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STATIC CHARACTERISTICS OF A UREA-SCR SYSTEM FOR NOx REDUCTION IN DIESEL ENGINES

  • Nam, J.G.
    • International Journal of Automotive Technology
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    • v.8 no.3
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    • pp.283-288
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    • 2007
  • This paper presents the static characteristics of a urea-SCR system. The static characterization of the urea-SCR system was generated by sweeping urea flow rates at common engine torque/speed operating points. Several experiments were performed using engine operating points at different raw NOx emission levels, space velocities, and SCR catalyst temperatures. The recorded NOx emissions from the engine exhaust outlet and engine tailpipe are then compared. The urea-SCR static system results indicated that a $50{\sim}60%$ NOx conversion is achievable at most engine operating points using the stoichiometric $NH_3/NOx$ ratio, and a high 98% NOx conversion is possible by exceeding the stoichiometric $NH_3/NOx$ ratio. The effect of the pre-oxidation catalyst volume was also investigated and found to have a profound impact on experimental results, particularly the static NOx conversion.

특집:녹색선박 SCR시스템 기술개발 현황 - 촉매반응기 내부 유동특성에 관한 수치해석

  • Jeong, Gyeong-Yeol;Park, Chang-Dae;Im, Byeong-Ju;Lee, Jung-Seop;Seo, Jeong-Se;Yun, Ji-Hun
    • 기계와재료
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    • v.24 no.2
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    • pp.80-93
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    • 2012
  • 본 연구는 5,000PS급 선박용 SCR 촉매시스템에 관한 내부 유동특성을 전산유체역학(CFD)을 통해 예측하고 설계에 반영하기 위한 기초를 확보하기 위함이다. 따라서 SCR 촉매반응기 내부 유동특성을 수치해석하기 위한 기법을 소개하였고, 촉매 Cell에 대한 수학적 모델링을 제시한 후 SCR 촉매시스템에서 NOx를 환원시켜 주는 촉매담체에 대한 압력강하를 실험과 수치해석을 통해 비교하였다. 그 결과 수치해석 결과가 실험에 매우 근접함을 확인할 수 있었다. SCR 촉매반응기에 대한 유동특성을 수치해석을 수행하여 각 지점에 대한 압력과 속도분포를 확인하였다. 또한 촉매 담체로 배기가스가 유입되는 입구부의 유동균일도를 예측하기 위해 Inlet pipe의 $90^{\circ}$ 각도에서 유입길이를 변화시켜 수치해석을 수행하였다. 그 결과 각도와 길이에 영향을 받는 것으로 나타났다.

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SNCR/SCR Combined 시스템을 이용한 DeNOx 연구

  • 최상기;남창모;박상원;최성우
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.26-27
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    • 2001
  • SNCR 기술을 이용한 NOx 저감은 반응온도 850~$1100^{\circ}C$에서 효과적이였으며, 몰비($NH_3$/NOx), $O_2$ 농도에 상당히 영향을 받고 있었다. 최적온도 $950^{\circ}C$, 몰비 1.5에서 약65%의 NOx 제거효율을 얻을 수 있으며, 온도구배가 없고 $O_2$ 농도가 2~4%로 낮아질 경우 더 높은 제거효율이 기대된다. SCR 기술에 의한 NOx 저감을 위해 $V_3$$O_{5}$/-$WO_3$/$TiO_2$ 상용촉매를 사용하였으며, 반응 온도는 200~$500^{\circ}C$ 범위로 확인되었으며, 약 84%의 NOx 제거효율이 몰비 1.5 에서 얻어졌다. $O_2$ 농도가 21%로 높아짐에 따라 상당히 효율이 떨어짐이 밝혀졌다. SNCR/SCR combined 시스템은 몰비=2.0, $T_{SNCR}$/=$850^{\circ}C$, $T_{SCR}$ /=$350^{\circ}C$ 반응조건에서는 약 93%의 NOx 저감효율을 보여주어 SNCR, SCR 단위기술보다 더 효과적이었다.

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DERIVED LIMITS AND GROUPS OF PURE EXTENSIONS

  • LEE, H.J.;KIM, S.J.;HAN, Y.H.;LEE, W.H.;LEE, D.W.
    • Honam Mathematical Journal
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    • v.21 no.1
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    • pp.157-169
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    • 1999
  • For a k-connected inverse system $({\scr{X}},\;*)=((X_{\lambda},\;*),p_{{\lambda}{{\lambda}}^{\prime}},\;{\Lambda})$ of pointed topological spaces and pointed preserving weak fibrations, inducting epimorphic chain maps, over a directed set, we show that the homotopy group ${\pi}_k(lim{\scr{X}},\;*)$ of the inverse limit is isomorphic to the integral homology group $$H_k(lim{\scr{X}};\mathbb{Z})$. Using the result of S. $Marde{\check{s}}i{\acute{c}}$, we prove that the group of pure extension $Pext(colimH^n({\scr{X}},\;A)$ is isomorphic to the group of extension $Ext({\Delta}({\lambda}),\;Hom(H^n({\scr{X}}),\;A))$.

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Control of SCR System for NOx Reduction in a Refuse Incineration Plant Using Repetitive Control Method (반복제어법을 이용한 소각장 NOx 저감용 SCR 시스템의 제어)

  • 김인규;여태경;김환성;김상봉
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.11
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    • pp.2762-2770
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    • 2000
  • The refuse incineration plant has an important role in saving the combustion energy for local heating system. But harmful combustion gas(NOx etc.) leads to some serious environmental problem. To reduce the gas, a SCR(Selective Catalytic Reduction)system is installed and it is controlled by adjusting the flow of ammonia gas(NH3) . In this paper, we apply a repetitive control method to reduce NOx by adjusting the flow of ammonia gas for SCR system in a refuse incineration plant which is located in Haeundae, Pusan, Firstly, we analyze the inlet NOx period by FFt method, and verify its periodic variations. Secondly, we design a repetitive control system by using state space model method. Lastly, the effectiveness of repetitive control system is shown by comparing to a conventional PID control in simulation and experimental results.

Optimization for Flow Uniformity on the Selective Catalytic Reduction (SCR) System of a Steam Supply Boiler (열병합 보일러 SCR 장치의 유동 균일화를 위한 최적화 연구)

  • Park, Young-Bin;Jang, Choon-Man
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.415-420
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    • 2009
  • Selective Catalytic Reduction(SCR) has been used for the reduction of $NO_x$ in a steam supply boiler. Recently, the reduction of $NO_x$ becomes an important research field because of its negative effect on an environment. Shape optimization of circular poles installed in the chamber, which is located in upstream of a SCR, has been performed using response surface method and three-dimensional Navier-Stokes analysis to enhance gas flow uniformity. Three design parameters, diameter, arranging angle and stretching ratio of circular poles, are considered in the present study. Throughout the shape optimization of a circular pole, gas flow uniformity is successfully increased by decreasing local recirculation flow in a square duct chamber. Recirculation flow observed in the corner of the square duct can be reduced by proper installation of a guide vane or a blunt body. Detailed flow characteristics are also analyzed and discussed.

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A Numerical Analysis on the Flow Characteristics inner Catalytic Reactor for Marine SCR System (선박용 SCR 시스템의 촉매반응기 내부 유동특성에 관한 수치해석)

  • Yi, C.S.;Suh, J.S.;Yun, J.H.;Lim, B.J.;Park, C.D.;Chung, K.Y.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2012.06a
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    • pp.125-126
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    • 2012
  • The key issues for the reduction technologies of the exhaust gas from diesel engine being developed are to reduce particulate matters and NOx. Performance of NOx removal in SCR process depends on such various factors as catalyst factors(catalyst composition, shape, velocity, etc.), exhaust gas temperature and velocity distribution. In this study checked flow uniformity with the flow characteristics in the SCR reactor by using STAR CCM+. The pressure drop of experiment and simulation had similar result more than 90% at catalytic Cell. Also, flow uniformity calculated about 0.9036 ant 1st catalytic ind SCR reactor.

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Switching Characteristics Analysis of Bypass SCR for Series Transformer in 3-phase Voltage Disturbance Generator (3상 전압변동발생기의 직렬변압기 바이패스용 SCR의 스위칭 특성해석)

  • Song, W.H.;Park, H.Y.;Nho, E.C.;Kim, I.D.;Kim, H.G.;Chun, T.W.
    • Proceedings of the KIPE Conference
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    • 2010.07a
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    • pp.71-72
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    • 2010
  • This paper deals with the SCR thyristor switching characteristics of a 3-phase voltage disturbance generator. The series transformers of the generator require bypass SCR thyristors to provide the source voltage to the output terminal in normal operating mode. The SCR thyristor switching characteristics is quite different according to the connection point to the series transformer. The switching characteristics is analysed and verified through simulation results.

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Switching Characteristics Analysis of Bypass SCR for Series Transformer in 3-phase Voltage Disturbance Generator (3상 전압변동발생기의 직렬변압기 바이패스용 SCR의 스위칭 특성해석)

  • Song, W.H.;Park, H.Y.;Nho, E.C.;Kim, I.D.;Kim, H.G.;Chun, T.W.
    • Proceedings of the KIPE Conference
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    • 2010.07a
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    • pp.532-533
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    • 2010
  • This paper deals with the SCR thyristor switching characteristics of a 3-phase voltage disturbance generator. The series transformers of the generator require bypass SCR thyristors to provide the source voltage to the output terminal in normal operating mode. The SCR thyristor switching characteristics is quite different according to the connection point to the series transformer. The switching characteristics is analysed and verified through simulation results.

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De-NOx Characteristics of V2O5 SCR according to the Ratio of TiO2 Crystal Structures

  • Seo, Choong-Kil;Bae, Jaeyoung
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.26-32
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    • 2015
  • The purpose of this study is to investigate the de-NOx performance characteristics according to the $TiO_2$ crystal structures ratio of $V_2O_5$ SCR catalysts. The anatase(100%) SCR catalyst showed the highest desorption peak of 80ppm at about $250^{\circ}C$, and $NH_3$ was not desorbed at $500^{\circ}C$. It can be confirmed that there was many $NH_3$ desorbed at a high temperature among other various crystal structures, which is because the catalyst was more acidized to increase the intensity of acid sites as the content of subacid sulfate ions($NH_2SO_4$) in the rutile phase increases. The anatase/rutile(7%/93%) SCR had the smallest width of de-NOx performance drop according to thermal aging, and had strong durability against thermal aging.