• Journal of the Korean Ceramic Society
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• v.47 no.6
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• pp.638-642
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• 2010

The spinel material $Li_4Ti_5O_{12}$ has attracted considerable attention as an anode electrode material for many battery applications owing to its light weight and high energy density. However, the real capacity of $Li_4Ti_5O_{12}$ powder as determined by the solid-state method is lower than the ideal capacity. In this study, we investigated the effect of the dopants in M-doped spinel $Ba_xLi_{4-2x}Ti_5O_{12}$(x=0.005, 0.05, 0.1) powders prepared by the solid-state reaction method and used as the anode material in lithiumion batteries. The results confirmed the effect of the Ba and Sr dopants on the powder properties of the spinel $Li_4Ti_5O_{12}$, which exhibited a pure spinel structure without any secondary phase in its XRD pattern. Moreover, the electrochemical properties of the spinel M-LTO materials were investigated using a half cell. The electrochemical data show that cells with anodes made of undoped $Li_4Ti_5O_{12}$ and Ba- and Sr-doped $Li_4Ti_5O_{12}$ have discharge capacities of 97, 130, and 112 mAh/g, respectively, at the first cycle. Moreover, the Ba- and Sr-doped spinel $Li_4Ti_5O_{12}$ demonstrated good properties in the mid-voltage range at 1.55 V, showing stable cyclic voltammogram properties which surpassed those of the same material without Ba or Sr at 1 C after 100 cycles.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.63 no.1
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• pp.34-39
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• 2014

In cognitive radios, secondary users can use the spectrum exclusively allocated to a primary wireless system if the secondary users detect the spectrum in idle states. Because the secondary users can utilize the idle state of the spectrum, the utilization rate of the spectrum can be improved. The idle states can be detected by using secondary users' sensing schemes. However, the wireless channel environment where secondary users perform the spectrum sensing is not very friendly to secondary users because the signal-to-noise ratio of the received primary signal is very low. Hence, cooperative sensing scheme where more than one secondary user take part in the spectrum sensing is generally used in cognitive radios. In this paper, we investigate the cooperative sensing performance for machine-to-machine communication devices operated by batteries with limited energy. In general, the energy consumed for the spectrum sensing increases as the length of the sensing period and the number of cooperative sensing nodes. Accordingly, even though the total amount of the consumed energy is the same, an energy allocation methodology how to distribute the energy to the sensing period and sensing nodes can achieve the optimum sensing performance, which is numerically analyzed.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.12
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• pp.1619-1625
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• 2018

Portable electronic devices secondary batteries can cause fire and explosion due to micro-current change in addition to the situation of short-circuit inrush current, safety can not be secured with a general operation limited current fuse. Therefore, in secondary battery, it is necessary for the protector to satisfy both the limit current type operation in the open-short-circuit inrush current and the current detection operation characteristic in the micro current change situation and for this operation, a fuse for the current detection type secondary battery protection circuit can be applied. The purpose of this study is to design a protection device that operates stably in the hazardous situation of small capacity secondary battery for portable electronic devices through the design of low melting fuse elements alloy of sensing type fuse and secures stability in abnormal current state. As a result of the experiment, I-T and V-T operation characteristics are satisfied in a the design of the alloy of the current sensing type self-contained low melting point fuse and the resistance of the heating resistor. It is confirmed that it can prevent accidents of short circuit over-current and micro current change of secondary battery.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.9
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• pp.326-332
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• 2018

Korea faces major changes in energy policy, which include eco-friendly and zero-nuclear power. On the other hand, there are very few policies for the waste-management of mid- to large-sized lithium-ion batteries, such as electric car batteries and energy storage systems, which are expected to increase explosively due to such energy policy changes. Therefore, this study estimated the amount of mid- to large-sized lithium ion batteries waste and performed economics analysis of a middle and large sized secondary battery recycling project. Based on the results, a policy alternative for the revitalization of the related lithium-ion battery recycling industry is suggested. As a result, the B / C ratio of a domestic mid - to large - sized lithium ion battery recycling project is 1.06, in which the benefit is higher than the cost, so the business is economic feasible. Although the recycling project's economic efficiency is high, the recycling industry has not been activated in Korea because the domestic demand for rechargeable batteries recycling is very low. To solve this problem, this study proposes a plan to activate the industry by adding lithium secondary batteries to the EPR (Extended Producer Responsibility) items.

• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.155-161
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• 2009

Lithium secondary batteries have been widely used in the portable electric devices as power source. Recently it is expected that the realm of its applications expands to the markets such as energy storage medium of hybrid electric vehicle(HEV), electric vehicle(EV). Cathode active material is crucial in terms of performance, durability, capacity of lithium secondary batteries. It is urgent to develope the technology for mass production of cathode material to cope with the markets' demands in the near future. In this study, a calcination furnace running in real production line is modelled in 3D, and the thermal flow and gas flow after chemical reaction in the furnace is analyzed through numerical computations. Based on the results, it is shown that large volume of $CO_2$ gas is generated from chemical reaction. High concentration of $CO_2$ gas and it's stagnation is clearly found from the reactant containers in which the reaction occur to the bottom area of the furnace. It is also studied that 15% or more $CO_2$ mol fraction could affect to proper formation of $LiCoO_2$ through TGA-DSC analysis. The solutions to evacuate carbon dioxide from the furnace are suggested through the change of furnace design and operating condition as well.

• Clean Technology
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• v.27 no.1
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• pp.33-38
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• 2021

Demand for lithium-based secondary batteries is greatly increasing with the explosive growth of related industries, such as mobile devices and electric vehicles. In Korea, there are several top-rated global lithium-ion battery manufacturers accounting for 40% of the global secondary battery business. Most discarded lithium secondary batteries are recycled as scrap to recover valuable metals, such as Nickel and Cobalt, but residual wastes are disposed of according to the residual lithium-ion concentration. Furthermore, there has not been an attempt on the possibility of water discharge system contamination due to the concentration of lithium ions, and the effluent water quality standards of public sewage treatment facilities are becoming stricter year after year. In this study, the as-received waste water generated from the cathode electrode coating process in the manufacturing of high-nickel-based NCM cathode material used for high-performance and long-term purposes was analyzed. We suggested a facile recycling process chart for waste water treatment. We revealed a correlation between lithium-ion concentration and pH effect according to the proposed waste water of each recycling process through analyzing standard water quality tests and daphnia ecological toxicity. We proposed a realistic waste water treatment plan for lithium electrode manufacturing plants via comparison with other industries' ecotoxicology.

• Journal of the Korean Electrochemical Society
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• v.8 no.4
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• pp.168-171
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• 2005

The electrochemical properties of $LiFePO_4$ as a cathode for Li-ion batteries were improved by incorporating conductive carbon into the $LiFePO_4$. X-ray diffraction analysis and SEM observations revealed that the carbon-coated $LiFePO_4$ consisted of fine single crystalline particles, which were smaller than the bare $LiFePO_4$. The electrochemical performance of the carbon-coated $LiFePO_4$ was tested under various conditions. The carbon-coated $LiFePO_4$ showed much better performance in terms of the discharge capacity and cycling stability than the bare $LiFePO_4$. The improved electrochemical performances were found to be attributed to the reduced particle size and enhanced electrical conductivity of the $LiFePO_4$ by the carbon.

• The Transactions of the Korean Institute of Power Electronics
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• v.11 no.6
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• pp.558-562
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• 2006

Although secondary batteries, called rechargeable batteries, are very important energy elements in modern society, their application is hindered by the typical nonlinear and irreversible characteristics. Precise monitoring of the state of health(SOH) for each battery cell on line is crucial for stable operation and proper management of them. This paper proposes diagnostic method of the SOH for a battery cell on line without interruption on its operation nor bad effect on its life. This paper practically diagnoses on 120 industrial batteries and provides some guide lines to decide whether to exchange or not.

• Proceedings of the KIPE Conference
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• 2014.07a
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• pp.191-192
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• 2014

Multiple output converters (MOCs) are widely used for applications which require various levels of the output voltages due to their benefits in cost, volume, and efficiency. However, most of the MOCs developed so far can regulate only one output tightly and require as many secondary windings in the transformer as the number of the outputs. In this paper, a novel Time Division Multiple Control (TDMC) method to regulate all the outputs in high precision is proposed and applied for the multiple output battery charger based on the phase shift full bridge topology to charge a multiple number of batteries at one time. The proposed converter can charge three different kinds of batteries or same kind of batteries in different state of charges (SOCs) by using constant current/constant voltage (CC/CV) charge mode independently. At the same time it can provide an even degree of tight regulation for each output to satisfy the strict ripple requirement of the battery. The validity and feasibility of the proposed method are verified through the experiments.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.180-186
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• 2018

We report the discovery of Li-rich $Li_{1+x}[(Ni_{0.225}Co_{0.15}Mn_{0.625})_{1-y}V_y]O_2$ as a cathode material for rechargeable lithium-ion batteries in which a small amount of tetravalent vanadium ($V^{4+}$) is selectively and completely incorporated into the manganese sites in the lattice structure. The unwanted oxidation of vanadium to form a $V_2O_5-like$ secondary phase during high-temperature crystallization is prevented by uniformly dispersing the vanadium ions in coprecipitated $[(Ni_{0.225}Co_{0.15}Mn_{0.625})_{1-y}V_y](OH)_2$ particles. Upon doping with $V^{4+}$ ions, the initial discharge capacity (>$275mA\;h\;g^{-1}$), capacity retention, and voltage decay characteristics of the Li-rich layered oxides are improved significantly in comparison with those of the conventional undoped counterpart.