanescent field microscopy. The 5'-biotinylated probe oligonucleotides were immobilized on the surface of DNA chip microarray and the hybridization reaction with the Rhodamine conjugated target oligonucleotide was excited fluorescence generated on the evanescent field microscopy. In the foundation of this result, we could be employed as the basis of a probe olidonucleotide, capable of detecting the target oligonucleotide and monitoring it in a large analyte concentration range and various mismatching condition.

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Thermal Atomic Layer Etching of the Thin Films: A Review (열 원자층 식각법을 이용한 박막 재료 식각 연구)

  • Hyeonhui Jo;Seo Hyun Lee;Eun Seo Youn;Ji Eun Seo;Jin Woo Lee;Dong Hoon Han;Seo Ah Nam;Jeong Hwan Han
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.53-64
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    • 2023
  • Atomic layer etching (ALE) is a promising technique with atomic-level thickness controllability and high selectivity based on self-limiting surface reactions. ALE is performed by sequential exposure of the film surface to reactants, which results in surface modification and release of volatile species. Among the various ALE methods, thermal ALE involves a thermally activated reaction by employing gas species to release the modified surface without using energetic species, such as accelerated ions and neutral beams. In this study, the basic principle and surface reaction mechanisms of thermal ALE?processes, including "fluorination-ligand exchange reaction", "conversion-etch reaction", "conversion-fluorination reaction", "oxidation-fluorination reaction", "oxidation-ligand exchange reaction", and "oxidation-conversion-fluorination reaction" are described. In addition, the reported thermal ALE processes for the removal of various oxides, metals, and nitrides are presented.