• Analytical Science and Technology
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• v.24 no.5
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• pp.395-400
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• 2011

This study has been carried out in order to effectively manage three groups of unregulated hazardous organic substances (PCDD/DFs, PAHs, PCBs) in South Korea. The investigated substances have been analyzed according to the test methods for hazardous substances in specified wastes provided by the National Institute of Environmental Research, Korea. Total contents of the organic compounds have been determined for hazardous wastes from three major industrial categories (paint, iron removal, steelmaking), such as waste organic solvent, waste paint or dust. By investigating the waste samples for 7 PAHs using GC/MSD, Naphthalene has been detected (N.D~1631.33 mg/kg). The highest Naphthalene concentration, which exceeded the korean marine dumping waste standard, was found in waste organic solvents and waste paints. Although a content analysis of 7 PCB isomers has been conducted, none of these compounds was detected. The analysis of PCDD/DFs has revealed that all samples meet the criterion for low POP content defined in the technical guidelines developed under the Basel Convention. The PCDD/DFs content in dust samples deriving from 10 manufacturing processes (billet, bloom) was determined to be in the range of N.D~5.66 ng I-TEQ/g waste.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.345-350
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• 2017

The sintered density of uranium oxide pellets for pressurized water reactors is generally analyzed with pellet's samples completed with the sintering process. In this paper, the sintered density was analyzed by the newly developed method measuring the chromatography of ammonium diuranate, a precursor of uranium oxide, by a spectrophotometer (CM-5, Konica Minolta) before completing the sintering process. As a result of the sintered density analysis based on the brightness, color coordinate values (L, a, b) obtained from five ammonium diuranate samples by a spectrophotometer and the trend line of sintered density analyzed by a previous method, the sintered density with respect to the L value was observed with 0.9967 of the decision factor $R^2$. In case of a value, $R^2$ value was 0.9534 indicating lower reliability than that of the L value. However, b value with $R^2$ value of 0.4349 showed a very low correlation.

• Applied Chemistry for Engineering
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• v.29 no.1
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• pp.22-27
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• 2018

In this study, the effect of physical properties of $Pt/TiO_2$ on $NH_3$-selective catalytic oxidation (SCO) reaction at $200{\sim}350^{\circ}C$ was investigated. CO-chemisoption and BET analysis were carried out to verify physical properties of $Pt/TiO_2$. By characterizing physical properties of $Pt/TiO_2$ with respect to the Pt loading, the metal dispersion degree decreased as a function of the Pt loading amount. Also, the catalyst having a higher metal dispersion showed an excellent conversion efficiency of $NH_3$ to $N_2$. Since the specific surface area of the support affects the metal dispersion, $Pt/TiO_2$ catalysts were prepared using $TiO_2$ with different physical properties. As a result, it was confirmed that the catalyst having a wide specific surface area exhibited a excellent conversion of $NH_3$ to $N_2$.

• Journal of Energy Engineering
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• v.25 no.3
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• pp.104-113
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• 2016

This study analyzes correlation between methane gas production and injection of food waste water to motivate to expand renewable energy as a way of GHG (Green House Gas) mitigation to achieve the national GHG target proposed for the climate agreement in Paris last year. Pretreatment of food waste water was processed with pH 6 at $35^{\circ}C$ and used the fixed-bed upflow type reactor with the porous media. As a result of operation of pilot-scaled bioreactor with food waste water, the methane gas production was 6 times higher than the methane gas production of control group with rain water. The average production of methane was $56{\ell}/day/m^3$ which is possible to produce $20m^3$ of methane in $1m^3$ of landfill. As a way of energy source, when it is applied to the landfill over $250,000m^3$, it is also able to achieve financial feasibility along with GHG reduction effect. GHG reductions of $250,000m^3$ scale landfill were assessed by registered CDM project and the annual amount of reductions was 40,000~50,000 $tCO_2e$.

• Proceedings of the KSRS Conference
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• 2008.03a
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• pp.113-118
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• 2008

본 연구는 Landsat 7 ETM+를 이용한 지열자원 평가 가능성 연구로써, 위성영상의 열적외 밴드에서 추출된 지표온도와 지열자료의 비교를 통해 위성영상이 초기 지열 탐사에 적용 가능한지를 평가하기 위하여 실시하였다. 지열자원 부존 가능성 평가를 위해 경상도지역(114-35)의 여름시기영상(2001년8월24일)과 겨울시기영상(2000년3월14일)사이의 DN(Digital Number) 값을 이용하였으며, 두 시기영상은 시추공 온도자료 및 지형자료와 함께 비교 분석을 실시하였다. 영상에서 지표온도 추출을 위해 1) NASA에서 제공하는 지표온도 산출 경험식 ( T = K $_2$ / ln ( K $_1$ / L $_{\lambda}$ + 1 ) )을 이용한 방법과 2) 기상청에서 제공하는 실제 지표면온도 관측자료(n=7)를 이용해 영상의 화소(Pixel) 값을 계산하여 실측값과 비교하였다. 3월과 8월 모두 Ground Truth 방법에 따라 추정한 지표면 온도값이 실측값과 더 가깝게 나타났고, 특히 3월은 NASA의 경험식을 이용했을 때 보다 실측 지표면 온도에 훨씬 더 가까운 것으로 나타났다. 지표온도의 일변화(Diurnal ${\triangle}$T)는 지표 열물성과 밀접한 관련이 있으므로, 일변화(Diurnal ${\triangle}$T) 보다는 지열의 영향이 더 클 것으로 기대되는 계절변화(Seasonal ${\triangle}$T)를 이용하여 지열 자료와 비교해 보았다. 그 결과, 계절변화(Seasonal ${\triangle}$T)는 고도에 영향을 받으며, 일사량에 의한 차이는 거의 일정하게 나타났다. 위성영상에서 계절변화(Seasonal ${\triangle}$T)와 심도 20m 온도를 비교해 본 결과결정계수(R$^2$)는 0.46으로 낮지만 심도 20m 온도가 높을수록 계절변화(Seasonal ${\triangle}$T)는 작아지는 경향을 보여 지열자원 탐사에 있어 위성영상 적용 가능성을 볼 수 있었다. 이번 연구는 기초단계로서 두 시기 위성영상을 이용하여 초기 지열자원탐사에 가능성만을 연구했지만, 지형과 특히 토지피복(함수량 등)에 의한 영향에 대해 좀 더 심도 있는 연구가 요구된다.

• Applied Biological Chemistry
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• v.40 no.3
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• pp.189-195
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• 1997

The structural basis of Iysine specificity of Achromobacter protease I (API) was investigated by means of site-directed mutagenesis. The precursor protein in which Glu190, one of the two candidates for determining Iysine specificity, was substituted by glutamine, aspartic acid or leucine was processed autocatalytically to attaln full pretense activity with lysine specificity. The substitution of the other candidate, Asp225, for asparagine or leucine produced no mature active forms of pro-API. The precursor protein of the mutant D225E slowly matured autocatalytically. The lysylendopeptidase activity of the mature D225E was 0.25% of that of native API, and this reduced activity is mainly due to a decrease in the affinity of the enzyme for lysine. These results suggest that Asp225 plays a critical rol in restricted substrate specificity as a lysylendopeptidase. However, D225E exhibited no measurable activity for synthetic ornithine substrate. Since the hydroxyl group of Ser194 in this mutant retained essentially the same reactivity to DFP or PMSF as that in native API, it can be noted that a methylene unit longer side chain of residue 225 is not compensated by a methylene unit shorter side chain at subsite P1 in the bound substrate.

• Analytical Science and Technology
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• v.16 no.5
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• pp.358-367
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• 2003

In this research, first of all, the analytical methods for the determination of major elements in sediment have been developed with ICP-MS (Inductively Coupled Plasma Mass Spectrometry). The analytical results of major elements (Al, Ca, K, Fe, Mg) with Cool ICP-MS were much better than those with normal ICP-MS. The analytical results were compared with those of NAA (Neutron Activation Analysis). NAA were a little superior to ICP-MS for the determination of major elements in sediment as a non-destructive trace analytical method. The analytical methods for the determination of minor elements (Cr, Ce, U, Co, Pb, As, Se) have been also developed with ICP-MS. The analytical results by standard calibration curve with ICP-MS were not accurate due to the matrix interferences. Thus, the internal standard method was applied, then the analytical results for minor elements with ICP-MS were greatly improved. The analytical results obtained by ICP-MS were compared with those obtained by NAA. It showed that the two analytical methods have great capabilities for the determination of minor elements in sediments. Accordingly, the NAA will play an important role in analysis of environment sample with complex matrix. ICP-MS also will play an important role because it has a great capability for the determination of Pb that could not be determined by NAA.

• Journal of Sensor Science and Technology
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• v.9 no.1
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• pp.28-35
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• 2000

In this study, we investigated the characteristics of polyurethane synthesis by simultaneously measuring resonant frequency and resonant resistance with a quartz crystal analyzer. The rapid decrease of resonant frequency was appeared because automatic catalytic reaction was caused by the polyurethane formed in initial stage of polyurethane synthesis. In prepolymer(PP) synthesis, the resonant frequency was slowly stabilized after a rapid decrease at a certain point of time. But in segmented polyurethane synthesis in which chain-extender was involved, the resonant frequency increased again after a rapid decrease at a certain point of time. It was considered that this tendency took place because the chain-extender, 1,4-butandiol, caused a soft segment to change to a hard segment. The resonant resistance was used in the analysis of mechanism. From the results, the characteristics of polyurethane synthesis could be analyzed on-line using a quartz crystal analyzer, and the synthesis mechanism could also be interpreted.

• Analytical Science and Technology
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• v.23 no.2
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• pp.147-154
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• 2010

Oseltamivir carboxylate (OC) and Oseltamivir ethylester (OE) were analyzed to evaluate the environmental distribution in pandemic season in Korea. The detected concentration of OE was the range of $0.008\sim0.087\;{\mu}g/L$, and OC was the range of $0.029\sim0.287\;{\mu}g/L$. The detected concentration of OC in this study was two times higher than reported concentration of OC in river water in Japan. But, these analytical results cannot be directly compared to the previous reported concentration, because of the different sampling period.

• Journal of Ginseng Culture
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• v.1
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• pp.1-10
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• 2019

The purpose of this study is to investigate the changes of ginseng properties through bibliographical records. The cultivation of Korean wild simulated ginseng (mountain cultivated ginseng) started from the Goryeo Dynasty around A.D. 1000. Thereafter, from A.D. 1500 to A.D. 1600, ginseng cultivation technology was established in the Joseon Dynasty. At this time, the ginseng was begun to grow in the field near the house, and it is recorded as Gasam (field cultivated ginseng). The Jung-Jo-Sil-Rok (A.D. 1790) states that Gasam cultivation has expanded to the whole country. The properties of ginseng described in almost all oriental medicine books from A.D. 250 to A.D. 1600 were a slightly cold. However, after A.D. 1600, it is said to be slightly warm or warm. Considering from this record, the slightly cold ginseng before A.D. 1600 can be recognized as the properties of wild ginseng or wild simulated ginseng, and the slightly warm ginseng after A.D. 1600 can be recognized as Gasam properties.