• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.1-4
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• 1998

Segmented Polyurethanes Elastomers are a class of polymers having interesting properties which arise from their unique phase-separated structures resulting from the thermodynamic incompatibility of the ingredients[1]. Segmented polyurethane Elastomer generally consists of a segment derived from a polymeric diol and a hard segment from a diisocyanate and a low molecular weight diol(chain extender).(omitted)

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.71-75
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• 1998

Segmented block copolymer인 polyurethane은 열역학적으로 불친화성을 갖는 두 segment unit (Hard segment unit과 Soft segment unit)에 의해 미세 상분리 현상이 나타나며 그 결과 hard-segment-rich hard domain과 soft-segment-rich soft matrix 구조를 갖는다. 상온보다 높은 유리전이온도를 갖는 hard segment와 낮은 유리전이온도를 갖는 soft segment의 특성으로 인해 polyurethane은 열가소성 탄성체의 성질을 갖으며 두 성분의 조성비에 따라 넓은 범위의 역학적인 성질을 나타낸다.(중략)

• 한국정밀공학회지
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• 제22권2호
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• pp.180-187
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• 2005

This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2002년도 추계총회 및 학술발표회
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• pp.61-61
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• 2002

• 한국막학회:학술대회논문집
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• 한국막학회 1999년도 추계 총회 및 학술발표회
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• pp.23-26
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• 1999

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 가을 학술발표회논문집
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• pp.98-101
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• 1998

Segmented polyurethane elastomers are an important class of polymeric materials consisting of thermodynamically incompatible hard and soft segments. Due to the chemical structural difference between the hard and soft segments, a microphase separation occurs, consisting of crystalline hard domains and amorphous soft domains. (omitted)

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 가을 학술발표회 논문집
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• pp.55-58
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• 2003

Segmented polyurethanes have been widely used for various commercial and experimental blood-contacting and tissue-contacting applications such as vascular prostheses, blood pumps, heart valves, pacemaker lead wire insulation, catheters, artificial hearts, and cardiac assist devices due to their generally favorable physical and mechanical properties, as well as fairly good biocompatibility and antithrombogenicity characteristics. (omitted)

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.5-8
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• 1998

Polyurethane elastomers are segmented cocoplymer with an [HS]n-type structure. Typically, these materials are two-phase systems, prepared from relatively polar and stiff component called the hard segment(H) and relatively flexible component known as the soft segment(S). Diisocyanate and chain extender together form the hard segment, which is dispersed within a matrix of the soft segment, composed of the macrodiolos.(omitted)

• 센서학회지
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• 제9권1호
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• pp.28-35
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• 2000

본 연구에서는 폴리우레탄 합성반응의 특성을 수정진동자 분석기(QCA)의 공진주파수와 공진저항을 동시에 측정하여 분석하였다. 폴리우레탄 합성반응 초기에 생성된 폴리우레탄이 자동촉매반응을 일으켜 공진주파수가 급격히 감소한다는 것을 알 수 있었다. 프리폴리머(prepolymer, PP) 합성반응에서는 어느 순간 급속히 공진주파수가 감소하다 서서히 안정화되었다. 사슬연장제가 첨가된 세그먼티드 폴리우레탄(segmented polyurethane, SPU) 합성반응에서는 어느 순간 공진주파수가 급속히 감소하다가 다시 증가하였다. 이는 소프트세그먼트(soft segment, SS)에 사슬연장제인 1, 4-butandiol이 반응하여 하드세그먼트(hard segment, HS)로 변화됨으로써 강직한 HS 분자구조의 생성에 따라 공진주파수가 증가하였다고 생각된다. 또한 공진저항은 각각의 메카니즘을 해석하는데 사용하였다. 본 연구 결과, 폴리우레탄의 반응특성을 수정진동자 분석기(QCA)를 이용함으로써 온라인 분석할 수 있었으며, 반응메카니즘을 해석할 수 있었다.

• 품질경영학회지
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• 제9권1호
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• pp.22-39
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• 1981

Spandex is a elastomeric fiber in which the-fiber-forming substance is a long chain polymer consisting of at least 85% segmented polyurethane. In the polyurethanes there are the additional oxygen atoms in the main chains of the molecule. The effect of these oxygen atoms is to make the molecule somewhat more flexible. From a physical point of view, elasicity and recovery from stretch are the most important properties of polyurethane, so its use has now expanded into many kitting industry. In this paper, I wish to Test the effect of dyeing condition on the quality of polyurethane.