• Title/Summary/Keyword: Selective separation

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Selective Separation of Amino Acid Mixture Using H2O-CH2Cl2-H2O Liquid Membrane containing p-Dimethylaminobenzaldehyde, 1-Napthol and Sulfosalicylic acid as a Carrier (II) (p-Dimethylaminobenzaldehyde, 1-Naphtol, Sulfosalicylic acid 등의 Carrier를 함유하는 H2O-CH2Cl2-H2O Liquid Membrane을 이용한 아미노산의 선택적 분리(II))

  • Park, Chung Oh;Hong, Jae Jin
    • Korean Journal of Clinical Laboratory Science
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    • v.36 no.2
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    • pp.115-120
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    • 2004
  • A bulk liquid membrane system was introduced for selective separation of an amino acid mixture. We confirmed p-diamethylaminobenzaldehyde (DAB), sulfosalicylic acid (SSA) and 1-naphtol were very useful carriers for selective separation of an amino acid mixture. As a result, Ala, Leu, Val, Phe and Ile were successfully separated by SSA, 1-naphtol in basic condition, 1-naphtol in weak acidic condition, DAB in strong acidic condition and DAB in strong basic condition. The separation mechanism was proposed by ion pair mechanism in the case of SSA and 1-naphtol and Imine bond formation mechanism was also introduced for DAB.

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Recovery of Sn from Copper Alloy Dross by a Selective Dissolution and Its Heat-treatment for the Synthesis of SnO2 (선택적 용해에 의한 동합금 부산물에서의 Sn 회수 및 열처리에 의한 SnO2 합성)

  • Ryu, Jeong Ho;Kong, Man-Sik;Lee, Jung-Il
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.4
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    • pp.173-177
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    • 2013
  • Separation and recovery of valuable metals such as zinc, nickel or tin from copper alloy dross has recently attracted from the viewpoints of environmental protection and resource recycling. In this report, preliminary study on concentration and separation of tin from copper alloy dross using selective dissolution method was performed. The tin in the copper alloy dross did not dissolve in the nitric acid solution which could allow the concentration and separation of the tin from the copper alloy dross. Precipitation of tin as $H_2SnO_3$ (metastannic acid) occurred in the solution and transformed to tin dioxide ($SnO_2$) after drying process. The dried sample was heat-treated at low temperature and its phase characteristics, surface morphology and chemical composition were investigated.

Multicomponent Nanostructured Materials for Separation Membranes

  • Peinemann, Klaus-Viktor
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.11-11
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    • 2004
  • Under the coordination of GKSS a new European project in the field of membrane development started recently. This project focuses on the development of novel nanostructured materials for selective material transport and separation. Two classes of materials will be developed in this project: nanostructured organic/inorganic hybrid materials and functional self-organized supramolecular copolymers.(omitted)

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Selective DNA Adsorption on Layered Double Hydroxide Nanoparticles

  • Kim, Kyoung-Min;Park, Chung-Berm;Choi, Ae-Jin;Choy, Jin-Ho;Oh, Jae-Min
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2217-2221
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    • 2011
  • We investigated the selective deoxyribonucleic acid (DNA) adsorption on layered double hydroxide (LDH) nanoparticles via studying the interaction between positively charged LDH nanoparticle as adsorbent and negatively charged adsorbates such as methyl orange (MO), fluorescein (FL), and DNA strands. The size controlled LDH $(Mg_{0.78}Al_{0.22}(OH)_2(CO_3)_{0.11}{\cdot}mH_2O)$ was prepared by conventional coprecipitation method, followed by the hydrothermal treatment. According to the adsorption isotherms, the adsorbed amounts of MO and FL were similar, however, that of DNA were much larger. The adsorption behaviors were well fitted to Freundlich adsorption model. The concentration dependent adsorption behavior on LDH surface was described in order to verify the selective DNA separation ability. The result showed that the LDH has advantages in selective adsorption of DNA competing with single molecular anions.

Development of Solid Separator for Selective Solid Circulation in Two-interconnected Fluidized Beds System (2탑 유동층 시스템에서 선택적 고체순환을 위한 고체분리기 개발)

  • Ryu, Ho-Jung;Park, Young Cheol;Lee, Seung-Yong;Kim, Hong-Ki
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.195-202
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    • 2009
  • As a basic research of developing two-interconnected fluidized beds system for selective solid circulation, a solid separator was developed to separate fine and coarse particles by means of particle size difference with particle size separation system equipped with metal screen. The effects of gas velocity, height of solid separator, and separation area on the solid separation rate were investigated as well. The solid separation rate increased as the gas velocity, height of solid separator, and separation area increased. As the gas velocity and height of the solid separator increased, the variation of the solid separation rate was consistent with that of bubble size. Consequently, coarse($212{\sim}300{\mu}m$) and fine($63{\sim}106{\mu}m$) particles were separated using the solid separator and the solid separation rate was ranged from 4.4 to 127 g/min. We also proposed two interconnenced fluidized beds system for sorption enhanced water-gas shift process equipped with the developed solid separator.

The Recovery of Non-ferrous Metals from Broken Light Bulbs using the Magnetic Liquid Based Separation

  • Chioran, Viorica;Ardelean, Ioan
    • Journal of Magnetics
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    • v.15 no.2
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    • pp.91-98
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    • 2010
  • The paper presents results of a study on the selective separation technology of ferrous and non-ferrous metals from broken light bulbs. The proposed method is to use magnetic fluids to obtain a magnetic fluid based- separation. [1] The study was conducted using three types of waste materials: regular light bulbs, auto light bulbs and neon tubes. In order to process the waste materials, a six stages technologic flow was developed: a) separation of light bulbs components; b) Physical and chemical analysis of raw materials; c) grain conditioning of the raw material; d) dry magnetic separation of ferrous components; e) magnetic fluid separation of non-magnetic material; f) recovery of the magnetic fluid adhered to the surface of the separated material grains. [2] This study shows that magnetic fluid separation is only profitable for regular and auto light bulbs and is not profitable in the case of neon tubes.

Selective adsorption of Ba2+ using chemically modified alginate beads with enhanced Ba2+ affinity and its application to 131Cs production

  • Kim, Jin-Hee;Lee, Seung-Kon
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.3017-3026
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    • 2022
  • The 131Cs radioisotope with a short half-life time and high average radiation energy can treat the cancer effectively in prostate brachytherapy. The typical 131Cs production processes have a separation step of the cesium from 131Ba to obtain a high specific radioactivity. Herein, we suggested a novel 131Cs separation method based on the Ba2+ adsorption of alginate beads. It is necessary to reduce the affinity of alginate beads to cesium ions for a high production yield. The carboxyl group of the alginate beads was replaced by a sulfonate group to reduce the cesium affinity while reinforcing their affinity to barium ions. The modified beads exhibited superior Ba2+ adsorption performances to native beads. In the fixed-bed column tests, the saturation time and adsorption capacity could be estimated with the Yoon-Nelson model in various injection flow rates and initial concentrations. In terms of the Cs elution, the modified alginate showed better performance (i.e., an elution over 88%) than the native alginate (i.e., an elution below 10%), indicating that the functional group modification was effective in reducing the affinity to cesium ions. Therefore, the separation of cesium from the barium using the modified alginate is expected to be an additional option to produce 131Cs.

Separation of Radiostrontium from Environmental Sample Using Strontim Selective Chromatographic Resin$(Sr.\;Spec^{TM})$ (스트론튬 선택적이온교환수지$(Sr.\;Spec^{TM})$를 이용한 환경시료중의 방사성 스트론튬의 분리)

  • Hong, Kwang-Hee;Lee, Chang-Woo;Choi, Yong-Ho;Lee, Myung-Ho
    • Journal of Radiation Protection and Research
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    • v.20 no.1
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    • pp.1-7
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    • 1995
  • Strontium selective chromatographic material $(Sr-Spec^{TM})$ was investigated for separation of radiostrontium from environmental soil and water sample. This chromatographic material has great capacity of binding of strontium ion in nitric acid media, and has selectivity to permit the separation of stontium from bulk amount of calcium. But the extraction of strontium was reduced by the other interfering ions such as K and Ba. So, in order to apply this material to the soil sample, prior removal treatment of K and Ba was needed. But the Sr-Spec material could provides simple and effective methods for the separation and removal of radiostrontium from liquid sample.

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Studies on Molecular Sieve Characteristics of Activated Carbon Fibers for Selective Gas Separation (선택적 가스분리를 위한 활성탄소섬유의 분자체 특성 연구)

  • 박병배;김도수;박영성
    • Journal of the Korean Ceramic Society
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    • v.38 no.1
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    • pp.1-8
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    • 2001
  • 선택적 가스분리를 위한 분자체탄소(Molecular Sieve Carbon: MSC)로서의 활용을 위해 제조된 활성탄소섬유의 흡착능과 분자체 특성이 다양한 분자크기를 갖는 가스 흡착실험을 통해 조사되었다. 각 활성화 조건별 세공크기분포와 세공발달 전개과정을 유추함으로서, 세공크기분포의 조절이 가능하게 되었으며 활성탄소섬유의 분자체 탄소로서 활용을 용이하게 할 수 있었다. 800, 85$0^{\circ}C$의 온도로 수증기에 의해 활성화한 활성탄소섬유의 경우 burn-off가 각각 50, 40% 정도를 가진 활성탄소섬유가 비교적 작은 분자크기(0.3~0.4nm)의 흡착질에 대한 분자체 특성을 나타냈다. 또한, 다양한 분자크기의 흡착질을 포함하는 혼합가스의 유속과 흡착온도의 조절로서 원하는 흡착질의 선택적 분리를 위해 활성탄소섬유가 갖는 분자체 특성 향상을 보였다.

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Study on Formation Behaviors of Hydroquinone Clathrates with CO2 and N2 for Application to Selective CO2 Separation/Recovery from Flue Gases (배가스 중 CO2 분리/회수로의 응용을 위한 CO2 및 N2 하이드로퀴논 크러스레이트의 형성 거동 연구)

  • LEE, DONGWON;YOON, JI-HO;LEE, JONG-WON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.289-295
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    • 2019
  • Effects of various reaction factors such as pressure, time, and temperature on clathrate formation were investigated for hydroquinone with $CO_2$ and $N_2$. Experimental and spectroscopic results indicate that $CO_2$ plays more preferential role in forming hydroquinone clathrates than $N_2$. These results can be used in application of selective $CO_2$ separation from flue gases with the formation of clathrate compounds.