• Title/Summary/Keyword: Se

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A Study on photoluminescience of ZnSe/GaAs epilayer

  • Park, Changsun;Kwangjoon Hong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.84-84
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, I$_2$ (D$^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3meV The exciton peak, lid, at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The I$_1$$\^$d/ peak was dominantly observed in the ZnSe/GaAs:Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs:Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a (V$\sub$se/ - V$\sub$zn/) - V$\sub$zn-/

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Synthesis of $Cu_2ZnSnSe_4$ compound by solid state reaction using elemental powders

  • Wibowo, Rachmat Adhi;Alfaruqi, Muhammad H.;Jung, Woon-Hwa;Kim, Kyoo-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.134-137
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    • 2009
  • Commercially available elemental powders of Cu, Zn, Sn and Se were employed for crystallizing a stannite-type $Cu_2ZnSnSe_4$ compound by means of solid state reaction. $Cu_2ZnSnSe_4$ reaction chemistry was also modeled based on differential-thermal analysis and X-ray powder diffraction results. It was observed that Se tends to react preferably with Cu to form CuSe and $CuSe_2$ phases at low reaction temperature. The formation of $Cu_5Zn_8$ intermetallic phase was found to be the intermediate reaction path for the binary ZnSe formation. A solid state reaction at $320^{\circ}C$ reacted elemental powderst obinary selenides of CuSe, ZnSe and SnSe completely. The crystallization of $Cu_2ZnSnSe_4$ was was detected to begin at $300^{\circ}C$ and its weight fraction increased with an increase of reaction temperature, which most probably formed from the reaction between $Cu_2SnSe_3$ and ZnSe.

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Properties of photoluminescience for ZnSe/GaAs epilayer grown by hot wall epitaxy

  • Hong, Kwangjoon;Baek, Seungnam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.105-110
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, $I_{2}$ ($D^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3 meV, The exciton peak, $I_{1}^{d}$ at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The $I_{1}^{d}$ peak was dominantly observed in the ZnSe/GaAs : Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs : Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a $(V_{se}-V_{zn})-V_{zn}$.

Fabrication and Characterization of CuInSe2 Thin Films by Co-evaporation Method (Co-evaporation방법를 이용한 CuInSe2 박막 제조 및 특성분석)

  • Kwon, Se-Han;Kim, Seok-Ki;Yoon, Kyung-Hoon;Ahn, Byung-Tae;Song, Jin-Soo
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1437-1439
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    • 1996
  • In this paper, investigations on a three stage processing technique involving the co-evaporation of In-Se, Cu-Se and In-Se in this order at different deposition condition was undertaken. At first stage, we obtained good $In_{2}Se_{3}$ films by In-Se coevaporation. $In_{2}Se_{3}$ films show smooth and dense structure. And ration of In:Se was 2:3 $CulnSe_2$ thin films deposited by three stage process have shown strong adhesion on Mo coated glass substrates and good morphological properties suitable device fabrication. XWD spectra show single phase chalcopyrite $CulnSe_2$ films with strong orientation in the 112 plane. Resistivity of $CulnSe_2$ thin films was about $5{\times}10^{5}\;{\Omega}{\cdot}cm$. Surface morphology of CdS/$CulnSe_2$/Mo films was very good because of no pin holes.

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A Study point defect for thermal annealed ZnSe/GaAs epilayer

  • Hong, Kwang-Joon;Lee, Sang-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.120-123
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, $I_2$ ($D^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3 meV. The exciton peak, $I_1^d$, at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The $I_1^d$ peak was dominantly observed in the ZnSe/GaAs:Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs:Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a $(V_{Se}-V_{Zn})-V_{Zn}$.

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Top-Level Implementation of AI4SE, SE4AI for the AI-SE convergence in the Defense Acquisition (무기체계 획득에서 인공지능-시스템엔지니어링 융화를 위한 최상위 수준의 AI4SE, SE4AI 구현방안)

  • Min Woo Lee
    • Journal of the Korean Society of Systems Engineering
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    • v.19 no.2
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    • pp.135-144
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    • 2023
  • Artificial Intelligence (AI) is a prominent topic in almost every field. In Korea, Systems Engineering (SE) procedures are applied in Defense Acquisition, and it is anticipated that SE procedures will also be applied to systems incorporating AI capabilities. This study explores the applicability of the concepts "AI4SE (AI for SE)" and "SE4AI (SE for AI)," which have been proposed in the United States, to the Korean context. The research examines the feasibility of applying these concepts, identifies necessary tasks, and proposes implementation strategies. For the AI4SE, many attempts and studies applying AI to SE Processes both Requirements & Architectures Define, System implementation & V&V, and Sustainment. It needs Explainability and Security. For the SE4AI, the Functional AI implementation level, Quality & Security of the Data-set, AI Ethics, and Review policies are needed. Furthermore, it provides perspectives on how these two concepts should ultimately converge and suggests future directions for development.

Evaluation of Se Accumulation in the Production of Se-treated Soybean Sprouts and Mungbean Sprouts

  • Bai, Hong-Sook;Kim, Hyeong-Soo;Bai, Sung-Chul;Kim, Dae-Jin
    • Preventive Nutrition and Food Science
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    • v.14 no.2
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    • pp.142-147
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    • 2009
  • In this study, the selenium (Se) accumulations of soybean sprouts and mungbean sprouts treated with various concentrations of Se-solutions were evaluated, as part of a broader effort to produce Se-enriched variants of the plants. Four levels of sodium selenate ($Na_{2}SeO_{4}$)-dissolved solutions (i.e. 0, T0; 6, T1; 60, T2; and $600{\mu}g/mL$, T3) were prepared and sprayed onto the plants during cultivation. The effect of different spraying periods on Se accumulation was also assessed by watering plant groups once a day for periods of one, two, or three days. Se solution remaining on the surfaces of the plants was washed out by spraying with distilled water on the final day of cultivation. However, the increase of Se accumulation in the plants was found to depend on both Se-concentration and watering period, and the soybean sprouts were determined to accumulate Se more effectively than the mungbean sprouts. Additionally, with regard to Se accumulation in the plants, the period of application of Se solution was determined to be more important than the concentration of the Se solution applied. The averaged total levels of Se-enrichment in whole soybean sprouts at T0, T1, T2, and T3 were 0.26, 65.86, 179.62, and $525.12{\mu}g/dry$ matter (DM) g, respectively, and the relative equations relating Se enrichment in soybean sprouts (Y) against watering days (X) were Y=32.505X-36.17 (T1), Y=88.46X-92.04 (T2), and Y=251.11X-254.9(T3). The averaged total levels of Se-enrichment in the whole mungbean sprouts at T1, T2, and T3 group were 0.05, 3.64, and $101.43{\mu}g/DM$ g, respectively, and the relative equations relating Se enrichment (Y) to watering days (X) for mungbean sprouts were Y=1.67X-1.3467 at T1 and Y=48.035X-46.907 at T2. The results of this study suggest that soybean sprouts and mungbean sprouts enriched with bioavailable Se can be produced on a large scale by Se supplementation, allowing for the development of healthy functional foods such as Se-enriched mungbean sprout soups and salads, Se-enriched functional drink and food additives, and selenium tablets to promote health.

Optical Properties of Photoferroelectic Semiconductors IV.(Optical Properties of SbSI:V, SbSeI:V, BiSI:V, BiSeI:V, SbSI:Cr, SbSeI:Cr, BiSI:Cr, BiSeI:Cr, SbSI:Ni, SbSeI:Ni, BiSI:Ni and BiSeI:Ni Single Crystals) (Photoferroelectric 반도체의 광학적 특성 연구 IV. (SbSI:V, SbSeI:V, BiSI:V, BiSeI:V, SbSI:Cr, SbSeI:Cr, BiSI:Cr, BiSeI:Cr, SbSI:Ni, SbSeI:Ni, BiSI:Ni 및 BiSeI:Ni 단결정의 광학적 특성에 관한 연구))

  • Oh, Seok-Kyun;Hyun, Seung-Cheol;Yun, Sang-Hyun;Kim, Wha-Tek;Kim, Hyung-Gon;Choe, Sung-Hyu;Yoon, Chang-Sun;Kwun, Sook-Il
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.236-245
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    • 1993
  • Single crystals, SbSI : V, SbSeI : V, BiSI : V, BiSeI : V, SbSI : Cr, SbSeI : Cr, BiSI : Cr, BiSeI : Cr, SbSI : Ni, SbSeI : Ni, BiSI : Ni, and BiSeI : Ni were grown by the vertical Bridgman method. It is found that the grown single crystals have an orthorhombic structure and the indirect optical transitions. The temperature dependence of energy gap shows the two reflection point related with the phase transitions and is well fitted with Varshni equation in the continuous region. The optical absorption peaks due to the doped impurities (V, Cr and Ni) are respectively attributed to the electron transitions between the split energy levels of $V^{+2}$, $Cr^{+2}$ and $Ni^{+2}$ ions sited at $T_d$ symmetry of the host lattice.

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Study on dielectric function of natural ZnSe oxide by spectroscopic ellipsomety (분광타원법을 이용한 ZnSe 자연 산화막의 유전율 함수에 관한 연구)

  • 김태중;성가영;최재규;김영동
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.252-256
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    • 2001
  • We performed spectroscopic ellipsometry measurement to obtain dielectric function(DF) of ZnSe at room temperature. Proper wet chemical etching procedure was carried out to remove overlayers on top of ZnSe, and our result indicates that the previous reports on the pure DF of ZnSe have inaccurate interpretations. We constructed DF of oxide on ZnSe by using reported DFs of amorphous-Se, $GaAsO_3$, and voids through Bruggeman effective-medium approximation.

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Luminescent Characteristics of CdSe Quantum Dot Phosphor Depending on Se Precursor Ratio (Se 전구체 함량 따른 CdSe 양자점 형광체의 발광특성)

  • Eom, Nu Si A;Kim, Taek-Soo;Choa, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.442-445
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    • 2012
  • The quantum dots (QD) have unique electrical and optical properties due to quantum dot confinement effect. The optical properties of QDs are decided by various synthesis conditions. In a prior QDs study, a study on the QDs size with synthesis condition such as synthesis time and temperature is being extensively researched. However, the research on QDs size with composition ratio has hitherto received scant attention. In order to evaluate the ratio dependence of CdSe crystal, synthesis ratio of Se precursor is changed from 16.7 mol%Se to 44 mol%Se. As the increasing Se ratio, the band gap was increased. This is caused by red shift of emission. We confirmed optical property of CdSe QDs with composition ratio.