• Title/Summary/Keyword: Segregation effect

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Microstructure and Wear Resistance Properties of Cu-W Sintered Materials Fabricated by Hot Pressing (Hot pressing으로 제조된 Cu-W계 소결재의 미세조직 및 내마모특성)

  • Park, Ji-Hwan;Kim, Su-Bang;Park, Yun-U
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.227-232
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    • 2000
  • Cu-W composites containing 20wt.% W were fabricated by hot pressing. Hot pressing was carried out at temperatures ranging from 800 to $1000^{\circ}C$ under pressures of 15MPa for 30MPa for 30min and 60min. This process gave composites of higher density, higher hardness and higher wear resistance than the conventional sintering processes. However, the microstructure of Cu-W composites under pressure of 15MPa revealed there was an inhomogeneous distribution of W, segregation of W on some area. These undesirable results are attributed to the immiscibility of W in Cu and the pressure effect on sintering.

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Application of Fuller's ideal curve and error function to making high performance concrete using rice husk ash

  • Hwang, Chao-Lung;Bui, Le Anh-Tuan;Chen, Chun-Tsun
    • Computers and Concrete
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    • v.10 no.6
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    • pp.631-647
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    • 2012
  • This paper focuses on the application of Fuller's ideal gradation curve to theoretically design blended ratio of all solid materials of high performance concrete (HPC), with the aid of error function, and then to study the effect of rice husk ash (RHA) on the performance of HPC. The residual RHA, generated when burning rice husk pellets at temperatures varying from 600 to $800^{\circ}C$, was collected at steam boilers in Vietnam. The properties of fresh and hardened concrete are reviewed. It is possible to obtain the RHA concrete with comparable or better properties than those of the specimen without RHA with lower cement consumption. High flowing concrete designed by the proposed method was obtained without bleeding or segregation. The application of the proposed method for HPC can save over 50% of the consumption of cement and limit the use of water. Its strength efficiency of cement in HPC is 1.4-1.9 times higher than that of the traditional method. Local standards of durability were satisfied at the age of 91 days both by concrete resistivity and ultrasonic pulse velocity.

The Relationship between Microstructure and Property of Rapidly Solidified Al-Mg-X(X=Cr, Zr or Mn) Asloys (급속응고 Al-Mg-X(X=Cr, Zr or Mn) 합금의 미세구조와 특성간의 관계)

  • 맹덕영
    • Journal of Powder Materials
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    • v.3 no.4
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    • pp.271-278
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    • 1996
  • In this study, the effect of the transition elements on the microstructure and mechanical properties of rapidly solidified Al-Mg-X alloys was investigated. As a result of the rapid solidification processing, fine equiaxed grains with a mean diameter of 2 $\mu$m were observed in these alloys. Many fine particles were found to be distributed rather homogeneously throughout the matrix with relatively large particles occasionally at grain boundaries. The ultimate tensile strengths of Al-Mg-X alloys were found to decrease rather remarkably at 150 $^{\circ}C$ without the gain of the ductility at 150 $^{\circ}C$, which may result from segregation of $\beta$ ($Al_{3}Mg_{2}$) precipitates. Fine dimples were observed on the fracture surfaces for all alloy systems and the variation of the size and shape of dimples was not observed upon alloy systems. The ductility at 530 $^{\circ}C$ was found to be ~100%, suggesting that grain boundary sliding did not contribute to ductiliy despite he grain size stabilization. The absence of superplastic behavior may be associated with low boundary misorientation in rapidly solidified Al-Mg-X alloys.

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Cost effective optimal mix proportioning of high strength self compacting concrete using response surface methodology

  • Khan, Asaduzzaman;Do, Jeongyun;Kim, Dookie
    • Computers and Concrete
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    • v.17 no.5
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    • pp.629-638
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    • 2016
  • Optimization of the concrete mixture design is a process of search for a mixture for which the sum of the cost of the ingredients is the lowest, yet satisfying the required performance of concrete. In this study, a statistical model was carried out to model a cost effective optimal mix proportioning of high strength self-compacting concrete (HSSCC) using the Response Surface Methodology (RSM). The effect of five key mixture parameters such as water-binder ratio, cement content, fine aggregate percentage, fly ash content and superplasticizer content on the properties and performance of HSSCC like compressive strength, passing ability, segregation resistance and manufacturing cost were investigated. To demonstrate the responses of model in quadratic manner Central Composite Design (CCD) was chosen. The statistical model showed the adjusted correlation coefficient R2adj values were 92.55%, 93.49%, 92.33%, and 100% for each performance which establish the adequacy of the model. The optimum combination was determined to be $439.4kg/m^3$ cement content, 35.5% W/B ratio, 50.0% fine aggregate, $49.85kg/m^3$ fly ash, and $7.76kg/m^3$ superplasticizer within the interest region using desirability function. Finally, it is concluded that multiobjective optimization method based on desirability function of the proposed response model offers an efficient approach regarding the HSSCC mixture optimization.

Effect of Rapid Thermal Annealing on the Resistivity Changes of Reactively Sputtered Tungsten Nitride Thin Film (Sputtering법으로 제조된 Tungsten Nitride 박막의 저항변화에 미치는 급속 열처리 영향)

    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.29-33
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    • 2000
  • The amorphous tungsten nitrides, WNx, film could be fabricated by reactive sputtering process. The nitrogen concentration for the amorphization ranges from 10 at% to 40at%. The amorphous $W_{67}N_{33}$ film was crystallized into low resistivity $\alpha$-tungsten phase with equiaxed grains and excess nitrogen after the rapid thermal annealing for 1min at 1273K, which was similar to the resistivity of the sputtered pure tungsten film. The excess nitrogen was depleted from $\alpha$-tungsten crystals and then segregated at $\alpha$-tungsten/poly-Si interface. The segregated nitrogen has favored the formation of the homogeneous diffusion barrier layer comprised of silicon nitride, $Si_3N_4$, nano-crystals, which undertaken the inhibition of the high resistivity tungsten silicide reaction.

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Empirical Analyses of Physical Exclusiveness of Multi-family Housing Estates in Seoul and Its Socioeconomic Effects (아파트단지의 물리적 폐쇄성과 사회경제적 효과에 관한 실증분석)

  • Kim, Ji-Eun;Choi, Mack-Joong
    • Journal of the Korean housing association
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    • v.23 no.5
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    • pp.103-111
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    • 2012
  • This study empirically investigates the degree of physical exclusiveness of multi-family housing estates and its socioeconomic effects. By combining various physical elements devised to blockade and control the entrance to the estate as well as housing units, it constructs the index to quantify the degree of physical exclusiveness for the multi-family housing estates of more than 300 households in Seoul. The statistics reveal that the degree of physical exclusiveness has increased over time and therefore, as a representative example, two-thirds of the estates are now equipped with barricade at the entrance, which often symbolizes 'gated community'. The estimation result of hedonic price model show that physical exclusiveness has a significant positive effect on housing price. The household survey data for the case study estates also demonstrate that the residents in the estate of higher degree of physical exclusiveness put a higher housing value on socioeconomic 'prestige' as well as 'community', beyond physical 'security', and have closer neighborhood relationship with the residents inside the estate. However, there is no significant difference in neighborhood relationship with the outside residents depending upon the degree of physical exclusiveness.

A Study on Fatigue strength by hardenability of Boron Addition Steel (보론 첨가강의 경화기구에 따른 기계적 성질에 관한 연구)

  • Lee, Jong-Hyung;Yoo, Duck-Sang;Park, Shin-Kyu
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.4
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    • pp.299-305
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    • 2003
  • This research is for the relationship with heat treatment cooling temprature and the characteristic of Mechanical properties of Boron-Addition-Steel, the main material and SM25C steel, the sub material, structure viewing fractography, hardness test, tensite test and are carried out after the manufacturing small-specimen treated with heat of $750^{\circ}C$, $850^{\circ}C$, $1050^{\circ}C$. The influence to the Mechanical properties accompanied by AISI51B20, Boron-Addition-steel shows the following result. 1. The influenc of heat treatment by the content of cabon-steel is dominant. Addition of boron result is Strengthening structure effectively by segregation and improving over all mechanical characters such as good. it results from the increase of temacity by the stability of inter granular with improvement of harden-ability. 2. Boron-Addition-Steel exist in the from of martensite structure accompanied by the ferrite precipitition centering around grain boundary, and is improved to Hv 200. 3. The height of harden-ability and fatigue stress the influence of heat results from crystal structure of martensite by difference of strength level in the structure of ferrite and doesn't have am effect on sensibility of temperature, and turns out to defend on production and growth of Matrix-structure-factor.

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Induced Mutant by Gamma Rays and Genetic Analysis for Mutant Characters in Flue-cured Tobacco Variety (Nicotiana tabacum L.) I. Induced Mutations and Characteristics of Mutant (황색종 연초 품종의 Gamma선에 의한 돌연변이 유수 및 변이형질의 유전분석 I. 돌연변이 유기 및 변이체의 특징)

  • Jung, Seok-Hun;Lee, S.C.;Kim, H.B.
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.12-23
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    • 1992
  • This experiment was conducted to determine the optimum dosage of gamma rays for inducing artificial mutation of several mutant characters in the flue-cured tobacco. 1) In Hicks and BY 104, the gammarays irradiation has no significantly different effect on seed germination from the control. However, the average dosage for 50% growth inhibition was 25-30kr for all the varieties tested, which inhibition 46-52% and 43-57% of the seedling growths for Hicks and BY 104, respectively. 2) A mutant line 83H-5 was selected from Hicks by irradiation gamma ray at the level of 30kr. It has white flower, more resistance to bacterial wilt, Pssudomonas solanacearum, lower plant and stalk height, narrower leaf width, larger leaf shape index(lento width) and later days to flower when compared with the original variety Hicks. 3) White flower was recessive to pink flower in F, and Br (F1 X Hicks) progenies. F2 population of the cross gave segregation ratio of 3 pink flower:1 white flower, and B, (F1 X 83H-5) Population gave 1:1 ratio. Results showed that the white flower character is governed by a single recessive gene.

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Effects of Cloned Genes on the Stability of Shuttle Vectors between Escherichia coli and Corynebacterium glutamicum (Escherichia coli와 Corynebacterium glutamicum간의 shuttle vectors의 C. glutamicum에서의 안정성에 대한 클론된 유전자의 영향)

  • 노갑수;김성준;오종원;이현환;현형환;이재흥
    • Korean Journal of Microbiology
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    • v.29 no.3
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    • pp.149-154
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    • 1991
  • Escherichia coli/Corynebacterium glutamicum shuttle vectors, pECCG1 and pECCG2 were constructed by joining a 3.00 kb cryptic plasmid pCB 1 from C. glutamicum and a 3.94 kb plasmid pACYC 177 from E. coli. By trimming unessential parts and introducing mulitiple cloning site into the plasmid pECCG 1, a plasmid pECCG122(5.1kb) was constructed. All the shuttle vectors were stably maintained in C. glutamicum up to about 40 generations irrespective of kanamycin addition in the medium. Threonine operon (homoserine dehydrogenase/homoserine kinase) and dapA gene (dihydrodipicolinate synthetase) of C. glutamicum were cloned into the plasmid pECCG122, and the resultant plasmids were designated pTN31 and pDHDP19, respectively. They were used to study the effect of cloned foreign gene on the stability of the plasmid pECCG122. Plasmids pTN31 and pDHDP19 were segregated rapidly from C. glutamicum when cultured in the medium without kanamycin. In medium with $50\mu${\g/ml} of kanamycin, their segregation rates were much slower than those in medium without kanamycin, but the danamycin addition didn't guarantee the complete maintenance of the plasmids in C. glutamicum.

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Influence of Nb Addition and Austenitizing Temperature on the Hardenability of Low-Carbon Boron Steels (저탄소 보론강의 경화능에 미치는 Nb 첨가와 오스테나이트화 온도의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.577-582
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    • 2015
  • The present study is concerned with the influence of niobium(Nb) addition and austenitizing temperature on the hardenability of low-carbon boron steels. The steel specimens were austenitized at different temperatures and cooled with different cooling rates using dilatometry; their microstructures and hardness were analyzed to estimate the hardenability. The addition of Nb hardly affected the transformation start and finish temperatures at lower austenitizing temperatures, whereas it significantly decreased the transformation finish temperature at higher austenitizing temperatures. This could be explained by the non-equilibrium segregation mechanism of boron atoms. When the Nb-added boron steel specimens were austenitized at higher temperatures, it is possible that Nb and carbon atoms present in the austenite phase retarded the diffusion of carbon towards the austenite grain boundaries during cooling due to the formation of NbC precipitate and Nb-C clusters, thus preventing the precipitation of $M_{23}(C,B)_6$ along the austenite grain boundaries and thereby improving the hardenability of the boron steels. As a result, because it considerably decreases the transformation finish temperature and prohibits the nucleation of proeutectoid ferrite even at the slow cooling rate of $3^{\circ}C/s$, irrespective of the austenitizing temperature, the addition of 0.05 wt.% Nb had nearly the same hardenability-enhancing effect as did the addition of 0.2 wt.% Mo.