• Title/Summary/Keyword: Secondary Battery

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Implementation of an Electrode Positioning System to Improve the Accuracy and Reliability of the Secondary Battery Stacking Process (2차 전지 적층 공정의 정확성과 신뢰성 향상을 위한 전극 위치결정 시스템 구현)

  • Lee, June-Hwan
    • Journal of Convergence for Information Technology
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    • v.11 no.6
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    • pp.219-225
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    • 2021
  • As for the battery package method, a prismatic package method is preferred for stability reasons, but it is rapidly expanding due to the stability verification of a pouch type package. The pouch type using the lamination process has an advantage of high battery energy density because it can reduce space waste, but has a disadvantage of low productivity. Therefore, in this paper, by extracting edge detection algorithm precision, pattern algorithm precision, and motion controller recall rate by improving backlight lighting fixtures to minimize light diffusion, securing standards for stereo camera position relationship displacement monitoring, and securing standards for lens release monitoring. We propose to implement a system that ensures accuracy and reliability in positioning. As a result of the experiment, the proposed system shows an average error range of 0.032mm for edge detection, 0.02mm for pattern algorithm, and 0.014mm for motion controller, thus ensuring the accuracy and reliability of the positioning mechanism.

Effective problem mitigation strategy of lithium secondary battery silicon anode utilized liquid precursor (에틸벤젠을 이용한 실리콘 산화물 음극재의 효과적인 카본 코팅 전략)

  • Sangryeol Lee;Seongsu Park;Sujong Chae
    • Journal of the Korean institute of surface engineering
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    • v.56 no.1
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    • pp.62-68
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    • 2023
  • Silicon (Si) is considered as a promising substitute for the conventional graphite due to its high theoretical specific capacity (3579 mAh/g, Li15Si4) and proper working voltage (~0.3V vs Li+/Li). However, the large volume change of Si during (de)lithiation brings about severe degradation of battery performances, rendering it difficult to be applied in the practical battery directly. As a one feasible candidate of industrial Si anode, silicon monoxide (SiOx) demonstrates great electrochemical stability with its specialized strategy, downsized Si nanocrystallites surrounded by Li+ inactive buffer phase (Li2O and Li4SiO4). Nevertheless, SiOx inherently has the initial irreversible capacity and poor electrical conductivity. To overcome those issues, conformal carbon coating has been performed on SiOx utilizing ethylbenzene as the carbon precursor of chemical vapor deposition (CVD). Through various characterizations, it is confirmed that the carbon is homogeneously coated on the surface of SiOx. Accordingly, the carbon-coated SiOx from CVD using ethylbenzene demonstrates 73% of the first cycle efficiency and great cycle life (88.1% capacity retention at 50th cycle). This work provides a promising synthetic route of the uniform and scalable carbon coating on Si anode for high-energy density.

Surface Treatment with Alkali Solution of Carbon Felt for Vanadium Redox Flow Battery (바나듐레독스흐름전지용 카본펠트전극의 알칼리용액을 이용한 표면개질)

  • KIM, SUNHOE;LEE, KEON JOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.4
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    • pp.372-377
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    • 2016
  • The carbon felt used as the electrode of vanadium redox flow battery (VRFB) requires imprived electrochemical activity for better battery performance and efficiencies. Many efforts have been tried to improve electrochemical activity of the carbon felt as electrodes. In this study the alkali solution, KOH, is applied on surface treatment of the carbon felt electrode. The carbon felts were treated with KOH under room temperature and $80^{\circ}C$. The isopropyl alcohol was applied to improve wettability of the carbon felt during KOH treatment. The KOH treated carbon felt was analyzed by using the X-ray photoelectron spectroscopy (XPS). The XPS analysis of carbon felt electrode revealed on increase in the overall surface oxygen content of the carbon felts after KOH treatment. Also, cyclic voltametry tests showed electrochemical characteristics enhancement of the carbon felt.

Development of Zinc Air Battery for Cellular Phone (휴대전화기용 아연공기전지 개발)

  • 엄승욱;김지훈;문성인;윤문수;김주용;박정식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.936-941
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    • 2004
  • In recent years, the rapid growth of portable electronic devices requires the high-energy density characteristics of batteries. Zinc air batteries have specific capacity as high as 820mAh/g. However, Zinc air batteries used for hearing aid applications only so far, because the atmosphere could affect it, and it has weakness in the rate capability. However, recent developments of electrode manufacturing technologies made us to overcome that weakness. And the efforts of applying zinc air batteries to portable electronic devices, especially in cellular phone application have been increased. In this paper, the effects of conducting material and polymer binder in cathode on the electrochemical characteristics were investigated. Our research team succeeded in producing 2.4Ah class zinc air battery for cellular phone application. Its volumetric energy density was 920 wh/l, and gravimetric energy density was 308 wh/kg. The volumetric energy density of our zinc air battery is two times higher than one of lithium secondary battery, and three times higher than that of alkaline manganese battery.

Diagnosis of State Of Health(SOH) for Battery Management System(BMS) (축전지 관리시스템(BMS)을 위한 건강상태(SOH) 진단방법)

  • Kim, Hyo-Sung
    • The Transactions of the Korean Institute of Power Electronics
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    • v.11 no.6
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    • pp.558-562
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    • 2006
  • Although secondary batteries, called rechargeable batteries, are very important energy elements in modern society, their application is hindered by the typical nonlinear and irreversible characteristics. Precise monitoring of the state of health(SOH) for each battery cell on line is crucial for stable operation and proper management of them. This paper proposes diagnostic method of the SOH for a battery cell on line without interruption on its operation nor bad effect on its life. This paper practically diagnoses on 120 industrial batteries and provides some guide lines to decide whether to exchange or not.

Preparation of Electrocatalysts and Comparison of Electrode Interface Reaction for Hybrid Type Na-air Battery (Hybrid type Na-air battery를 위한 촉매들의 제조 및 전극 계면 반응 성능 비교)

  • Kim, Kyoungho
    • Journal of Adhesion and Interface
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    • v.22 no.1
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    • pp.1-7
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    • 2021
  • The importance of high capacity energy storage devices has recently emerged for stable power supply through renewable energy generation. From this point of view, the Na-air battery (NAB), which is a next-generation secondary battery, is receiving huge attention because it can realize a high capacity through abundant and inexpensive raw materials. In this study, activated carbon-based catalysts for hybrid type Na-air batteries were prepared and their characteristics were compared and analysed. In particular, from the viewpoint of resource recycling, activated carbon (Orange-C) was prepared using discarded orange peel, and performance was compared with Vulcan carbon, which is widely used. In addition, a Pt/C catalyst (homemade-Pt/C, HM-Pt/C) was synthesized using a modified polyol method to check whether the prepared activated carbon can be used as a supported catalyst, and a commercial Pt/C catalyst (Commercial Pt/C) and electrochemical performance were compared. The prepared Orange-C exhibited a typical H3 type BET isotherm, which is evidence that micropore and mesopore exist. In addition, in the case of HM-Pt/C, it was confirmed through TEM analysis that Pt particles were evenly distributed on the activated carbon supported catalyst. In particular, the HM-Pt/C-based NAB showed the smallest voltage gap (0.224V) and good voltage efficiency (92.34%) in the 1st galvanostatic charge-discharge test. In addition, the cycle performance test conducted for 20 cycles showed the most stable performance.

Observation of Water Consumption in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.10 no.4
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    • pp.381-386
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    • 2019
  • Zn-air battery uses oxygen from the air, and hence, air holes in it are kept open for cell operation. Therefore, loss of water by evaporation through the holes is inevitable. When the water is depleted, the battery ceases to operate. There are two water consumption routes in Zn-air batteries, namely, active path (electrolysis) and passive path (evaporation and corrosion). Water loss by the active path (electrolysis) is much faster than that by the passive path during the early stage of the cycles. The mass change by the active path slows after 10 h. In contrast, the passive path is largely constant, becoming the main mass loss path after 10 h. The active path contributes to two-thirds of the electrolyte consumption in 24 h of cell operation in 4.0 M KOH. Although water is an important component for the cell, water vapor does not influence the cell operation unless the water is nearly depleted. However, high oxygen concentration favors the discharge reaction at the cathode.

Analysis and Implementation of a DC-DC Converter for Hybrid Power Supplies Systems

  • Yang, Lung-Sheng;Lin, Chia-Ching
    • Journal of Power Electronics
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    • v.15 no.6
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    • pp.1438-1445
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    • 2015
  • A new DC-DC power converter is researched for renewable energy and battery hybrid power supplies systems in this paper. At the charging mode, a renewable energy source provides energy to charge a battery via the proposed converter. The operating principle of the proposed converter is the same as the conventional DC-DC buck converter. At the discharging mode, the battery releases its energy to the DC bus via the proposed converter. The proposed converter is a non-isolated high step-up DC-DC converter. The coupled-inductor technique is used to achieve a high step-up voltage gain by adjusting the turns ratio. Moreover, the leakage-inductor energies of the primary and secondary windings can be recycled. Thus, the conversion efficiency can be improved. Therefore, only one power converter is utilized at the charging or discharging modes. Finally, a prototype circuit is implemented to verify the performance of the proposed converter.

Fabrication and Characterization of ${LiMn_2}{O_4}$ Cathode for Lithium Rechargeable Battery by R.F.Magnetron Sputtering (R.F. Magnetron Sputtering을 이용한 리튬이차전지 정극용 ${LiMn_2}{O_4}$의 제조 및 특성)

  • 우태욱;손영국
    • Journal of the Korean Ceramic Society
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    • v.37 no.6
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    • pp.552-558
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    • 2000
  • LiMn2O4 thin fiolm cathodes for Li-ion secondary battery were fabricated by r.f. magnetron sputtering technique. As-deposited films were amorphous. A spinel structure could not be obtained LiMn2O4 films by in-situ thermal annealing. After post thermal annealing over $700^{\circ}C$ in oxygen atmosphere, LiMn2O4 films prepared above 100 W r.f. power could be crystallized into a spinel structure. The electrochemical property of the LiMn2O4 film cathodes was tested in a Li/1 M LiClO4 in PC/LiMn2O4 cell. From cyclic voltammetry at scan rate of 2mV/sec of 2.5~4.5V, LiMn2O4 electrode prepared by post annealing at 75$0^{\circ}C$ showed good initial capacity. LiMn2O4 electrode prepared by post annealing at 80$0^{\circ}C$ showed the best crycling performance.

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Battery Management System for Secondary Battery (이차전지용 배터리 관리시스템)

  • Nam, Jong-Ha
    • Proceedings of the KIPE Conference
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    • 2008.10a
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    • pp.94-96
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    • 2008
  • 이차전지는 방전을 통하여 화학에너지를 전기에너지로 변환하여 사용하고 이의 역반응인 충전과정을 통하여 전기에너지를 화학에너지로 변환하여 저장함으로써 반복 사용이 가능하다. 많은 이차전지 중에서 리튬이차전지는 현재 핸드폰, 노트북, PDA 등 휴대용 전자기기가 보편화된 Mobile Energy 시대의 동력원이며, 최근 하이브리드 자동차, 지능형 로봇 등의 신산업분야에 적용하기 위한 고출력, 중/대형 이차전지의 개발이 활발히 진행되고 있다. 아울러 경쟁력을 확보하기 위해 전지부문에서는 에너지 밀도, 출력밀도, 사이클 수명, 안전성 등에서 지속적인 성능향상을 거듭하고 있으며, 활용면에서는 고밀도화에 따른 발열, 발화 사고의 안전성 문제를 해결하기 위해 배터리 보호회로를 필수적으로 장착하며, 이러한 보호회로는 용도에 따라 PCM(Protection Circuit Module), 스마트모듈(Smart Module), BMS(Battery Management System) 등으로 명칭되며, 각 사용분야별로 개발이 활발히 진행되고 있어 전지 시스템의 고안전성 및 고신뢰성을 추구하고 있다.

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