• Title/Summary/Keyword: Selective agent

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A traffic control agent to manage flow usage in Differentiated Service Network (차별화서비스 네트워크에서 흐름 관리를 위한 트래픽 제어 에이전트)

  • 이명섭;박창현
    • Proceedings of the IEEK Conference
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    • 2003.07a
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    • pp.69-72
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    • 2003
  • This paper presents a traffic control agent that can perform the dynamic resource allocation by controlling traffic flows on a DiffServ network. In addition, this paper presents a router that can support DiffServ on Linux to support selective QoS in IP network environment. To implement a method for selective traffic transmission based on priority on a DiffServ router, this paper changes the queuing discipline in Linux, and presents the traffic control agent so that it can efficiently control routers, efficiently allocates network resources according to service requests, and relocate resources in response to state changes of the network.

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A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

Catecholalane (1,3,2-Benzodioxaluminole) as a Selective Reducing Agent

  • 차진순;장석원;이지은;김종미;권오운;이형수;송한철
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.720-724
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    • 1996
  • Catecholalane (1,3,2-Benzodioxaluminole, CA) prepared from catechol and aluminum hydride in tetrahydrofuran (THF) is found to be a selective reducing agent. The systematic study in order to characterize the reducing properties of the reagent under practical conditions (THF, 0 or 25 ℃, the quantitative amount of reagent to compound) has been done. The reagent reduces aldehydes, ketones, esters and acid chlorides to the corresponding alcohols, and primary amides to the corresponding amines. Especially noteworthy is that the reagent can convert both aromatic and aliphatic nitriles to the corresponding aldehydes in very high yields.

Selective Ni Recovery from Spent Ni-Mo-Based Catalysts (니켈-몰리브데늄 성분계 폐촉매로부터 니켈의 선택적 회수)

  • Lee, Tae Kyo;Han, Gi Bo;Yoon, Suk Hoon;Lee, Tae Jin;Park, No-Kuk;Chang, Won Chul
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.668-673
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    • 2008
  • The objective of this study is to optimize the leaching conditions of sequential leaching and extracting processes for selective Ni recovery from spent Ni-Mo-based catalyst. The selective Ni recovery process consists of two processes of leaching and extracting process. In this 2-step process, Ni component is dissolved from solid spent Ni-Mo-based catalyst into leaching agent in leaching process and sequentially extracted to Ni complex with an extracting agent in the extracting process. The solutions of nitric acid ($HNO_3$), ammonium carbonate ($(NH_4)_2CO_3$) and sodium carbonate ($Na_2CO_3$) were used as a leaching agent in leaching process and oxalic acid was used as an extracting agent in extracting process. $HNO_3$ solution is the most efficient leaching agent among the various leaching agent. Also, the optimized leaching conditions for the efficient and selective Ni recovery were the leaching temperature of $90^{\circ}C,\;HNO_3$ concentration of 6.25 vol% and elapsed time of 3 h. As a result, Nickel oxalate having the highest yield of 88.7% and purity of 100% was obtained after sequentially leaching and extracting processes under the optimized leaching conditions.

The Experimental Study of SPM(Selectively Permeable Membrane Materials) by using Aerosol Test Instrument (에어로졸 시험장비를 이용한 방호 의복 소재의 여과 효율에 대한 연구)

  • Kwon, Tae Geun;Seo, Hyeon Kwan;Kim, Jin Won;Kang, Jae Sung;Kang, Ki Tae;Ahn, Kang Ho;Choi, Jin Soo;Cho, Jae Ho;Kwon, Yong Taek;Park, Hyen Bae
    • Particle and aerosol research
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    • v.10 no.3
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    • pp.109-117
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    • 2014
  • In Korea, permeable protection clothes for chemical agent is being developed and distributed. But permeable protection clothes are vulnerable for biological agent of particle type. Therefore selective permeable membranes are being developed to protect chemical agent and biological agent simultaneously. In this study, aerosol collection efficiency test was performed to validate the protection performance of permeable clothes and selective permeable membranes. Aerosol collection efficiency test was performed by using the aerosol test equipment that could test aerosol particle diameter from $0.005{\mu}m$ to $3.0{\mu}m$. This study shows the test method and performance test results for collection efficiency by using the aerosol test equipment.

Thexylalkoxyborane as Hydroborating Agent for Alkenes and Alkynes

  • 차진순;서원우;김종미;권오운
    • Bulletin of the Korean Chemical Society
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    • v.17 no.10
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    • pp.892-899
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    • 1996
  • In order to elucidate the effect of alkoxy substituent in thexylborane and hence establish their usefulness as hydroborating agent, reactions of alkenes and alkynes with thexylalkoxyborane (ThxBHOR; R=Et, i-Pr, i-Bu, sec-Bu, t-Bu, Ph) were investigated in detail. The reagents readily hydroborated alkenes and alkynes of various structural types at 25 ℃ in excellent regioselectivity. The selectivity increases consistently with increasing steric size of alkoxy substituent. Especially, the selectivity achieved by the sec-butoxy derivative is comparable to that previously achieved by thexylhaloborane-methyl sulfide (ThxBHX·SMe2), the most selective hydroborating agent known.

Evaluation of NOx Reduction Efficiency and Emission Factor from Large Combustion Facilities in Seoul (서울지역 대형연소시설에서의 질소산화물 제거효율과 배출계수 산정)

  • 신진호;오석률;김정영;전재식;신정식
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.27-33
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    • 2003
  • This survey was performed to investigate the NOx emission factors at 3 Municipal Solid Waste Incinerators(MSWI) and 5 Power generation boilers in Seoul. The NOx concentrations were measured before and after control systems. The results were as follows. 1) The NOx reduction efficiencies of Selective Catalytic Reduction (SCR) using ammonia as reducing agent ranged from 53.7% to 89.9%. The NOx reduction efficiencies of SCR using methanol as reducing agent, Non- Selective Catalytic Reduction (NSCR) using ethanol as reducing agent and low-NOx burner were 20.8%, 29.1% and 24.7%, respectively. 2) The NOx emission factors at A-1, A-2 and A-3 facilities of MSWI were 0.786, 0.127 and 0.594 kg Nox/ton fuel, respectively. The factors of A-1 and A-3 facilities were higher than the average value of Korea. 3) The NOx emission factors at B-1, B-2, B-3, B-4 and B-5 facilities of Power generation boiler were 2.109, 0.726, 4.106, 8.378 and 5.168 kg Nox/ton fuel, respectively. The factors of B-4 and B-5 facilities were higher than the average value of Korea.

Highly Selective Derivative Spectrophotometry for Determination of Nickel Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

  • Eskandari, Habibollah
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1137-1142
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    • 2004
  • A spectrophotometric and first derivative spectrophotometric method was developed in aquatic Tween 80 micellar solutions for selective determination of nickel without using any pre-separation step. 1-(2-Pyridylazo)-2-naphthol (PAN), as a sensitive chromogenic complexing agent formed a red-colored Ni(II)-PAN complex in Tween 80 media with satisfactory solubility and stability. Conditions such as pH, PAN concentration, type and concentration of micellizing agent were optimized. Molar absorptivity of Ni-PAN complex was found $4.62\;{\times}\;10^4L\;cm^{?1}\;mol^{?1}$ at 569 nm, under the optimum condition. Calibration graphs were derived by zero, first and second derivative spectrophotometry at maximum wavelengths of 569, 578 and 571 nm with linear ranges of 30-1800, 20-2500 and 30-2000 ng $mL^{?1}$ , respectively. Precision as standard deviation as well as accuracy as recovery percent were in the range of 1-20 ng $mL^{?1}$, and 93.3-103.3%, respectively, for the entire of the linear ranges. Spectrophotometric detection limit was 3 ng $mL^{?1}$ and effects of diverse ions on the first derivative determination of nickel were studied to investigate selectivity of the method. Interferences of cobalt and copper on the nickel determination were prevented using o-phenanthroline as masking agent. The recommended procedures were applied to the various synthetic and stainless steel alloys, tea leaves and human hair, with satisfactory results.