• Corrosion Science and Technology
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• 제8권1호
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• pp.1-10
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• 2009

The influence of Schiff bases on the corrosion inhibition of mild steel in 1 M $H_2SO_4$ have been investigated by weight loss, gasometry, impedance and polarization techniques. The results obtained reveal that these compounds act as good inhibitors. The inhibition efficiency of Schiff bases increased with concentration and synergistically increased on addition of chromate, sulphate and halide ions. Potentiodynamic polarization measurements clearly reveal that the investigated inhibitors are of mixed type but they are more cathodic in nature. The adsorption of these compounds on mild steel surface for both the acids were found to obey Langmuir adsorption isotherm. The surface morphology was studied by SEM and UV reflectance spectra.

• 대한화학회지
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• 제59권6호
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• pp.483-487
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• 2015

The different calculated quantum chemical descriptors by DFT method were used for prediction of some sulphanilamide Schiff bases inhibitor activity as a binding constant (log K). Multiple linear regression (MLR) and artificial neural network (ANN) were employed for developing the useful quantitative structure activity relationship (QSAR) model. The obtained results presented superiority of ANN model over the MLR one. The offering QSAR model is very easy to computation and Physico-Chemically interpretable. Sensitivity analysis was used to determine the relative importance of each descriptor in ANN model. The order of importance of each descriptor according to this analysis is: molecular volume, molecular weight and dipole moment, respectively. These descriptors appear good information related to different structure of sulphanilamide Schiff bases can participate in their inhibitor activity.

• 대한화학회지
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• 제56권1호
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• pp.54-57
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• 2012

New Schiff base derivatives of organoheterobimetallic-${\mu}$-oxoisopropoxide $[Bu_2SnO_2Ti_2(OPr^i)_6]$ have been synthesized by the thermal condensation ${\mu}$-oxoisopropoxide compound with Schiff bases in different molar ratios (1:1-1:4) yielded the compounds of the type $[Bu_2SnO_2Ti_2(OPr^i)_{6-n}(SB)_n]$ (where n is 1-4 and SB=Schiff base anion) respectively. The ${\mu}$-oxoisopropoxide derivatives have been characterized by elemental, spectral analysis (IR, $^1H$, $^{13}C$, $^{119}Sn$ NMR) and molecular weight measurement The studies reveal that the derivative compounds show monomeric nature. Further these are found less susceptible to hydrolysis as compared to parent compound and may prove excellent precursors for the mixed metal oxides.

• Mycobiology
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• 제37권2호
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• pp.141-146
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• 2009

Novel copper(II) complexes have been synthesized from the macrocyclic Schiff bases derived from Knoevenagel condensed ${\beta}$-ketoanilides (obtained by the condensation of acetoacetanilide and substituted benzaldehydes), 4-aminoantipyrine and ophenylene diamine. The structural features have been determined from their analytical and spectral data. All the Cu(II) complexes exhibit square planar geometry. Their high molar conductance values support their 1 : 2 electrolytic nature. The magnetic moment data provide evidence for the monomeric nature of the complexes. The X-band ESR spectra of the |$CuL^1$|$(OAc)_2$ in DMSO solution at 300 and 77 K were recorded and their salient features are reported. The in vitro biological screening effects of the investigated compounds were tested against the bacterial species Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae, Proteus vulgaris and Pseudomonas aeruginosa and fungal species Aspergillus niger, Rhizopus stolonifer, Aspergillus flavus, Rhizoctonia bataicola and Candida albicans by well diffusion method. A comparative study of inhibition values of the Schiff bases and their complexes indicate that complexes exhibit higher antimicrobial activity than the Schiff bases. Copper ions proved to be essential for the growth-inhibitor effect. The extent of inhibition appeared to be strongly dependent on the initial cell density and on the growth medium.

• 대한화학회지
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• 제47권3호
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• pp.199-205
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• 2003

우라닐 이온, $UO^+_2$와 Schiff-base 와의 착화합물이 글리실글라이신과 살리실알데히드, 2-히드록시-1-나프트알데히드, 2,3-디히드록시 벤즈알데히드 그리고 2,4-디히드록시 벤즈알데히드와의 축합에 의해 합성되었으며 이들 착화합물의 특성을 원소분석, 전도도 측정, 자기화율 측정, UV, IR, NMR 스펙트라와 DTA, TG, DSC 결과를 이용하여 조사하였다. 구조와 열분해 메카니즘이 제안되었다.

• Bulletin of the Korean Chemical Society
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• 제16권4호
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• pp.326-331
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• 1995

Poly(enaryloxynitriles) containing Schiff bases were prepared from p-bis(1-chloro-2,2-dicyanovinyl)benzene (2) and various aromatic diols having Schiff base moiety by interfacial polymerization. The chemical structure of the polymers was confirmed through synthesis of their corresponding model compounds. All the polymers were soluble in polar aprotic solvents and their brittle films were cast from DMF solution. They showed a large exotherm around 340 ℃ attributable to the chemical change of dicyanovinyl group. Especially, curing of azomethine group was observed to occur at 390 ℃ by differential scanning calorimetry. According to the thermogravimetric analyses, they exhibited excellent thermal stability with 60-90% residual weight at 500 ℃ in nitrogen.

• Bulletin of the Korean Chemical Society
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• 제26권4호
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• pp.548-552
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• 2005

The interaction between ionic surfactants and different nonionic molecules and polymers are studied using ion surfactant selective electrode. From the experimental data, critical concentrations of the interaction and binding process are evaluated. The interaction between hexadecyltrimethylammonium bromide (HTAB) with polyethylene glycol (PEG) in three molecular weights (1000, 10000 and 100000) and also schiff-bases, 2-[2-carboxyphenyl nitrilomethylidyne]-phenol (ortho CNP), 2-[3-carboxyphenyl nitrilomethylidyne]-phenol (meta CNP)and 2-[4-carboxyphenyl nitrilomethylidyne]-phenol (para CNP) with the potentiometric method were investigated using HTAB membrane selective electrode. In the case of PEG with increasing molecular weights more interaction to HTAB occurs. The electromotive force (EMF) data also showed that interaction between para CNP with HTAB is more than the other schiff-bases. It seems this case related to less space interference of COOH group for that compound. The onset of binding ($T_1$) of course is the same for three schiffbase molecules.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.850-858
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• 2010

The electronic absorption spectra of five Schiff bases derived from 2-hydroxy-1-naphthaldehyde with glycine, alanine, leucine, valine and phenylalanine have been measured in various solvents. The observed bands were assigned to the proper electronic transitions and compared with the predicted transitions at the semiempirical level of theory. The calculated equilibrium constants are in agreement with the experimental results, predicting the existence of all studied compounds predominantly or completely in keto-imine tautomerism. On the other hand, a correlation between $\nu\;(cm^{-1})$ (main frequency of each compound) and the well known solvent parameters $E_T$ (30), $\varepsilon_T$, $\pi^*$ been made. Furthermore, the acid dissociation constants, $pK_a$, were determined by using three different spectrophotometric methods.

• 분석과학
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• 제36권5호
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• pp.236-249
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• 2023

Carbon dioxide (CO₂) capture and storage is a critical issue for mitigating climate change. Porous aromatic Schiff base complexes have emerged as a promising class of materials for CO₂ capture due to their high surface area, porosity, and stability. In this study, we investigate the potential of Schiff base complexes as an effective media for CO₂ storage. We review the synthesis and characterization of porous aromatic Schiff bases materials complexes and examine their CO₂ sorption properties. We find that Schiff base complexes exhibit high CO₂ adsorption capacity and selectivity, making them a promising candidate for use in carbon capture applications. Moreover, we investigate the effect of various parameters such as temperature, and pressure on the CO₂ adsorption properties of Schiff base complexes. The Schiff bases possessed tiny Brunauer-Emmett-Teller surface areas (4.7-19.4 m²/g), typical pore diameters of 12.8-29.43 nm, and pore volumes ranging from 0.02-0.073 cm³/g. Overall, our results suggest that synthesized complexes have great potential as an effective media for CO₂ storage, which could significantly reduce greenhouse gas emissions and contribute to mitigating climate change. The study provides valuable insights into the design of novel materials for CO₂ capture and storage, which is a critical area of research for achieving a sustainable future.

• 대한화학회지
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• 제52권4호
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• pp.439-444
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• 2008