• Title/Summary/Keyword: Selective Assembly

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Efficient Electron Transfer in CdSe-py-SWNTs FETs

  • Jeong, So-Hee;Shim, H.C.;Han, Chang-Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.63-63
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    • 2010
  • Ability to transport extracted carriers from NQDs is essential for the development of most NQD based applications. Strategies to facilitate carrier transport while preserving NQDs' optical characteristics include: 1) Fabricating neat films of NQDs with modified surfaces either by adapting series of ligands with certain limitations or by applying physical processes such as heat annealing 2) Coupling of NQDs to one-dimensional nanostructures such as single walled carbon nanotubes (SWNTs) or various types of nanowires. NQD-nanowire hybrid nanostructures are expected to facilitate selective wavelength absorption, charge transfer to 1-D nanostructures, and efficient carrier transport. Even with the vast interests in using NQD-SWNT hybrid materials in optoelectric applications, still, no reports so far have clearly elucidated the optoelectric behavior when they were assembled on the FET mainly because the complexity involving in both components in their preparation and characterization. We have monitored the optical properties of both components (NQDs, SWNTs) from the synthesis, to the assembly, and to the device. More importantly, by using pyridine molecules as a linker to non-covalently attach NQDs to SWNTs, we were able to assemble NQDs on SWNTs with precise density control without harming their electronic structures. Furthermore, by measuring electrical signals from the fabricated aligned SWNTs-FET using dielectrophoresis (DEP), we were able to elucidate the charge transfer mechanism.

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Development of Transportation Robots in Semiconductor Logistics (반도체 물류 이송로봇의 개발)

  • Woohyeon Hwang;Iljun Jang;Nayun Hwang;Seungbyeong Chae;Seongyun Kim
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2024.01a
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    • pp.307-309
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    • 2024
  • 세계적으로 물류 자동화 시장은 2026년까지 약 44조원으로 예상되며, 연평균 10.6%의 성장률을 기록할 것으로 예측된다. 특히 국내 시장은 2025년까지 연평균 성장률 11.5%로 1조원 이상으로 전망되고 있다. 2025년까지 물류 자동화 시장은 270억 달러로 급성장할 것으로 예상되며, 반도체 분야에서 로봇이 상품 입고, 보관, 상품 피킹, 분류, 출고 작업을 담당하는 트렌드가 강조된다. 본 논문은 반도체 물류 분야를 대상으로 작은 크기와 민첩성을 갖춘 로봇을 개발하여 작업 공간을 효율적으로 활용하고 인력을 최소화하려는 목적이다. 수직 및 수평 로봇은 효율적인 자동화 시스템을 제공하며, UI를 사용하여 AGV, 선반, 스카라 로봇을 하나의 통합 시스템으로 개발하고자 한다. 특히 코드 인식, 초음파 센서, 아두이노 MCU, 스카라 로봇, AGV 등을 활용한 로봇 시스템을 개발하여 반도체 물류 작업을 효율적으로 수행하고자 한다. 다양한 분야에서 활용 가능한 스카라 로봇을 개발하기 위해 마이크로 스텝과 풀리, 타이밍 벨트를 이용한 구동 방식 등을 채택한다. 반도체 물류 센터에서의 자동화는 물류 공간의 확대와 인건비 절감을 기대할 수 있으며, 로봇 및 드론을 활용하여 인건비 절감과 효율성 향상을 통해 기업 비용 절감에 기여할 것으로 예상된다.

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Wall flow characteristics with static mixer position and housing geometry for preventing urea-salt deposition (우레아염 퇴적 방지를 위한 믹서 위치 및 하우징 형상에 따른 벽면 유동특성에 관한 연구)

  • Lee, Banguk;Lee, Jeekeun
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.4
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    • pp.368-377
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    • 2013
  • The Urea-SCR system commercialized shows a remarkable performance to reduce NOx emission in heavy duty diesel engines. However, Urea-water solution injected upstream a mixer, which is set up inside a exhaust pipe to promote exhaust gas-atomized droplet mixing, bumps up against the wall of a exhaust pipe as the droplets flow downstream through the exhaust gas. The urea deposited on the wall of the exhaust pipe is changed into the Urea-salt, resulting in the decreased life-time of the SCR catalysts. Therefore, the development of the urea deposition avoidance technologies is being treated as an important issue of the Urea-SCR systems. An experimental study was carried out to investigate the effects of the wall flow characteristics around the mixer-housing assembly with the variation of the mixer housing surrounding and supporting the mixer, which is designed to increase the wall flow and then to reduce droplet deposition. The flow characteristics was investigated by using a hot-wire anemometry for 2-D simplified duct model, and the housing tilt angles and the position of the mixer were changed : angle of $0^{\circ}$, $1^{\circ}$, $2^{\circ}$, $3^{\circ}$, and mixer positions of 0L, 0.5L, 1L. The results showed that the wall flow onto the exhaust pipe was improved with changing the tilt angle of the mixer housing, and the wall flow improved more when the position of the mixer was on 1L.

Genome-wide survey and expression analysis of F-box genes in wheat

  • Kim, Dae Yeon;Hong, Min Jeong;Seo, Yong Weon
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.141-141
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    • 2017
  • The ubiquitin-proteasome pathway is the major regulatory mechanism in a number of cellular processes for selective degradation of proteins and involves three steps: (1) ATP dependent activation of ubiquitin by E1 enzyme, (2) transfer of activated ubiquitin to E2 and (3) transfer of ubiquitin to the protein to be degraded by E3 complex. F-box proteins are subunit of SCF complex and involved in specificity for a target substrate to be degraded. F-box proteins regulate many important biological processes such as embryogenesis, floral development, plant growth and development, biotic and abiotic stress, hormonal responses and senescence. However, little is known about the F-box genes in wheat. The draft genome sequence of wheat (IWGSC Reference Sequence v1.0 assembly) used to analysis a genome-wide survey of the F-box gene family in wheat. The Hidden Markov Model (HMM) profiles of F-box (PF00646), F-box-like (PF12937), F-box-like 2 (PF13013), FBA (PF04300), FBA_1 (PF07734), FBA_2 (PF07735), FBA_3 (PF08268) and FBD (PF08387) domains were downloaded from Pfam database were searched against IWGSC Reference Sequence v1.0 assembly. RNA-seq paired-end libraries from different stages of wheat, such as stages of seedling, tillering, booting, day after flowering (DAF) 1, DAF 10, DAF 20, and DAF 30 were conducted and sequenced by Illumina HiSeq2000 for expression analysis of F-box protein genes. Basic analysis including Hisat, HTseq, DEseq, gene ontology analysis and KEGG mapping were conducted for differentially expressed gene analysis and their annotation mappings of DEGs from various stages. About 950 F-box domain proteins identified by Pfam were mapped to wheat reference genome sequence by blastX (e-value < 0.05). Among them, more than 140 putative F-box protein genes were selected by fold changes cut-offs of > 2, significance p-value < 0.01, and FDR<0.01. Expression profiling of selected F-box protein genes were shown by heatmap analysis, and average linkage and squared Euclidean distance of putative 144 F-box protein genes by expression patterns were calculated for clustering analysis. This work may provide valuable and basic information for further investigation of protein degradation mechanism by ubiquitin proteasome system using F-box proteins during wheat development stages.

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Deposition of Poly(3-hexylthiophene)(P3HT) by Vapor Deposition and Patterning Using Self-Assembled Monolayers (Oxide 표면에 Self-Assembly Monolayers를 이용한 전도성 고분자 Poly(3-hexylthiophene)(P3HT) 증착 및 Patterning 연구)

  • Pang, Il-Sun;Kim, Hyun-Ho;Kim, Sung-Soo;Lee, Jae-Gab
    • Korean Journal of Materials Research
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    • v.18 no.12
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    • pp.664-668
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    • 2008
  • Vapor phase polymerization of a conductive polymer on a $SiO_2$ surface can offer an easy and convenient means to depositing pure and conductive polymer thin films. However, the vapor phase deposition is generally associated with very poor adhesion as well as difficulty when patterning the polymer thin film onto an oxide dielectric substrate. For a significant improvement of the patternability and adhesion of Poly(3-hexylthiophene) (P3HT) thin film to a $SiO_2$ surface, the substrate was pre-patterned with n-octadecyltrichlorosilane (OTS) molecules using a ${\mu}$-contact printing method. The negative patterns were then backfilled with each of three amino-functionalized silane self-assembled monolayers (SAMs) of (3-aminopropyl) trimethoxysilane (APS), N-(2-aminoethyl)-aminopropyltrimethoxysilane (EDA), and (3- trimethoxysilylpropyl)diethylenetriamine (DET). The quality and electrical properties of the patterned P3HT thin films were investigated with optical and atomic force microscopy and a four-point probe. The results exhibited excellent selective deposition and significantly improved adhesion of P3HT films to a $SiO_2$ surface. In addition, the conductivity of polymeric thin films was relatively high (${\sim}13.51\;S/cm$).

Molecular Level Detection of Heavy Metal Ions Using Atomic Force Microscope (원자간인력현미경을 이용한 분자수준의 중금속 이온 검출)

  • Kim, Younghun;Kang, Sung Koo;Choi, Inhee;Lee, Jeongjin;Yi, Jongheop
    • Clean Technology
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    • v.11 no.2
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    • pp.69-74
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    • 2005
  • A metal ion detector with a submicron size electrode was fabricated by field-induced AFM oxidation. The square frame of the mesa pattern was functionalized by APTES for the metal ion detection, and the remaining portion was used as an electrode by the self-assembly of MPTMS for Au metal deposition. The conductance changed with the quantity of adsorbed copper ions, due to electron tunneling between the mobile and surface electrodes. The smaller electrode has a lower limit of detection due to the enhancement in electron tunneling through metal ions that are adsorbed between the conductive-tip (mobile) and the surface (fixed) electrode. This two-electrode system immobilized with different functional groups was successfully used in the selective adsorption and detection of target materials.

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Macrocyclic Isomers with S2O-Donor Set as Silver(I) Ionophores

  • Park, Sung-Bae;Yoon, Il;Seo, Joo-beom;Kim, Hyun-Jee;Kim, Jae-Sang;Lee, Shim-Sung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.713-717
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    • 2006
  • $S_2O$-donor macrocyclic isomers incorporating a xylyl group in o- ($L^1$), m- ($L^2$) and p-positions ($L^3$) extract no metal ions except silver(I) from aqueous to chloroform phase. And the magnitudes of %Ex for silver(I) are in the order of $L^1$ > $L^2$ > $L^3$. Taking this result into account, $L^1$-$L^3$ were utilized as membrane active components to prepare potentiometric silver(I)-selective electrodes. The proposed macrocycles-based electrodes E1 ($L^1$), E2 ($L^2$) and E3 ($L^3$) exhibited comparable results which show considerable selectivity toward silver(I) over alkali, alkali earth and other transition metal ions. Comparative NMR study on $L^1$-$L^3$ and their complexes with silver(I) in solution was also accomplished. In addition, a unique sandwich-type complex $[Ag(L^1)_2]CIO_4$ was prepared from the assembly reaction of $L^1$ with $AgClO_4$ and structurally characterized by an X-ray diffraction analysis.

Finite element analysis for 3-D self-contact problems of C.v.joint rubber boots (3차원 자체접촉을 위한 유한요소해석에 의한 등속조인트 고무부트의 변형해석)

  • Lee, H.W.;Kim, S.H.;Lee, C.H.;Huh, H.;Lee, J.H.;Oh, S.T.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.12
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    • pp.2121-2133
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    • 1997
  • A finite element code is developed for 3-D self-contact problems, using continuum elements with a SRI(Selective Reduced Integration) scheme to prevent locking phenomenon by the incompressibility of rubber. Contact treatment is carried out in two ways : using the displacement constraints in case of rigid contact ; and imposing the same contact forces on two contact boundaries in case of self-contact. The finite element code developed is applied to the deformation analysis of C.V.joint boots which maintain lubrication conditions and protect the C.V.joint assembly from impact and dust. The boot accompanies large rotation depending on the rotation of the wheel axis and leading to the self-contact phenomena of the boot bellows. Since this contact phenomenon causes wear of the product and has great influence on the endurance life of the product, it is indispensable to carry out stress analysis of the rubber boots. In case of self-contact, various methods for determining contact forces have been suggested with an appropriate contact formulation. Especially, the types of penetration in self-contact are modularized to accelerate conputation with a contact algorithm.

Current Status of Emitter Wrap-Through c-Si Solar Cell Development (에미터 랩쓰루 실리콘 태양전지 개발)

  • Cho, Jaeeock;Yang, Byungki;Lee, Honggu;Hyun, Deochwan;Jung, Woowon;Lee, Daejong;Hong, Keunkee;Lee, Seong-Eun;Hong, Jeongeui
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.17-26
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    • 2013
  • In contrast to conventional crystalline cells, back-contact solar cells feature high efficiencies, simpler module assembly, and better aesthetics. The highest commercialized cell and module efficiency was recorded by n-type back-contact solar cells. However, the mainstream PV industry uses a p-type substrate instead of n-type due to the high costs and complexity of the manufacturing processes in the case of the latter. P-type back-contact solar cells such as metal wrap-through and emitter wrap-through, which are inexpensive and compatible with the current PV industry, have consequently been developed. In this paper the characteristics of EWT (emitter wrap-through) solar cells and their status and prospects for development are discussed.

Self-assembly of ZnO Stripes Prepared by Anodization in an Ethanolic Sulfuric Acid (에탄올/황산 혼압액에서 양극산화법을 이용한 자기정렬된 ZnO 줄무늬 구조 제조 연구)

  • Kim, Sung Joong;Choi, Jinsub
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.686-691
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    • 2008
  • There are no many research reports on the preparation of ZnO by electrochemical oxidation since the zinc oxide is very easily dissolved in an acidic or basic environment, even though zinc oxides have attracted many attentions because of their optical/electrical properties. In this paper, we describe the fabrication of self-ordered stripes of ZnO by anodization of Zn in an ethanolic sulfuric acid. The formation of stripes of ZnO originating from Zn is attributed to water-selective dissolution of ZnO during anodization. We study in detail the effects of concentration of $H_2SO_4$, applied potential, anodization time, and addition of a small amount of water on the fabrication of stripes of ZnO. Mechanisms for the fabrication of ZnO stripes are discussed in terms of the above-mentioned effects.