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Freezing and Melting Phenomena of Urea-water Solution for Diesel Vehicle SCR System (디젤차량 SCR 시스템용 요소수용액의 동결과 해동 현상)

  • Choi, B.C.;Seo, C.K.;Myong, K.J.
    • Journal of Power System Engineering
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    • v.13 no.4
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    • pp.5-10
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    • 2009
  • Urea-SCR system, the selective catalytic reduction using urea as reducing agent, is a powerful technique to reduce nitrogen oxides(NOx) emitted from diesel engines. However, a tank of urea(32.5 wt%)-water solution can be frozen in low ambient temperature levels of below $-11^{\circ}C$. The purpose of this study is to understand freezing and melting phenomena of the urea-water solution, and its can be applied to get the urea-water solution from frozen it within 5 minutes after cold start. Factors considered were the type of heater and the urea tank shape. From the results, it was found that melting volume of cartridge heater B during 5 minutes of heating period was 83ml when supplying electric power of 150W. Horizontal heater B, which was put in the narrow bottom space of the tank T1, had fast melting characteristics.

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Development of Dimmable Magnetic Ballast for HID-Lamps by Zero Current Switching on SCRs (SCR의 영전류 스위칭에 의한 HID 램프용 조도제어형 자기식 안정기 개발)

  • Lee, Hyeon-Jin;Yoo, Jae-Woong;Park, Chong-Yeon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.12
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    • pp.9-16
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    • 2010
  • In this paper, we have proposed a new dimmable magnetic ballast for HID(High Intensity Discharge) lamps consisted of AC switches to variate inductance value by using Silicon Controlled Rectifiers and the isolated zero current detector on inductor. Conventional dimming ballast has used relays or Solid State Relays in AC switches. However, a relay is difficult to zero current switching, because it has long operating time(10[ms]), and price competitiveness of SSR is very low. The proposed AC switches are suitable to switch at zero inductor current and it is accurately detected by using a opto-coupler. SCR is cheaper than SSR, and it is suitable to switch at zero inductor current because SCR is automatically turned off under holding current at no gate signal. Operating principles, simulation results and experimental results of the proposed ballast are described.

Frozen and Melting Characteristics of Urea-aqueous Solution for Urea-SCR System by Circulation of Engine Coolant (엔진 냉각수 순환에 의한 urea-SCR 시스템용 요소수의 동결 및 해동 특성)

  • Choi, B.C.;Kim, Y.K.;Kim, H.N.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.42-47
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    • 2011
  • The purpose of this study is to investigate the best melting condition with various winding number of a heating pipe, supplying quantity of engine coolant and coolant temperature at the inlet of the heating pipe. Also, it is to suggest getting method of an appropriate quantity of the agent for the urea-SCR system within 10 minutes. For this matter, this study identifies the temperature distribution of inside of urea-tank while it is frozen at the low temperature condition, and suggests the best melting condition of the frozen urea within 10 minutes. From the results, it was found that 2L of melted urea was obtained by the coolant flow rate of 200L/hr at $70^{\circ}C$ for 10 minutes from the start of engine operating.

Characterization analysis of SCR catalyst contained recycling Aluminium dross (재활용 된 알루미나를 포함한 SCR 탈질 촉매의 특성 분석)

  • Bae, Min-A;Kim, Hong-Dae;Kim, Kwang-Ho;Lee, Man-Sig
    • Proceedings of the KAIS Fall Conference
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    • 2011.12b
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    • pp.496-498
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    • 2011
  • 본 논문에서는 알루미늄 드로스를 재활용하여 생성 된 수산화알루미늄을 이용하여 질소산화물 제거 SCR 촉매를 제조하였다. 현재 상용중인 촉매와 화학적 특성과 질소산화물 제거 효율을 비교하기 위해 동일 타입의 하니컴 형태의 $V_2O_5-WO_3-TiO_2-Al_2O_3$ SCR 촉매를 제조하였으며, XRF와 BET를 사용하여 화학적 특성을 평가 비교하였다. 또한 MR(Micro Reactor)을 이용하여 $350^{\circ}C$$450^{\circ}C$에서 질소산화물 제거 평가를 실시하였으며, 평가 결과 80~90%의 제거 효율을 확인하였다.

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특집:녹색선박 SCR시스템 기술개발 현황 - 가변 유량 Urea 분사 모듈개발

  • Jeong, Gyeong-Yeol;Park, Chang-Dae;Im, Byeong-Ju;Lee, Chung-Won;Heung, Jeong-Gu;Gu, Geon-U
    • 기계와재료
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    • v.24 no.2
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    • pp.48-61
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    • 2012
  • NOx 저감방법으로 여러 가지 방법들이 존재하며 연구되고 있다. 그중 Urea-SCR은 적용가능한 온도범위가 넓고 우수한 저감효율을 보여 자동차엔진의 NOx 저감장치로 많은 연구가 진행되어 왔다. Urea-SCR은 고체 Urea의 열 해리반응으로 생성되는 암모니아가스와 NOx 와의 화학반응으로 제거하는 것이 목적이다. NOx저감효율에 직접적인 영향을 주는 변수에는 분사노즐의 분무특성, 배기관내 분사위치, 요소수의 유량제어 등 여러 가지가 존재한다. 따라서 본문에서는 여러 가지 분사노즐, 유량제어방법, 배기가스 물성치 및 관내 유동특성 등에 대해 소개하고 Urea-SCR시스템 적용가능성을 언급하고자 한다.

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특집:녹색선박 SCR시스템 기술개발 현황 - 선박용 SCR 국내.외 현황 및 시장동향

  • Jeong, Gyeong-Yeol;Park, Chang-Dae;Im, Byeong-Ju;Bae, Jong-Uk
    • 기계와재료
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    • v.24 no.2
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    • pp.18-26
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    • 2012
  • 지구 환경오염문제가 대두되면서 세계 각국에서는 환경오염을 최소화하려는 움직임이 활발히 이루어지고 있다. 국제해사기구(IMO)에서는 해양 대기오염의 상당량이 선박에서 배출되는 배기가스에 의한 것으로 판단하고 있으며, 이에 따라 선진국을 중심으로 선박관련 환경규제 및 선박 배기가스 배출기준을 점차적으로 강화해 가고 있고, 친환경 선박 및 기자재 개발을 적극적으로 진행하고 있다. 현재 선박에 적용 가능한 NOx 제거장치로는 ECR(Exhaust Gas Recirculation), SCR(Selective, Catalytic Reduction), SAM(Scavenge Air Moistening) 등이 개발되었으며, 연소온도 조절 및 촉매 환원반응 등을 이용하여 NOx를 제거하고 있다. 현재 개발된 탈질설비 중 현실적으로 가장 적합한 것은 SCR시스템으로 인식되고 있으나, 연료효율 감소로 인하여 가스연료를 이용하거나 새로운 연료개발 등 사용연료에 변화를 주는 방법들이 미래의 대안으로 제시되고 있다.

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NUMERICAL STUDY ON THE MIXER TYPE OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템의 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.;Kim, W.S.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.368-375
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the NH3-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed device. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of NH3 by numerical simulation.

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NUMERICAL STUDY ON THE MIXER TYPES OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템에서 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.
    • Journal of computational fluids engineering
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    • v.15 no.4
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    • pp.9-16
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the $NH_3$-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore, it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed devices. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of $NH_3$ by numerical simulation.

A development of reactor design software for De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 De-NOx 시스템의 반응로 설계 전산프로그램 개발)

  • 정경열;오상훈;동은석;이수태;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.187-191
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    • 2002
  • The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

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Commercialization of SCR System for Removal of NOx from Marine Diesel Exhaust Gas (선박 디젤엔진용 NOx 배출저감을 위한 SCR 시스템 상용화)

  • Yang, Hee-Sung;Seong, Hee-Je;Ko, Joon-Ho;Lee, Sung-Young;Park, Kee-Yong;Park, Jong-Kuk;Song, Seok-Yong
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.23-24
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    • 2006
  • The International Maritime Organization announced that the regulation of nitrogen oxide put into force for vessels constructed after 2000 from May, 2005 as agenda is satisfied on May, 2004. A honeycomb-typed Pillared Inter-Layered Clay(PILC) catalyst was developed for do-NOx SCR system in 2004. This catalyst has been applied to 9H25/33 engine that is one of the main diesel engines in Engine Machinery Division of the Hyundai Heavy Industries CO., LTD. In addition, we have tried to develop better catalysts in the aspects of easy synthetic method and performance.

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