• Title/Summary/Keyword: Secondary roughness

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Effect of Surface Modification by Solvent Treatment on Morphology and Radionuclide Pick-up Efficiency of Polysulfone Film (폴리설폰 필름의 형상 및 방사성 오염물 채취에 있어 용매처리의 효과)

  • 한명진;이근우;서범경;박진호;남석태
    • Membrane Journal
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    • v.14 no.2
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    • pp.126-131
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    • 2004
  • The surface of dense polysulfane films was modified through solvent treatment. The modification process consisted of dipping a film for one second in dimethylformamide and then immersing it Into a nonsolvent bath. After being solidified, the original transparent film transformed into an opaque white one, which is due to the light scattering on pores newly developed on the surface. The surface roughness entailing the pore formation was more explicit on a film coagulated by water as nonsolvent than on a film coagulated by isopropanol. The surface-modified films show the better pick-up efficiency than a conventional filter paper on the detaching of radioactive contaminants on the contaminated area. The pick-up efficiency of the film prepared by the water immersion process was superior to that of the film prepared in the isopropanol bath, which was consistent with the surface roughness result. The surface-modified films kept the dense inner structure, playing a major role preventing a possible secondary contamination during the pick-up process.

Effect of Defect Energy levels on the AC PDP Discharging Characteristics (MgO 보호막의 결함 전위 레벨이 AC-PDP 방전 특성에 미치는 효과)

  • Kwon, Sang-Jik;Kim, Yong-Jae;Cho, Eou-Sik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.12
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    • pp.12-17
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    • 2007
  • The effects of the evaporation rate of MgO films using an electron beam on the MgO properties and the discharge characteristics of a plasma display panel(PDP) were investigated and analyzed. Mgo films were deposited with the various MgO evaporation rates. The MgO properties such as the crystal orientation, the surface roughness, and the film structure, were inspected using XRD(X-ray diffractometry), AFM(atomic force microscopy). From the experiments and Paschen law, the maximum value of the secondary, electron emission coefficient $(\gamma)$ was obtained at the evaporation rate of $5\AA/sec$. The minimum firing voltage and the maximum luminous efficiency were obtained at an evaporation rate of $5\AA/sec$. In the MgO film deposited at $5\AA/sec$, the (200) orientation and $F^+$ center were most intensive. The XRD results and cathode-luminescence(CL) spectra show the $\gamma$ values are correlated with $F/F^+$ centers of the molecular structure of MgO films.

Simplified Design of Commercial Pipes with Considering Secondary Losses (부차 손실을 고려한 상용관로의 간편 설계)

  • Yu, Dong-Hun;Jeong, Won-Guk
    • Journal of Korea Water Resources Association
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    • v.34 no.1
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    • pp.31-43
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    • 2001
  • The friction factor of commercial pipe varies with wide range depending on pipe type and pipe size. Various methods can describe the wide variation of friction factor with good accuracy, but they normally require an iteration process even for solution of a simple case. Power law can result in an explicit form of solver so that the power law is rigorously employed for the development of direct solution technique. The parameters used in the present form of power law are allowed to haute some variation with pipe size and Reynolds number as well as pipe type for wider coverage with good accuracy, while Hazen-Williams equation permits limited variation which accounts only for the roughness or the pipe type. Furthermore secondary loss is considered in the development of explicit equations for design of commercial pipes.

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Manufacture of magnetite (Fe3O4) electrode and its electrochemical properties (마그네타이트 (Fe3O4) 전극의 제조와 전기화학 특성)

  • Kim, Myong-Jin;Kim, Dong Jin;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.14 no.1
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    • pp.19-24
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    • 2015
  • Flow Accelerated Corrosion (FAC) causes unexpected accidents in a secondary side of a nuclear power plant. The secondary side pipes are mainly carbon steel tubes that have a protective magnetite ($Fe_3O_4$) layer on the inner surface. The stability of the protective magnetite layer depends on the parameters related to the FAC phenomena such as pH, temperature, flow rate, surface roughness etc. The dissolution of magnetite is basically the electrochemical reaction, but the most of the experiments of magnetite dissolution were carried out thermodynamically to determine the solubility of magnetite. The knowledge of the electrochemical properties of magnetite is required to understand the dissolution process of magnetite. This paper reviews the manufacture of the magnetite ($Fe_3O_4$) electrode, and summaries the electrochemical properties of the magnetite.

The Study of Formation of Ti-silicide deposited with Composite Target [II] (Composite Target으로 증착된 Ti-silicide의 현성에 관한 연구[II])

  • Choi, Jin-Seog;Paek, Su-Hyon;Song, Young-Sik;Sim, Tae-Un;Lee, Jong-Gil
    • Korean Journal of Materials Research
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    • v.1 no.4
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    • pp.191-197
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    • 1991
  • The surface roughnesses of titanium silicide films and the diffusion behaviours of dopants in single crystal and polycrystalline silicon substrates durng titanium silicide formation by rapid thermal annealing(RTA) of sputter deposited Ti-filicide film from the composite $TiSi_{2.6}$ target were investigated by the secondary ion mass spectrometry(SIMS), a four-point probe, X-ray diffraction, and surface roughness measurements. The as-deposited films were amorphous but film prepared on single silicon substrate crystallized to the orthorhombic $TiSi_2$(C54 structure) upon rapid thermal annealing(RTA) at $800^{\circ}C$ for 20sec. There was no significant out-diffusion of dopants from both single crystal and polycrystalline silicon substrate into titanum silicide layers during annealing. Most of the implanted dopants piled up near the titanium silicide/silicon interface. The surface roughnesses of titanium silicide films were in the range between 16 and 22nm.

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A study for development of a dielectric protection layer in PDP (I) (The annealing characteristics of thickness-optimized $Al_2O_3/MgO$) (PDP용 유전체 보호막 재료 개발을 위한 연구 (I) (두께 최적화된 $Al_2O_3/MgO$의 열처리 특성 ))

  • Jeoung, Jin-Man;Yim, Ki-Ju;Shin, Kyung;Lee, Hyun-Yong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.117-120
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    • 1998
  • In this study, $Al_2O_3/MgO$ bilayer was prepared with Electron-beam evaporation and the properties of the film was investigated in order to improve the property of MgO film, which is used for the protection layer in PDP(P1asma Display Panel). The thickness of $Al_2O_3/MgO$ bilayer was optimized by the Matrix Theory for the fabrication of antireflection structure for 5350A wavelength. The secondary electron emission yields of as-deposited film and annealed film were measured and compared, the bilayer was considered for the applicability as PDP. XRD showed the strong (200) primary peak of MgO. The intensity of (200) peak in the film annealed at 300C was decreased. As the result of SEM analysis for MgO films and Alz03 films, it is considered that the morphology of the films were improved of roughness and it were condensed by annealing.

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Charge-Discharge Characteristics of Physically Coated Lithium Anodes by Carbon Powders (탄소분말이 물리적으로 코팅된 리튬 음전극의 충방전 특성)

  • Kim, Kwang Man;Lee, Sang Hyo;Lee, Young-Gi
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.554-559
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    • 2011
  • To improve the safety and electrode characteristics of lithium metal anode, physically coated electrodes on lithium metal surface by three kinds of carbon are prepared and their charge-discharge performances are investigated by adopting the C-Li electrodes as the anode of rechargeable lithium batteries. The lithium anode coated by the carbon powder with smaller particle size and higher surface area, which has higher packing density and lower surface roughness, shows better performance in charge-discharge characteristics. The carbon coating on lithium surface can be more effective in small-sized cells.

Improving the Crystallinity of Heteroepitaxial Single Crystal Diamond by Surface Modification (표면개질에 의한 헤테로에피텍시 단결정 다이아몬드의 결정성 향상)

  • Bae, Mun Ki;Kim, Min Su;Kim, Seong Woo;Yoon, Su Jong;Kim, Tae Gyu
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.3
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    • pp.124-128
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    • 2020
  • Recently, many studies on growth of single crystal diamond using MPECVD have been conducted. The heteroepitaxial method is one of the methods for growing diamonds on a large-area substrate, and research on synthesis of single crystal diamonds using SrTiO3, MgO, and sapphire substrates has been attempted. In addition, research is being conducted to reduce the internal stress generated during diamond growth and to improve the crystallinity of the diamond. The compressive stress generated therein causes peeling and bowing from the substrate. This study aimed to synthesize heteroepitaxial single crystal diamonds with high crystallinity by surface modification. A diamond thin film was first grown on a sapphire/Ir substrate by MPECVD, and then etched with H2 gas to modified the morphology and roughness of the surface. A secondary diamond layer was grown on the surface, and the internal stress, crystallinity of the diamond were investigated. As a result, the fabrication of single crystal diamonds with improved crystallinity was confirmed.

Efficiency Characteristics of Cu(In,Ga)Se2 Photovoltaic Thin Films According to the Mo:Na Thickness (Mo:Na두께에 따른 Cu(In,Ga)Se2 태양전지 박막의 효율 특성)

  • Shin, Younhak;Kim, Myunghan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.701-706
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    • 2013
  • We have focused on the conversion efficiency of CIGS thin film solar cell prepared by co-evaporation method as well as the optimization of process condition. The total thickness of back electrode was fixed at 1 ${\mu}m$ and the structural, electric and optical properties of CIGS thin film were investigated by varying the thickness of Mo:Na bottom layer from 0 to 500 nm. From the experimental results, the content of Na was appeared as 0.28 atomic percent when the thickness of Mo:Na layer was 300 nm with compactly densified plate-shape surface morphology. From the XRD measurements, (112) plane was the strongest preferential orientation together with secondary (220) and (204) planes affecting to the crystallization. The lowest roughness and resistivity were 2.67 nm and 3.9 ${\Omega}{\cdot}cm$, respectively. In addition, very high carrier density and hole mobility were recorded. From the optimization of Mo:Na layer, we have achieved the conversion efficiency of 9.59 percent.

A Behavior of Fatigue Crack Growth of Nonmagnetic Steel with Large Grain Size (조대조직을 갖는 비자성강의 피로균열진전거동)

  • Lee, Jong-Hyung;Choi, Seong-Dae;Cheong, Seon-Hwan;Kwon, Hyun-Kyu;Yang, Seong-Hyeon
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.4
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    • pp.88-94
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    • 2004
  • High manganese steel was maintained stability of Non-Magnetics performance. Fatigue tests were carried out under constant stress amplitude, using a non-magnetic high manganese steel. The fatigue crack growth mechanism of the high manganese steel was clarified from results such as observation of crack growth path and fracture surface. The result of getting this study was shown as following: 1) Remarkably ${\Delta}Kth$ of the high manganese steel is big with about 3 times of the general steel product. 2) In the low ${\Delta}K$ value region, da/dN is dependent on Kmax, and in the high ${\Delta}K$ value region, it is dependent on ${\Delta}Keff$. The reason of this behavior is crack closure due to fracture surface roughness and fretting oxide. 3) It seems to ease the stress concentration of crack tip crack growth behavior in the ${\Delta}Kth$ vicinity by the generation of the secondary crack.

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