• Title/Summary/Keyword: Selective reduction

Search Result 768, Processing Time 0.036 seconds

Ammonia Flow Control for NOx Reduction in SCR(Selective Catalytic Reduction) System of Refuse Incineration Plant (소각로의 Nox제어용 SCR시스템의 암모니아 공급량 제어)

  • 김인규;여태경;김상봉
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 1997.04a
    • /
    • pp.30-34
    • /
    • 1997
  • This paper Describe a modelling method for SCR(selective Catalytic reduction) system in refuse incineration plant. We consider the SCR system as a single input single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input (.NH/sap2/.), and taken an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to discrete system with 0.5 sampling time. Using the obtained SCR model, we simulate the SCR system to reduce the outlet NOx content by a conventional PID control method.

  • PDF

A development of diesel engine De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 디젤엔진의 De-NOx 시스템 개발에 관한 연구)

  • 정경열;김재윤;오상훈;박정일;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
    • /
    • 2001.05a
    • /
    • pp.187-191
    • /
    • 2001
  • In the paper, an approach to the development of the selective catalytic reduction process of NOx is presented. The reduction process can be efficiently controlled using a conventional combination of feed-forward and feed-back control structures. The aim of this paper is to test and verify an approach to the SCR process which is based on an industrial pilot plant of combustion and nitric oxide formation. The systems are based on measurements of a NOx removal ratio and the fuel flow rate, and NH$_3$slip which are usually available as a part of de-NOx control system.

  • PDF

Selective Graphene Oxide Reduction Utilizing Photon Energy (광에너지를 활용한 선택적 산화그래핀의 환원)

  • Shin, Jae-Soo;Choi, Eunmi
    • Journal of the Semiconductor & Display Technology
    • /
    • v.17 no.4
    • /
    • pp.16-20
    • /
    • 2018
  • Graphene is attracting attention due to its outstanding properties as line material for next-generation semiconductor. Graphene pattern technology is essential to apply graphene line. Selective graphene oxide reduction as one of graphene pattern method does not require a substrate thereby a high flexibility device can be applied. Particularly, the method using photon energy has advantages of short process time and environment friendly. In this review, we introduce the photocatalytic method and the photo-thermal energy conversion method using photon energy in the selective reduction process of graphene oxides.

DeNOx by SCR (Selective Catalytic Reduction) Using LPG as a Reductant (LPG-SCR에 의한 질소산화물 제거)

  • Kim, Moon-Chan
    • Applied Chemistry for Engineering
    • /
    • v.23 no.6
    • /
    • pp.588-593
    • /
    • 2012
  • In this study, selective catalytic reduction (SCR) reaction was performed using liqufied petroleum gas (LPG) as a reductant for removing NOx. The catalysts were manufactured with different amounts of Cu and Fe supported on HZSM-5 in order to remove NOx. The NOx conversion ratio was studied with changing the temperature and the catalyst amount. The catalysts were manufactured by calcination with flowing the ambient air at $500^{\circ}C$ for three hours. Cupper of 1~4 wt% and iron of 0.5~2 wt% were supported on HZSM-5 of which Si/Al ratio were 80. According to the reaction results, the catalyst which Cu of 3 wt% supported on HZSM-5 showed the highest conversion rate. XRD, XPS, and TPR analysis were also performed for the characterization of catalysts.

Selective Reduction of Organic Compounds with Non-Free Hydride Reducing Agents

  • Cha, Jin Soon
    • Journal of Integrative Natural Science
    • /
    • v.1 no.3
    • /
    • pp.192-194
    • /
    • 2008
  • A series of non-free hydride reducing systems containing boron or aluminum atom, which possess no metal-hydride bond but an available hydrogen at a branched ${\beta}$-position, has been applied to the selective reduction (chemo--, regio-, and stereoselective reduction) of organic compounds. The systems, comprised of diisopinocampheylborane and diisobutylalane derivatives, exhibited almost perfect selectivities in the reduction of aldehydes and ketones. The characteristics features of this systems leading to a perfect transformation have been depicted in this report, especially in the 1) Reduction of ${\alpha}$,${\beta}$-Unsaturated Carbonyl Compounds to Allylic Alcohols via 1,2-Reduction, 2) Chemoselective Reduction between Structurally Different Carbonyl Compounds, and 3) Stereoselective Reduction of Cyclic Ketones.

  • PDF

A development of reactor design software for De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 De-NOx 시스템의 반응로 설계 전산프로그램 개발)

  • 정경열;오상훈;동은석;이수태;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
    • /
    • 2002.05a
    • /
    • pp.187-191
    • /
    • 2002
  • The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

  • PDF

Selective Reduction of Carbonyl Compounds with Diisopinocampheylhaloboranes

  • Cha, Jin Sun;Kim, Eun Ju;Gwon, O Un;Kim, Jong Mi
    • Bulletin of the Korean Chemical Society
    • /
    • v.17 no.1
    • /
    • pp.50-55
    • /
    • 1996
  • Reaction of carbonyl compounds with diisopinocampheylhaloboranes (Ipc2BX,X=Cl, Br, I) was investigated in detail in order to establish their usefulness as selective reducing agents. The reagents reduced aldehydes and ketones to the corresponding alcohols. The reactivities are in the order of Ipc2BCl Ipc2BBr>Ipc2BI.The reagents also reduced ${\alpha}{\beta}-unsaturated$, aldehydes and ketones to the corresponding allylic alcohols without any detectable 1,4-reduction. Especially, the chloro derivative nicely achieved the selective reduction of aldehyde or ketone groups in the presence of many other functional groups. The most remarkable result of this investigation is that aldehydes and ketones can be selectively reduced in the presence of acid chlorides.

Selective Data Reduction in Gas Chromatography/Infrared Spectrometry

  • Pyo, Dong Jin;Sin, Hyeon Du
    • Bulletin of the Korean Chemical Society
    • /
    • v.22 no.5
    • /
    • pp.488-492
    • /
    • 2001
  • As gas chromatography/infrared spectrometry (GC/IR) becomes routinely avaliable, methods must be developed to deal with the large amount of data produced. We demonstrate computer methods that quickly search through a large data file, locating thos e spectra that display a spectral feature of interest. Based on a modified library search routine, these selective data reduction methods retrieve all or nearly all of the compounds of interest, while rejecting the vast majority of unrelated compounds. To overcome the shifting problem of IR spectra, a search method of moving the average pattern was designed. In this moving pattern search, the average pattern of a particular functional group was not held stationary, but was allowed to be moved a little bit right and left.

Monochorionic Triamniotic Triplet Pregnancy Following Assisted Reproductive Technology and Radiofrequency Ablation for Selective Reduction

  • Lee, Jeong-Heon;Oh, Su-Hyun;Hong, Ah-Reum;Jeong, Young-Ju;Cho, Sung-Nam;Cho, Dong-Hyu
    • Perinatology
    • /
    • v.29 no.4
    • /
    • pp.180-184
    • /
    • 2018
  • In assisted reproductive techniques, monozygotic twinning is not influenced by the trial of reducing the number of embryos transferred. We present extremely rare case of monochorionic triamniotic triplet pregnancy following in vitro fertilization and two-embryo transfer. During the first trimester, the crucial ultrasound findings of monochorionic triamniotic triplet pregnancy are three distinct amniotic sacs forming a triangle or ipsilon zone within a single chorionic cavity. After prudential counseling about the potential risk of a monochorionic triamniotic triplet pregnancy with the patient, selective reduction of two fetuses via radiofrequency ablation was performed. We report a case of selective reduction for monochorionic triamniotic triplet pregnancy using radiofrequency ablation at 12 weeks' gestation and obstetric progression after radiofrequency ablation was uneventful until 20 weeks' gestation.