• Title/Summary/Keyword: Segregation effect

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Effect of Manganese on the Microstructure of Cemented Carbides

  • Weidow, Jonathan;Norgren, Susanne;Elfwing, Mattias;Andren, Hans-Olof
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.348-349
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    • 2006
  • The plastic deformation behavior of cemented carbides is related to the WC grain boundary strength. Ab initio calculations predict that Co and Mn segregate to WC/WC grain boundaries. To experimentally study the effect of Mn, a WC-Co-Mn material was manufactured and compared to a WC-Co material. The microstructure was studied using scanning electron microscopy (SEM), including electron backscatter diffraction (EBSD). Special attention was paid to the WC grain size and the frequency of special low-energy grain boundaries. Mn was found to have negligible effect on both the WC grain growth and the fraction of $\sum2$ WC/WC boundaries in the as-sintered material.

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아크릴계 증점제 사용량이 저분체 고유동 콘크리트의 물리적 특성에 미치는 영향에 관한 실험적 연구 (Experimental Study on the Effect of the Amount of Acrylic Viscosity Agent on the Physical Properties of High-Fluidity Concrete using Low-Binder)

  • 고혜빈;공태웅;조인성;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 봄 학술논문 발표대회
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    • pp.72-73
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    • 2021
  • For the development of high-fluidity concrete using low-binder, The effect of the use of the developed acrylic viscosity agent on the physical properties of concrete evaluated. The amount acrylic viscosity agent used was 1.5%, 1.7%, and 2.0% based on the binder amount of 400kg/m3, and slump flow test, slump flow 500mm arrival time measurement, air volume measurement, and U-Box passing test were conducted to determine the effect of the physical properties of concrete. it was judged that 1.5% of the acrylic viscosity agent used in high-fluidity concrete using low-binder was most suitable.

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셀룰로스계 증점제의 첨가량이 고유동 저분체 콘크리트의 물리적 특성에 미치는 영향에 관한 실험적 연구 (Experimental Study on the Effect of the Amount of Cellulose type Viscosity Agent on the Physical Properties of High-Fluidity Concrete Using Low-Binder)

  • 고혜빈;조인성;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.129-130
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    • 2021
  • For the development of high-fluidity concrete using low-binder, The effect of the use of the developed acrylic viscosity agent on the physical properties of concrete evaluated. The amount acrylic viscosity agent used was 0.28%, 0.29% and 0.30% based on the binder amount of 350kg/m3, and slump flow test, air volume measurement, U-Box passing test and strength compressive were conducted to determine the effect of the physical properties of concrete. it was judged that 0.29% of the cellulose type viscosity agent used in high-fluidity concrete using low-binder was most suitable.

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고성능콘크리트의 특성에 미치는 혼화재 치환변화의 영향에 관한 실험적 연구 - 제1보: 아직 굳지 않은 상태의 특성 - (An Experimental Study on the Effect for Replacement of Pozzolanic Admixtures Influencing to the Properties of High-Performance Concrete - Part1:properties of Fresh Concrete -)

  • 조병영;최청각;윤기원;이정희;한천구;반호용
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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    • pp.22-25
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    • 1995
  • This study is aimed for analyzing the effect on replacing change of fly ash and silica fume of high performance concrete. From the results, the flowability is good when the replacing rate of fly ash increases. The placeability is best in the ratio of 15 to 5 ; F.A:S.F and the segregation-resistibility is appeared good when the replacing ratio of silica fume increases.

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Al계 편정합금의 중력 편석에 관한 연구(II);Pb, Bi 입자의 분산에 미치는 모하금 첨가의 영향 (A Study on the Gravity Segregation in Monotectic Al Alloys.(II);The Effect of Master Alloy Addition on the Distribution of Pb, Bi Particles)

  • 황호을;이재하;김희명;최정철;윤의박
    • 한국주조공학회지
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    • 제10권5호
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    • pp.392-398
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    • 1990
  • To improve free-cutting property, fine Pb, Bi particles is necessary to be distributed evenly in Al-Cu alloy. The control of added element size and distribution are very difficult because of the physical properties of Pb, Bi. The effect of master alloy compositions on microstructure and particle distribution was investigated. The ribbon shape of Pb-50wt% Bi master alloy showed the best results. And Ti addition improved even distribution of Pb, Bi particles. Particles grown from $L_2$ phase were considered to be the Pb, Bi compound.

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B390 알루미늄 합금의 초정Si 입자분포에 미치는 원심주조 공정인자의 영향 (Effect of Centrifugal Casting Parameters on The Distribution of Primary Si Particles of B390 Aluminum Alloy)

  • 박정욱;김헌주
    • 한국주조공학회지
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    • 제28권1호
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    • pp.25-30
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    • 2008
  • To develop a functionally graded microstructure of cylindrical liner, effect of centrifugal casting parameters such as pouring temperature of hyper-eutectic Al-Si alloy melt, mold pre-heating temperature, and rotational frequency of mold on distribution of primary Si particles across wall thickness were investigated. Segregation tendency of Si particles toward inner side of cylindrical liner increased as the increase of rotational frequency of mold, pouring temperature of melt and mold pre-heating temperature. Especially, distribution density of primary Si particles within 1.5 mm from inner surface of cylindrical liner was above 35% under the centrifugal casting condition of $750^{\circ}C$ melt pouring temperature, $300^{\circ}C$ mold pre-heating temperature, and 2500 rpm mold rotational frequency.

Ren$\'{e}$ 95 초내영 합금 분말을 이용한 열간 정수압 성형 및 성형 조건에 따른 미세조직 변화 (HIP Consolidation and Effect of Process Variables on Micristructure for Ren$\'{e}$ 95 Superalloy Powders)

  • 표성규
    • 한국분말재료학회지
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    • 제6권2호
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    • pp.152-162
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    • 1999
  • The present study is concerned with the effect of PM process variables on the microstructure by using atomized superalloy powders. It is suggested that the inhomogeneity of composition is strongly dependent on the process variables. The contents of segregation elements of plasma rotating electrode process (PREP) powders are larger than those of Ar atomization (AA) powders. As HIP treatment temperature in-increases, the secondary phases on the prior particle boundaries (PPB) have continuous,uniform distribution and high density, but the amount of PPB decreases suddenly at 1150$^{\circ}$C. Segregated phases on the PPB are identified to be MC type carbide. Brittle MC type carbides on the PPB provide fracture initiation sites and preferred fracture path, thereby leading to intergranular type brittle fracture.

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티타늄 및 구리증착이 알루미나 곡강도에 미치는 영향 (The Effect of Titanium and Copper Coatings on the Modulus of Rupture of Alumina)

  • 황하룡;이임렬
    • 한국표면공학회지
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    • 제27권1호
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    • pp.29-35
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    • 1994
  • The effects of coating of 3$\mu\textrm{m}$ thickness on the mechanical property of alumina after heat treatment at 100$0^{\circ}C$ for 30minutes under $10^{-6}$torr vacuum was quantified in terms of modulus of rupture(MOR) using Weibull plot. While the copper coating did not change MOR of alumina due to the nonwetting behavior of Cu on $Al_2O_3$, the reactive titanium metal coating caused a noticeable 29% reduction in averaged MOr strength. This was related with the combined effects of microcracks in coating formed during heat treatment and good bonding character between Ti and $Al_2O_3$. The effect of cosputtering of Ti and Cu, bilayer coatings of Cu/Ti and Ti/Cu were also investigated. It was found that Ti, cosputtered, Cu/ti and Ti/Cu coatings reduced MOR strength of alumina in the order listed. This was correlated with the amount of Ti at coating/alumina inter-face associated with a coated layer or segregation of Ti during heat treatment.

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Space Charge Effect on Grain Growth Kinetics of Tetragonal Zirconia Polycrystal

  • Chon, Uong
    • The Korean Journal of Ceramics
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    • 제5권1호
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    • pp.1-11
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    • 1999
  • The effect of aliovalent dopents, $Nb_3O_5$ and MnO, on the grain growth kinetics of 12 mol% ceria stabilized tetragonal zirconia polycrystals (Ce-TZP) was studied. All specimens were sintered at $1550^{\circ}C$ for 20 minutes prior to annealing at different temperatures to study grain growth kinetics. Grain growth kinetics of Ce-TZP and 1 mol% $Nb_2O_5$ doped Ce-TZP (Ce-TZP/$Nb_3O_5$) during annealing at 1475, 1550, and $1600^{\circ}C$ adequately matched with square law $(D^2-D_\;o^2=k_at)$. However, grain growth in 1 mol% MnO suppressed grain growth in Ce-TZP by drag force exerted by $Mn^{+2}$ ions which segregated strongly to the positively-charged grain boundaries of Ce-TZP, $Nb_2O_5$ enhanced grain growth by increasing the concentration of vacancies of $Zr^{+4}$ ion and $Ce^{+4}$ ions. Surface analysis with X-ray photoelectron spectroscopy (XPS) showed the segregation of Mn+2 ions to grain boundaries. The kinetics of grain growth obtained in the base Ce-TZP and the Ce-TZPs with the aliovalent dopants were examined in the context of impurity drag effect and space charge effect.

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비정질 및 단결정 실리콘에서 10~50 keV 에너지로 주입된 안티몬 이온의 분포와 열적인 거동에 따른 연구 (A Study on Implanted and Annealed Antimony Profiles in Amorphous and Single Crystalline Silicon Using 10~50 keV Energy Bombardment)

  • 정원채
    • 한국전기전자재료학회논문지
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    • 제28권11호
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    • pp.683-689
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    • 2015
  • For the formation of $N^+$ doping, the antimony ions are mainly used for the fabrication of a BJT (bipolar junction transistor), CMOS (complementary metal oxide semiconductor), FET (field effect transistor) and BiCMOS (bipolar and complementary metal oxide semiconductor) process integration. Antimony is a heavy element and has relatively a low diffusion coefficient in silicon. Therefore, antimony is preferred as a candidate of ultra shallow junction for n type doping instead of arsenic implantation. Three-dimensional (3D) profiles of antimony are also compared one another from different tilt angles and incident energies under same dimensional conditions. The diffusion effect of antimony showed ORD (oxygen retarded diffusion) after thermal oxidation process. The interfacial effect of a $SiO_2/Si$ is influenced antimony diffusion and showed segregation effects during the oxidation process. The surface sputtering effect of antimony must be considered due to its heavy mass in the case of low energy and high dose conditions. The range of antimony implanted in amorphous and crystalline silicon are compared each other and its data and profiles also showed and explained after thermal annealing under inert $N_2$ gas and dry oxidation.