• 제목/요약/키워드: Self diffusion

검색결과 386건 처리시간 0.03초

해저유기퇴적물 수거시스템의 실험 및 수치해석 (Experiments and Numerical Analysis on a System for Collecting Organic Sediment from Seabed)

  • 김도정;박제웅;정우철;김성근
    • 해양환경안전학회지
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    • 제14권1호
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    • pp.15-20
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    • 2008
  • 오염된 퇴적물은 연안의 생태계 파괴에 근본적인 원인이 되고 있음에 따라, 선진 외국에서는 1960년대부터 이러한 문제 해결을 위한 새로울 기술개발을 진행하여 오고 있다. 본 연구에서는 유기퇴적물 수거를 위한 시스템 설계 및 개발에 있어서 오탁확산에 의한 2차 오염을 방지하거나 최소화 할 수 있는 Pilot 규모 형태의 흡입식 펌프 준설 시스템을 설계 제작하였으며, 시스템의 성능시험을 통한 적용 가능성을 제시하였다. 시스템 최적화를 위하여 수치해석기법을 통한 퇴적물 수거 시스템의 형상에 대한 성능평가를 수행하고, 제작 시스템의 성능시험에 있어서는 시스템의 정지 상태와 이동 상태에서의 퇴적물 수거 성능에 대한 실험을 수행하였다. 본 연구를 통하여 해저 유기퇴적물의 상부만을 준설할 수 있는 시스템의 개발 가능성을 확인하였다.

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배추 생산자들의 신종자 이용 행태에 관한 연구 (Study on the Chinese cabbage producers' using patterns about a new variety of seed)

  • 홍승지;김용규
    • 농업과학연구
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    • 제38권3호
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    • pp.549-557
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    • 2011
  • Chinese cabbage is a staple food to Korean, which has the high degree of self-sufficiency and worldwide breeding technique in the aspect of seed. However, the producers' competitiveness has been decreasing after the agricultural product market was open. In order to cope with this problem, the government introduced some policies for promoting seed industry in 2007 to reflect producer's needs for high quality seeds of Chinese cabbage. These policies will be a good opportunity for producers to secure and promote the producers' competitiveness against low-price importing Chinese cabbage. In this aspect it is very important to know how well these policies are established and what Chinese cabbage farmers want in regard to a new variety of Chinese cabbage seed. This study was carried out to look over the Chinese cabbage producers' using pattern about a new variety of seed and show some directions for efficient way of diffusion of a new variety of seed to producers using a survey research. The main results are as follows. The producers thought the characteristics of a new variety of seed most important factor compared to other factors such as the seed price, and easiness of cabbage sales when they choose a seed. Also, the 65% of respondents were willing to accept a new variety of seed and thought the government support for an exhibition field and diffusing public information about a new variety of Chinese cabbage seed are important in accepting a new variety of seed.

Pilgering 법에 의해 제조된 Zr-Nb-O 및 Zr-Nb-Sn-Fe 합금 피복관의 원주방향 Creep 거동 (Circumferential Creep Behaviors of Zr-Nb-O and Zr-Nb-Sn-Fe Alloy Cladding Tubes Manufactured by Pilgering)

  • 이상용;고산;박용권;김규태;최재하;홍순익
    • 소성∙가공
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    • 제17권5호
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    • pp.364-372
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    • 2008
  • In this study, the circumferential creep behaviors ofpilgered advanced Zirconium alloy tubes such as Zr-Nb-O and Zr-Nb-Sn-Fe were investigated in the temperature range of $400\sim500^{\circ}C$ and in the stress range of 80$\sim$150MPa. The test results indicate that the stress exponent for the steady-state creep rate of the Zr-Nb-Sn-Fe alloy decreases with the increase of stress(from 6$\sim$7 to 4), while that of the Zr-Nb-O alloy is nearly independent of stress(5$\sim$6). The activation energy of creep deformation is found to be nearly the same as the activation energy for Zr self diffusion. This indicates that the creep deformation may be controlled by dislocation climb mechanism in Zr-Nb-O. On the other hand, the transition of stress exponent(from 6-7 to 4) in Zr-Nb Sn-Fe strongly suggests the transition of the rate controlling mechanism at high stresses. The lower stress exponent at high stresses in Zr-Nb-Sn-Fe can be explained by the dynamic deformation aging effect caused by interaction of dislocations with Sn substitutional atoms.

대학생 절주교육 프로그램(과음없는 캠퍼스 만들기) 개발: Intervention Mapping과 Transtheoretical Model의 적용 (Development of "Drink Smart" Alcohol Education Program for University Students: Application of the Intervention Mapping and Transtheoretical Model)

  • 김혜경;김명;이은희;권은주;조한익
    • 보건교육건강증진학회지
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    • 제28권5호
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    • pp.145-160
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    • 2011
  • Objectives: This study attempted to apply the Intervention mapping and Transtheoretical models to develop a program to promote moderate alcohol drinking in university students. Methods: Surveyed data from 1,137 university students were analyzed to identify personal and environmental determinants for alcohol drinking. Based on these determinants, program objectives were established. Crossing the objectives with related important determinants resulted in matrices of learning objectives for which educational strategies were developed. Subsequently, an intervention program were designed to achieve those objectives. Results: Identified personal determinants included awareness, attitudes, self-efficacy and behavioral skills. Environmental determinants were binge drinking behaviors of family members and peers, and social pressure for drinking. Program, impact and learning objectives were developed to change the identified determinants. Program activities included provision of information on positive and negative consequences of binge drinking, opportunities for assessing one's drinking pattern, increasing outcome expectancies of and skill building for monitoring drinking, resisting peer pressure and managing stress. To facilitate adoption and maintenance of the program, an intervention diffusion plan was suggested. An evaluation plan was developed by utilizing RE-AIM framework. Conclusions: In order to expand evidence bases for effective theory-based programs, the developed program should be tested in diverse university settings.

AZ31마그네슘 합금의 고온특성 및 크리이프 변형기구에 관한연구 (A Study on the Characteristics of High Temperature and Mechanisms for Creep Deformation of AZ31 Mg Alloy)

  • 강대민;안정오
    • 동력기계공학회지
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    • 제9권4호
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    • pp.96-101
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    • 2005
  • Magnesium alloys have been widely used for many structural components of automobiles and aircraft because of high specific strength and good cast ability in spite of hexagonal closed-packed crystal structure of pure magnesium. In this study, uniaxial tension tests at high temperature and creep tests are done in order to investigate the characteristics of high temperature and mechanisms for creep deformation of AZ31 Mg alloy. Yield stress and ultimate tensile stress decreased with increasing temperature, but elongation increased from results of uniaxial tension test at high temperature. The apparent activation energy Qc, the applied stress exponent n and rupture life have been determined during creep of AZ31 Mg alloy over the temperature range of 473K to 573K and stress range of 23.42 MPa to 93.59 MPa, respectively, in order to investigate the creep behavior. Constant load creep tests were carried out in the equipment including automatic temperature controller, whose data are sent to computer. At around the temperature of $473K{\sim}493K$ and under the stress level of $62.43{\sim}93.59%MPa$, and again at around the temperature of $553K{\sim}573K$ and under the stress level of $23.42{\sim}39.00MPa$, the creep behavior obeyed a simple power-law relating steady state creep rate to applied stress and the activation energy for the creep deformation was nearly equal, respectively, and a little low to that of the self diffusion of Mg alloy including aluminum. Also rupture surfaces at high temperature have had bigger dimples than those at lower temperature by SEM.

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HSLA-100강 및 HY-100강의 응력제거처리 균열에 관한 연구 (A Study on the Stress Relief Cracking of HSLA-100 and HY-100 steels)

  • 박태원;심인옥;김영우;강정윤
    • Journal of Welding and Joining
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    • 제14권3호
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    • pp.48-57
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    • 1996
  • A study was made to examine the characteristics of base metal and stress relief cracking(SRC) of heat affected zone(HAZ) for HY-100 and Cu-bearing HSLA-100 steels. The Gleeble thermal/mechanical simulator was used to simulate the SRC/HAZ. The details of mechanical properties of base plate and SRC tested specimens were studied by impact test, optical microscopy and scanning electron microscopy. The specimens were aged at $650^{\circ}C$ for HSLA-100 steel and at $660^{\circ}C$ for HY-100 steel and thermal cycled from $1350^{\circ}C$ to $25^{\circ}C$ with a cooling time of $\Delta$t_${800^{circ}C/500^{circ}C}$=21sec. corresponds to the heat input of 30kJ/cm. The thermal cycled specimens were stressed to a predetermined level of 248~600MPa and then reheated to the stress relief temperatures of $570~620^{\circ}C$. The time to failure$(t_f)$ at a given stress level was used as a measure of SRC susceptibility. The strength, elongation and impact toughness of base plate were greater in HSLA-100 steel than in HY-100 steel. The time to failure was decreased with increasing temperature and/or stress. HSLA-100 steel was more susceptible to stress relief cracking than HY-100 steel under same conditions. It is thought to be resulted from the precipitation of $\varepsilon$-Cu phase by dynamic self diffusion of solute atoms. By the precipitation of $\varepsilon$-Cu phase, the differential strengthening of grain interior relative to grain boundary may be greater in the Cu-bearing HSLA-100 steel than in HY-100 steel. Therefore, greater strain concentration at grain boundary of HSLA-100 steel results in the increased SRC susceptibility. The activation energies for SRC of HSLA-100 steel are 103.9kcal/mal for 387MPa and 87.6kcal/mol for 437MPa and that of HY-100 steel is 129.2kcal/mol for 437MPa.

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HSLA-100강 및 HY-100강의 응력제거처리 균열에 관한 연구 (A Study on the Stress Relief Cracking of HSLA-100 and HY-100 Steels)

  • 박태원;심인옥;김영우;강정윤
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 1996년도 특별강연 및 춘계학술발표 개요집
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    • pp.186-189
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    • 1996
  • A study was made to examine the characteristics of base metal and stress relief cracking(SRC) of heat affected zone(HAZ) for HY-100 and Cu-bearing HSLA-100 steels. The Gleeble thermal/mechanical simulator was used to simulate the SRC/HAZ. The details of mechanical properties of base plate and SRC tested specimens were studied. The specimens were aged at $650^{\circ}C$ for HSLA-100 steel and at 66$0^{\circ}C$ for HY-100 steel and thermal cycled from 135$0^{\circ}C$ In $25^{\circ}C$ with a cooling time of $\Delta$ $t_{800^{\circ}50}$ $0^{\circ}C$/=21sec. corresponds to the heat input of 30kJ/cm. The thermal cycled specimens were stressed to a predetermined level of 248~600MPa and then reheated to the stress relief temperatures of 570~62$0^{\circ}C$. The time to failure( $t_{f}$) at a given stress level was used as a measure of SRC susceptibility. The strength, elongation and impact toughness of base plate were greater in HSLA-100 steel than in HY-100 steel. The time to failure was decreased with increasing temperature and/or stress. HSLA-100 steel was more susceptible to stress relief cracking than HY-100 steel under same conditions. It is thought to be resulted from the precipitation of $\varepsilon$-Cu phase by dynamic self diffusion of solute atoms. Therefore, greater strain concentration at grain boundary of HSLA-100 steel results in the increased SRC susceptibility.y.

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Exploration of growth mechanism for layer controllable graphene on copper

  • Song, Woo-Seok;Kim, Yoo-Seok;Kim, Soo-Youn;Kim, Sung-Hwan;Jung, Dae-Sung;Jun, Woo-Sung;Jeon, Cheol-Ho;Park, Chong-Yun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.490-490
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    • 2011
  • Graphene, hexagonal network of carbon atoms forming a one-atom thick planar sheet, has been emerged as a fascinating material for future nanoelectronics. Huge attention has been captured by its extraordinary electronic properties, such as bipolar conductance, half integer quantum Hall effect at room temperature, ballistic transport over ${\sim}0.4{\mu}m$ length and extremely high carrier mobility at room temperature. Several approaches have been developed to produce graphene, such as micromechanical cleavage of highly ordered pyrolytic graphite using adhesive tape, chemical reduction of exfoliated graphite oxide, epitaxial growth of graphene on SiC and single crystalline metal substrate, and chemical vapor deposition (CVD) synthesis. In particular, direct synthesis of graphene using metal catalytic substrate in CVD process provides a new way to large-scale production of graphene film for realization of graphene-based electronics. In this method, metal catalytic substrates including Ni and Cu have been used for CVD synthesis of graphene. There are two proposed mechanism of graphene synthesis: carbon diffusion and precipitation for graphene synthesized on Ni, and surface adsorption for graphene synthesized on Cu, namely, self-limiting growth mechanism, which can be divided by difference of carbon solubility of the metals. Here we present that large area, uniform, and layer controllable graphene synthesized on Cu catalytic substrate is achieved by acetylene-assisted CVD. The number of graphene layer can be simply controlled by adjusting acetylene injection time, verified by Raman spectroscopy. Structural features and full details of mechanism for the growth of layer controllable graphene on Cu were systematically explored by transmission electron microscopy, atomic force microscopy, and secondary ion mass spectroscopy.

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PIII&D (Plasma immersion ion implantation & deposition)를 이용한 a-Ge (amorphous-Germanium) Thin Film의 결정성장

  • Jeon, Jun-Hong;Choi, Jin-Young;Park, Won-Woong;Lim, Sang-Ho;Han, Seung-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.153-153
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    • 2011
  • 유리나 폴리머를 기판으로 하는 TFT(Thin film transistor), solar cell에서는 낮은 공정 온도에서($200{\sim}500^{\circ}C$) amorphous semiconductor thin film을 poly-crystal semiconductor thin film으로 결정화 시키는 기술이 매우 중요하게 대두 되고 있다. Ge은 Si에 비해 높은 carrier mobility와 낮은 녹는점을 가지므로, 비 저항이 낮을 뿐만 아니라 더 낮은 온도에서 결정화 할 수 있다. 하지만 일반적으로 쓰이는 Ge의 결정화 방법은 비교적 높은 열처리 온도를 필요로 하거나, 결정화된 원소에 남아있는 metal이 불순물 역할을 한다는 문제점, 그리고 불균일한 결정크기를 만든다는 단점이 있었다. 그 중에서도 현재 가장 많이 쓰이고 있는 MIC, MILC는 metal과 a-Ge이 접촉되는 interface나, grain boundary diffusion에 의해 핵 생성이 일어나고, 결정이 성장하는 메커니즘을 가지고 있으므로 단순 증착과 열처리 만으로는 앞서 말한 단점을 극복하는데 한계를 가지고 있다. 이에 PIII&D 장비를 이용하면, 이온 주입된 원소들이 모재와 반응 할 수 있는 표면적이 커짐으로 핵 생성을 조절 할 수 있을 뿐만 아니라, 이온 주입 시 발생하는 self annealing effect로 결정 크기까지도 조절할 수 있다. 또한 이러한 모든 process가 한 진공 장비 내에서 이루어지므로 장비의 단순화와, 공정간 단계별로 발생하는 불순물과 표면산화를 막을 수 있으므로 절연체 위에 저항이 낮고, hall mobility가 높은 poly-crystalline Ge thin film을 만들 수 있다. 본 연구에서는, 주로 핵 생성과정에서 seed를 만드는 이온주입 조건과, 결정 성장이 일어나는 증착 조건에 따라서 Ge의 결정방향과 크기가 많은 차이를 보이는데, 이는 HR-XRD(High resolution X-ray Diffractometer)와 Raman spectroscopy를 이용하여 측정 하였으며, SEM과 AFM으로 결정의 크기와 표면 거칠기를 측정하였다. 또한 Hall effect measurement를 통해 poly-crystalline thin film 의 저항과 hall mobility를 측정하였다.

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