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Improvement of Wettability and Removal of Skin Layer on Ar-Plasma-Treated Polypropylene Blend Surface (폴리프로필렌 복합소재의 아르곤 플라즈마 처리로 표면층 제거와 젖음성 향상)

  • Weon, Jong-Il;Lee, Sun-Yong
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.461-469
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    • 2012
  • The surface modification and characterization of Ar-plasma treated polypropylene (PP) blend are investigated using x-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and contact angle measurement. An increase in Ar-plasma treatment time leads to an increase in wettability, oxygen containing polar functional groups, the amount of talc, and surface roughness on the PP blend surface. A careful observation using SEM indicates that there exists a skin layer consisting of only PP component. The difference in viscosity between PP and rubber particles facilities the formation of skin layer. However, it is found that an increase in Ar-plasma treatment time helps to decrease the thickness of skin layer. Additional methodologies for the elimination of skin layer during injection molding are also discussed. The surface modification and morphological alteration induced by Ar-plasma treatment provides a hydrophilic state, followed by the improvement in wettability, on the PP blend surface.

Effect of Conductive Additives in La0.8Sr0.2MnO3 Perovskite Electrodes for Oxygen Reduction and Evolution in Alkaline Solution (알칼리용액에서 La0.8Sr0.2MnO3 페롭스카이트 촉매의 산소환원 및 발생반응에서 도전재의 영향)

  • SHIM, JOONGPYO;LOPEZ, KAREEN J.;YANG, JIN-HYUN;SUN, HO-JUNG;PARK, GYUNGSE;EOM, SEUNGWOOK;LEE, HONG-KI
    • Journal of Hydrogen and New Energy
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    • v.27 no.3
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    • pp.276-282
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    • 2016
  • The effects of conductive additives in a $La_{0.8}Sr_{0.2}MnO_3$ perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM). The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.

On-orbit test simulation for field angle dependent response measurement of the Amon-Ra energy channel instrument

  • Seong, Sehyun;Kim, Sug-Whan;Ryu, Dongok;Hong, Jinsuk;Lockwood, Mike
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.211.1-211.1
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    • 2012
  • The on-orbit test simulation for predicting the instrument directional responsivity was conducted by the Monte Carlo based integrated ray tracing (IRT) computation technique and analytic flux-to-signal conversion algorithms. For the on-orbit test simulation, the Sun model consists of the Lambertian scattering sphere and emitting spheroid rays, the Amon-Ra instrument is a two-channel including a broadband scanning radiometer (energy channel) and an imager with ${\pm}2^{\circ}$ FOV (visible channel). The solar radiation produced by the Sun model is directed to the instrument viewing port and traced through the dual channel optical train. The instrument model is rotated on its rotation axis and this gives a slow scan of the Sun model over the full field of view. The direction of the incident lights are fed with scanned images obtained from the visible channel instrument. The instrument responsivity was computed by the ratio of the incident radiation input to the instrument output. In the radiometric simulation, especially, measured BRDF of the 3D CPC was used for scattering effects on radiometry. With diamond turned 3D CPC inner surface, the anisotropic surface scattering model from the measured data was applied to ray tracing computation. The technical details of the on-orbit test simulation are presented together with field-of-view calibration plan.

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Spatial Analysis by Matching Methods using Elevation data of Aerophoto and LIDAR (항공사진과 LIDAR 표고 데이터의 매칭 기법에 의한 공간정보 분석 연구)

  • Yeon, sang-ho;Lee, Young-wook
    • Proceedings of the Korea Contents Association Conference
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    • 2008.05a
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    • pp.449-452
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    • 2008
  • The building heights of big cities which charged with most space are 3-D information as relative vertical distance from ground control points, but they didn't know the heights using contour with maps as lose of skyline or building heights for downtown, practically continuously developed of many technology methods for implementation of 3-D spatial earth. So, For the view as stereos of variety earth form generated 3-D spatial and made terrain perspective map, 3-D simulated of regional and urban space as aviation images. In this papers, it composited geospatial informations and images by DEM generation, and developed and presented for techniques overlay of CAD data and photos captured at our surroundings uses. Particularly, The airborne LiDAR surveying which are very interesting trend have laser scanning sensor and determine the ground heights through detecting angle and range to the grounds, and then designated 3-D spatial composite and simulation from urban areas. Therefore in this papers are suggested ease selections on the users situation by compare as various simulations that its generation of 3-D spatial image by collective for downtown space and urban sub, and the implementation methods for more accurate, more select for the best images.

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Effect of ALD-Al2O3 Passivation Layer on the Corrosion Properties of CrAlSiN Coatings (ALD-Al2O3 보호층이 적용된 CrAlSiN 코팅막의 내부식성 특성에 관한 연구)

  • Wan, Zhixin;Lee, Woo-Jae;Jang, Kyung Su;Choi, Hyun-Jin;Kwon, Se Hun
    • Journal of Surface Science and Engineering
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    • v.50 no.5
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    • pp.339-344
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    • 2017
  • Highly corrosion resistance performance of CrAlSiN coatings were obtained by applying ultrathin $Al_2O_3$ thin films using atomic layer deposition (ALD) method. CrAlSiN coatings were prepared on Cr adhesion layer/SUS304 substrates by a hybrid coating system of arc ion plating and high power impulse magnetron sputtering (HiPIMS) method. And, ultrathin $Al_2O_3$ passivation layer was deposited on the CrAlSiN/Cr adhesion layer/SUS304 sample to protect CrAlSiN coatings by encapsulating the whole surface defects of coating using ALD. Here, the high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and energy dispersive X-ray spectrometry (EDX) analysis revealed that the ALD $Al_2O_3$ thin films uniformly covered the inner and outer surface of CrAlSiN coatings. Also, the potentiodynamic and potentiostatic polarization test revealed that the corrosion protection properties of CrAlSiN coatings/Cr/SUS304 sample was greatly improved by ALD encapsulation with 50 nm-thick $Al_2O_3$ thin films, which implies that ALD-$Al_2O_3$ passivation layer can be used as an effect barrier layer of corrosion.

A Study on the Effect of Polyetherimide Surface Treatment on the Adhesion and High Temperature/High Humidity Reliability of MCM-D Interface (Polyetherimide 접착제의 표면 처리에 따른 MCM-D 계면 접착력 및 고온고습 신뢰성 변화에 관한 연구)

  • Yoon, Hyun-Gook;Ko, Hyoung-Soo;Paik, Kyung-Wook
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1176-1180
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    • 1999
  • The adhesion strength and high temperature/high humidity reliability of polyetherimide (PEI) adhesive on silicon wafer after being treated by each reactive ion etching (RIE) Aluminum (Al)-chelate adhesion promoter were investigated. 180$^{\circ}$ peel test and <85$^{\circ}C$ 85%> humidity test were performed for the initial adhesion strength and high temperature/high humidity reliability, respectively. For investigating surface effect scanning electron microscope (SEM), atomic force microscope (AFM), deionized (DI)-water contact angle studies were carried out. To investigate RIE effect, PEI was treated with $^O_2$ RIE, and then laminated. The initial peel strength increased slightly from 1.6 kg/cm for the first 2 minutes, and then decreased. High temp/high humid resistance decreased rapidly by RIE etching. RIE treatment on PEI affected on both of roughness and hydrophilicity increase. Aluminum-chelate adhesion promoter was coated by spinning on silicon wafer. The initial peel strength showed no effect of adhesion promoter treatment, but high temp/high humidity resistance increased remarkably. Al-chelate adhesion promoter did not affect the roughness but increased hydrophilicity.

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Surface Immobilization of $(1{\to}3)(1{\to}6)-{\beta}-glucan$ onto Biodegradable Polymer for Tissue Regeneration (조직 재생을 위한 Poly (D, L-lactide-co-glycolide) 표면에 $(1{\to}3)(1{\to}6)-{\beta}-glucan$ 고정에 대한 세포 점착 및 성장 효과)

  • Lee, S.G.;Lee, J.B.;Yu, S.M.;Park, J.C.;Choi, J.B.;Kim, J.K.
    • Journal of Biomedical Engineering Research
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    • v.27 no.5
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    • pp.218-223
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    • 2006
  • We examined the effects of ${\beta}$-glucan-reinforced PLGA film and scaffold on HDFs (human dermal fibroblast) attachment and proliferation. The PLGA films were prepared by simple solvent-casting method. The prepared films were grafted with $(1{\to}3)(1{\to}6)-{\beta}-glucan$ in various ratios after plasma treatment on surface. The surface of the film was characterized by contact angle measurement, scanning electron microscope (SEM), and Fourier-transform infrared spectrophotometer (FT-IR). The amount of $(1{\to}3)(1{\to}6)-{\beta}-glucan$ in the prepared film was indirectly determined by phenol-sulfuric acid method. The HDFs (Human dermal fibroblasts) were used to evaluate the cell attachment and proliferation on PLGA specimens before and after plasma/${\beta}-glucan$ treatment. The result showed that the plasma treated groups exhibited more mont of ${\beta}-glucan$ might be grafted than the non plasma treated groups. Cell attachment was significantly enhanced in the plasma/${\beta}-glucan$ grafted group after 4 hours incubation (p<0.05) due to the improved hydrophilicity and cytoactivity effect of the ${\beta}-glucan$. The cell proliferation of plasma/${\beta}-glucan$ (2mg/ml) grafted group was the highest rate among the groups (p<0.05).

A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Functionalization of Electrospun Nano/Micro-fibrous Scaffolds Using Gamma-ray Irradiation (감마선 조사법을 이용한 전기방사 나노/마이크로 섬유 지지체의 표면 기능화)

  • Lim, Jong-Young;Shin, Young Min;Choi, Jong-Bae;Jeong, Jin-Oh;Gwon, Hui-Jeong;Jeong, Sung In;Park, Jong-Seok;Lim, Youn-Mook
    • Journal of Radiation Industry
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    • v.7 no.1
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    • pp.45-49
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    • 2013
  • In tissue engineering application, a fibrous structure of scaffolds has been issued as an alternative system to regulate cell survival and tissue regeneration, and electrospinning technique has been popularly used to generate fibrous meshes or sheets mimicking the structure of native extracellular matrix (ECM). However, recent strategy in the scaffold development is expanded to provide the structural property as well as a biological property of native ECM, a variety of surface modification techniques have been used to introduce biological property. In this study, we developed biomimetic poly(L-lactide-co-${\varepsilon}$-caprolactone) (PLCL) nano- and micro-fibrous scaffolds as a unique platform with structural and biological properties with native ECM using electrospinning method and gamma-ray irradiation. Surface morphology of the scaffolds was observed by scanning electron microscopy, and alteration of surface property was evaluated with toluidine blue O staining, water contact angle measurement and ATR-FTIR analysis.

Optical properties and color analysis of various pearl shells (다양한 진주조개 패각의 색상 및 광학적 특성 분석)

  • Lee, Myung-Jin;Chae, Weon-Sik;Seo, Jin-Gyo;Park, Jong-Wan
    • The Korean Journal of Malacology
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    • v.25 no.3
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    • pp.203-210
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    • 2009
  • Optical properties and color analysis of nacreous layers were performed using various pearl shells. The cross section and microstructure of the surface in each nacreous layers were observed through a SEM (Scanning Electron Microscope), and the diffraction pattern on SEM images was analyzed using FFT (Fast Fourier Transform). Through these analysises, it was verified that the color and optical characteristics are closely related to the structure of nacreous layers. Incident angle-dependent reflection spectrum was used to examine the phenomena of color differenceas the direction of observation. Quantified values on the color change were obtained by CIE $L^*a^*b^*$ color scale. Using this research, database for the characteristics of natural pearl shells can be established, and the precise analytic method for observation of pearl shells was suggested.

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