• Title/Summary/Keyword: Self-aggregates

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Contribution of lysine-containing cationic domains to thermally-induced phase transition of elastin-like proteins and their sensitivity to different stimuli

  • Jeon, Won-Bae
    • BMB Reports
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    • v.44 no.1
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    • pp.22-27
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    • 2011
  • A series of elastin-like proteins, $SKGPG[V(VKG)_3VKVPG]_n$-(ELP1-90)WP (n = 1, 2, 3, and 4), were biosynthesized based on the hydrophobic and lysine linkage domains of tropoelastin. The formation of self-assembled hydrophobic aggregates was monitored in order to determine the influence of cationic segments on phase transition properties as well as the sensitivity to changes in salt and pH. The thermal transition profiles of the proteins fused with only one or two cationic blocks (n = 1 or 2) were similar to that of the counterpart ELP1-90. In contrast, diblock proteins that contain 3 and 4 cationic blocks displayed a triphasic profile and no transition, respectively. Upon increasing the salt concentration and pH, a stimulus-induced phase transition from a soluble conformation to an insoluble aggregate was observed. The effects of cationic segments on the stimuli sensitivity of cationic bimodal ELPs were interpreted in terms of their structural and molecular characteristics.

Fabrication of Single Crystal Poly(3,4-ethylenedioxythiophene) Nanowire Arrays

  • Cho, Bo-Ram;Sung, Myung-M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.537-537
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    • 2012
  • We have studied a fabrication of vapor phase polymerized Poly(3,4-ethylenedioxythiophene) (PEDOT) nanowire arrays for the first time. The vapor-phase polymerization (VPP) technique is a bottom-up processing method that utilizes the organic arrangement of macromolecules to easily produce ordered aggregates, including on the nanoscale, or prepare thin films of self-assembled molecules, micropatterns, or modified microstructures of pure conducting polymers. Also, liquid-bridge-mediated nanotransfer molding (LB-nTM), which was reported as a new direct patterning method recently, is for the arrayed formation of two- or three-dimensional structures with feature sizes as small as tens of nanometers over large areas up to 4 inches across and is based on the direct transfer of various materials from a mould to a substrate through a liquid bridge between them. The PEDOT nanowires grown by VPP method and transferred on a substrate to use LB-nTM method have been fabricated to single crystal PEDOT nanowires investigated Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Selected Area Electron Diffraction (SAED), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and electrical properties.

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The Formation and Control of the Biofilm in Dairy Industry: A Review (유가공 산업에서의 바이오필름 형성과 제어관리: 총설)

  • Chung, Yong Hwa;Chung, Dae Hak;Baick, Seung Chun
    • Journal of Dairy Science and Biotechnology
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    • v.33 no.2
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    • pp.139-151
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    • 2015
  • Biofilms are aggregates of microorganisms present in a self-produced matrix of extracellular polymeric substance (EPS) adhered to a surface. Formation of a biofilm in the environment on farms and in dairy plants comprises several stages: attachment, growth (development), and detachment. Generally, biofilms are harmful to humans and need to be controlled. Stainless steel (SS) surfaces that are untreated or are scratched comprise substrata that are especially vulnerable to biofilm formation; therefore, SS surfaces should be polished and sanitized. Various approaches are available for the destruction of biofilms; cleaning-in-place (CIP) is the method mainly used in dairy plants. Further study on optimum detergents, cleaning conditions, and methods for this purpose is needed.

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The Physical Properties of Granite Microfines and the Workability of Mortar with Granite Microfines

  • Koehler, Eric;Hahn, Michael De Moya;Trachet, Alison;Rached, Marc;Choi, Jae Jin;Fowler, David
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.69-74
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    • 2009
  • This paper summarizes the analysis of granite microfines from California for use in portland cement concrete. For reference, the granite microfines were compared to microfines used in previous International Center for Aggregates Research(ICAR) projects. The particle shape characteristics, based on the packing density results, were assessed and apparent clay content, based on the methylene blue value test, was evaluated. Also, the physical properties of the microfines were confirmed in self-consolidating mortar mixtures.

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Theoretical and experimental investigation of piezoresistivity of brass fiber reinforced concrete

  • Mugisha, Aurore;Teomete, Egemen
    • Computers and Concrete
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    • v.23 no.6
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    • pp.399-408
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    • 2019
  • Structural health monitoring is important for the safety of lives and asset management. In this study, numerical models were developed for the piezoresistive behavior of smart concrete based on finite element (FE) method. Finite element models were calibrated with experimental data collected from compression test. The compression test was performed on smart concrete cube specimens with 75 mm dimensions. Smart concrete was made of cement CEM II 42.5 R, silica fume, fine and coarse crushed limestone aggregates, brass fibers and plasticizer. During the compression test, electrical resistance change and compressive strain measurements were conducted simultaneously. Smart concrete had a strong linear relationship between strain and electrical resistance change due to its piezoresistive function. The piezoresistivity of the smart concrete was modeled by FE method. Twenty-noded solid brick elements were used to model the smart concrete specimens in the finite element platform of Ansys. The numerical results were determined for strain induced resistivity change. The electrical resistivity of simulated smart concrete decreased with applied strain, as found in experimental investigation. The numerical findings are in good agreement with the experimental results.

Comparison of rheological properties containing natural and crushed sands in self-compacting concretes (잔골재 종류에 따른 고유동 콘크리트의 유동 특성)

  • Lee, Keun-Su;Choi, Yeol;Jung, Woong;Lee, Jae-Ik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.365-368
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    • 2008
  • In recent, the crushed sand as a fine aggregate has increasingly used for concrete industry due to the shortage of natural sand from river and the growing demand for protection of natural environments. Aggregates may have a significant influence on the properties of self-compacting concrete (SCC) including self-compacting mortar (SCM). The rheological properties of SCC and SCM using crushed sand as a fine aggregate has been compared to that of SCC and SCM using natural sand and mixed sand of both. Test results indicate that the yield stress of SCM containing 50% of mixed sand present higher than those prepared with natural sand and crushed sand according to SP content. the slump values of SCC with natural sand have approximately 5-15% higher than those of SCC with crushed sand. Also the L-box test values ($H_2/H_1$) of SCC with natural sand have approximately 20-30 higher than those of SCC with crushed sand under same water/cement ratio and viscosity enhancing admixture.

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Incorporation of CrusHed Sands and Tunisian Desert Sands in the Composition of Self Compacting Concretes Part I: Study of Formulation

  • Rmili, Abdelhamid;Ouezdou, Mongi Ben;Added, Mhamed;Ghorbel, Elhem
    • International Journal of Concrete Structures and Materials
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    • v.3 no.1
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    • pp.3-9
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    • 2009
  • This paper examines the incorporation of the crushed sand (CS) and desert sand (DS) in the formation of self compacting concrete (SCC). These sands have been substituted for the rolled sand (RS), which is currently the only sand used in concretes and which is likely to run out in our country. DS, which comes from the Tunisian Sahara in the south, is characterized by a tight distribution of grains size. CS, a by-product of careers containing a significant amount of fines up to 15%, is characterized by a spread out granulometry having a maximum diameter of around 5mm. These two sands are considered as aggregates for the SCC. This first part of the study consists in analyzing the influence of the type of sand on the parameters of composition of the SCC. These sands consist of several combinations of 3 sands (DS, CS and RS). The method of formulation of the adopted SCC is based on the filling of the granular void by the paste. The CS substitution to the RS made it possible, for all the proportions, to decrease the granular voids, to increase the compactness of the mixture and to decrease the water and adding fillers proportioning. These results were also obtained for a moderate substitution of DS/CS (< 40%) and a weak ratio of DS/RS (20%). For higher proportions, the addition of DS to CS or RS did not improve the physical characteristics of the SCC granular mixture.

Effect of rubber fiber size fraction on static and impact behavior of self-compacting concrete

  • Thakare, Akshay A.;Siddique, Salman;Singh, Amardeep;Gupta, Trilok;Chaudhary, Sandeep
    • Advances in concrete construction
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    • v.13 no.6
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    • pp.433-450
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    • 2022
  • The conventional disposal methods of waste tires are harmful to the environment. Moreover, the recycling/reuse of waste tires in domestic and industrial applications is limited due to parent product's quality control and environmental concerns. Additionally, the recycling industry often prefers powdered rubber particles (<0.60 mm). However, the processing of waste tires yields both powdered and coarser (>0.60 mm) size fractions. Reprocessing of coarser rubber requires higher energy increasing the product cost. Therefore, the waste tire rubber (WTR) less favored by the recycling industry is encouraged for use in construction products as one of the environment-friendly disposal methods. In this study, WTR fiber >0.60 mm size fraction is collected from the industry and sorted into 0.60-1.18, 1.18-2.36-, and 2.36-4.75-mm sizes. The effects of different fiber size fractions are studied by incorporating it as fine aggregates at 10%, 20%, and 30% in the self-compacting rubberized concrete (SCRC). The experimental investigations are carried out by performing fresh and hardened state tests. As the fresh state tests, the slump-flow, T500, V-funnel, and L-box are performed. As the hardened state tests, the scanning electron microscope, compressive strength, flexural strength and split tensile strength tests are conducted. Also, the water absorption, porosity, and ultrasonic pulse velocity tests are performed to measure durability. Furthermore, SCRC's energy absorption capacity is evaluated using the falling weight impact test. The statistical significance of content and size fraction of WTR fiber on SCRC is evaluated using the analysis of variance (ANOVA). As the general conclusion, implementation of various size fraction WTR fiber as fine aggregate showed potential for producing concrete for construction applications. Thus, use of WTR fiber in concrete is suggested for safe, and feasible waste tire disposal.

Mechanical properties of sustainable green self-compacting concrete incorporating recycled waste PET: A state-of-the-art review

  • Shireen T. Saadullah;James H. Haido;Yaman S.S. Al-Kamaki
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.35-57
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    • 2023
  • Majority of the plastic produced each year is being disposed in land after single-use, which becomes waste and takes up a lot of storage space. Therefore, there is an urgent need to find alternative solutions instead of disposal. Recycling and reusing the PET plastic waste as aggregate replacement and fiber in concrete production can be one of the eco- friendly methods as there is a great demand for concrete around the world, especially in developing countries by raising human awareness of the environment, the economy, and Carbon dioxide (CO2) emissions. Self-compacting concrete (SCC) is a key development in concrete technology that offers a number of attractive features over traditional concrete applications. Recently, in order to improve its durability and prevent such plastics from directly contacting the environment, various kinds of plastics have been added. This review article summarizes the latest evident on the performance of SCC containing recycled PET as eco-friendly aggregates and fiber. Moreover, it highlights the influence of substitution content, shape, length, and size on the fresh and properties of SCC incorporating PET plastic. Based on the findings of the articles that were reviewed for this study, it is observed that SCC made of PET plastic (PETSCC) can be employed in construction era owing to its acceptable mechanical and fresh properties. On the other hand, it is concluded that owing to the lightweight nature of plastic aggregate, Reusing PET waste in the construction application is an effective approach to reduces the earthquake risk of a building.

Evaluation Method of Healing Performance of Self-Healing Materials Based on Equivalent Crack Width (등가균열폭에 기반한 자기치유 재료의 치유성능 평가 방법)

  • Lee, Woong-Jong;Kim, Hyung-Suk;Choi, Sung;Park, Byung-Sun;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.383-388
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    • 2021
  • In this study, constant head water permeability test was adopted to evaluate self-healing performance of mortars containing inorganic healing materials which consist of blast furnace slag, sodium sulfate and anhydrite. Clinker powder and sand replaced for a part of cement and fine aggregates. On constant head water permeability test for self-healing mortars, unit water flow rate of mortar specimens were measured according to crack width and healing period. As a result of evaluating the healing performance of self-healing mortar, it was confirmed that with the initial crack width of 0.3mm, the healing rate at healing period of 28 days increased by more than 30%p compared to plain mortar, greatly improving the healing performance. Furthermore, the coefficient(α) which was estimated from the relationship between crack width and unit water flow rate was used for calculating equivalent crack width. By analyzing the correlation of healing rate and equivalent crack width, the time and initial crack width attaining healing target crack width were predicted.