• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.54-61
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• 2019

In this study, a magnetic adsorbent was synthesized by growing ferrite nanoparticles substituted with metals (Me = Co, Mn, Ni) on zeolite 4A for the efficient separation of waste adsorbents present in the solution after the adsorption of Cu(II). The metal ferrite grown on the surface of zeolite was prepared by solvothermal synthesis. Characteristics of the magnetic adsorbent were analyzed by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and physical property measurement system (PPMS). The saturation magnetization of the A type zeolite coated with Co-ferrite (CFZC) was the highest at 5 emu/g and the Cu(II) adsorption performance was also excellent. The adsorption results of Cu(II) on CFZC were well fitted by the Langmuir model at 298 K. Also, the adsorption of Cu(II) on CFZC follows a pseudo-second order kinetic. The Gibbs free energy values (${\Delta}G^0$) ranging from -4.63 to -5.21 kJ/mol indicates that the Cu(II) adsorption is spontaneous in the temeprature range between 298 and 313 K.

• Current Applied Physics
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• v.18 no.11
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• pp.1320-1326
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• 2018

High crystalline quality CrN thin films have been grown on $La_{0.67}Sr_{0.33}MnO_3$ (LSMO) templates by molecular beam epitaxy. The structure and magnetic properties of CrN/LSMO heterojunctions are investigated combining with the experiments and the first-principles simulation. The N?el temperature of the CrN/LSMO samples is found to be 281 K and the saturation magnetization of CrN/LSMO increases compared to that of LSMO templates. The magnetic property of CrN/LSMO heterostructures mainly comes from Cr atoms of (001) CrN and Mn atoms of (001) LSMO. The (001) LSMO induces and couples the spin of the CrN sublattice at CrN/LSMO interface.

• Proceedings of the KSR Conference
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• 2011.10a
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• pp.1832-1837
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• 2011

This paper presents the optimal permanent magnet shape on the rotor of an interior permanent magnet motor to reduce the core losses and improve the performance. As permanent magnet has conductivity inherently, it causes huge amount of eddy current losses by the slot harmonics with concentrated winding. This loss is roughly 100 times larger than that of distributed winding in high speed operation and it cannot be ignored, especially on traction motors. Each eddy current loss on permanent magnet has been investigated in detail by using FEM(Finite Element Method) instead of EMCNM(Equivalent Magnetic Circuit Network Method) in order to consider saturation and non-linear magnetic property. Simulation-based DOE(Design Of Experiment) is also applied to avoid large number of analyses according to each design parameter and consider expected interactions among parameters. Consequently, the optimal design to reduce the core loss on the permanent magnet while maintaining or improving motor performance is proposed by an optimization algorithm using regression equation derived and lastly, the core loss reduction on the proposed shape of the permanent magnet is verified by FEM.

• Advances in nano research
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• v.1 no.4
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• pp.183-192
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• 2013

One-dimensional multiferroic nanostructured composites have drawn increasing interest as they show tremendous potential for multifunctional devices and applications. Herein, we report the synthesis, structural and dielectric characterization of barium titanate ($BaTiO_3$)-bismuth ferrite ($BiFeO_3$) composite fibers that were obtained using a novel sol-gel based electrospinning technique. The microstructure of the fibers was investigated using scanning electron microscopy and transmission electron microscopy. The fibers had an average diameter of 120 nm and were composed of nanoparticles. X-ray diffraction (XRD) study of the composite fibers demonstrated that the fibers are composed of perovskite cubic $BaTiO_3$-$BiFeO_3$ crystallites. The magnetic hysteresis loops of the resultant fibers demonstrated that the fibers were ferromagnetic with magnetic coercivity of 1500 Oe and saturation magnetization of 1.55 emu/g at room temperature (300 K). Additionally, the dielectric response of the composite fibers was characterized as a function of frequency. Their dielectric permittivity was found to be 140 and their dielectric loss was low in the frequency range from 1000 Hz to $10^7$ Hz.

• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2546-2552
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• 2012

A novel biguanide-functionalized $Fe_3O_4/SiO_2$ magnetite nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperbase in chemical transformations. The structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (TEM), powder X-ray diffraction (XRD), vibrating sample magnetometry (VSM), elemental analyzer (EA), thermogravimetric analysis (TGA), $N_2$ adsorption-desorption (BET and BJH) and FT-IR. The biguanide-functionalized $Fe_3O_4/SiO_2$ nanoparticles showed a superpara-magnetic property with a saturation magnetization value of 46.7 emu/g, indicating great potential for application in magnetically separation technologies. In application point of view, the prepared catalyst was found to act as an efficient recoverable nanocatalyst in nitroaldol and domino Knoevenagel condensation/Michael addition/cyclization reactions in aqueous media under mild condition. Additionally, the catalyst was reused six times without significant degradation in catalytic activity and performance.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.270-270
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• 2016

We fabricated an organic-inorganic nano laminated encapsulation layer using molecular layer deposition (MLD) combined with atomic layer deposition (ALD). The $Al_2O_3$ inorganic layers as an effective single encapsulation layer were deposited at 80 degree C using ALD with alternating surface-saturation reactions of TMA and $H_2O$. A self-assembled organic layers (SAOLs) were fabricated at the same temperature using MLD. MLD and ALD deposition process were performed in the same reaction chamber. The prepared SAOL-$Al_2O_3$ organic-inorganic nano laminate films exhibited good mechanical stability and excellent encapsulation property. The measurement of water vapor transmission rate (WVTR) was performed with Ca test. We controlled thickness-ratio of organic and inorganic layer, and specific ratio showed a lowest WVTR value. Also this encapsulation layer contained very few pin-holes or defects which were linked in whole area by defect test. To apply into real OLEDs panels, we controlled a film stress from tensile to compressive and flexibility defined as an elastic modulus with organic-inorganic ratio. It has shown that OLEDs panel encapsulated with nano laminate layer exhibits better properties than single layer encapsulated in acceleration conditions. These results indicate that the organic-inorganic nano laminate thin films have high potential for flexible display applications.

• Transactions of the KSME C: Technology and Education
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• v.2 no.2
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• pp.105-111
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• 2014

Generally the lower part of the Earth's atmosphere, which is 20km above the ground, is called "air." The composition of this area is almost consistent consisting of nitrogen, oxygen, and other gases. Air density refers to the mass per unit volume of earth atmosphere. Though air is made of the mixed gases in a constant composition, the water vapor is one of the very changeable components. The density of moist air is lower than the dry one at the same temperature and pressure. As the density varies according to the pressure and temperature, this paper attempts to explore the main factors in the air quantity calculation by examining first the density calculation process according to the air property, and second the relation between the actual and standard air flow.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.851_852
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• 2009

Shrink fitting which is assembling process to fix stator core on the motor frame is widely used at the mass production line of motors because of cost and productivity. This process produces compressive stress on a stator core, which causes negative effect for example, core and copper losses on motor performance. Magnetic properties of electrical steel are effected by both compressive and tensile and thermal stresses. Electromagnetic field analysis is considered one of the effective process since one can predict motor performance including core loss precisely. This method can consider non linear magnetic property with magnetic saturation which is typical electrical steel behavior. However this method is strongly depended on non linear magnetic data, one may have different calculation result whether considering mechanical stress or not. This study describes magnetic field analysis of a motor considering mechanical stress from shrink fitting. Analysis results are compared with each stress-free and stressed condition.

• Magazine of the Korean Society of Agricultural Engineers
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• v.16 no.3
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• pp.3477-3491
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• 1974

Following are the results of the study on the property of falling permeation of stratified soil in the close state under existence of stagnant water on a soil layer. 1. When on the stratified soil a least permeating layer was put on the soil layer the load Pressure was present owing to appearance of saturation close state driving decrease of the pressure in the lower layer, on the other hand when the least permeating layer was placed under the layer the lower least permeating layer pressure was decreased. 2. In the case of least permeating layer the variation of current gradient according to the respective level after treating the layer was enormous and due to usal storage phenomena for the Kl layer which was coarse that was trifle. 3. The permeability of the respective layer of stratified soil in the close state died not always coincide with that of single layer. 4. Generally Zunker's equation of average permeability was valid but actually calculated permeating velocity after treating the layer of stratified soil was seriously differ from the measured value owing to the variation of current gradient, especially when the pressure head at the layer boundany was discontinuous the validity of the equation of average permeability was seemed to be doubtful. 5. The permeating velocity of stratified soil was regulated by the least permeating layer, i.e. it is thought to be rational to estimate the value by calculating the current gradient with its proper permeability, pressure headon the layer and its thickness.

• Journal of Satellite, Information and Communications
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• v.3 no.1
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• pp.15-21
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• 2008

The high peak to average power ratio (PAPR) of OFDM (Orthogonal Frequency Division Multiplexing) system introduces inevitable non-linear distortion in the transmission due to the amplifier non-linear property. This causes both in-band distortion and out of band spectrum re-growth. In this paper we tried to compensate the problem by using polynomial based pre-distortion. Estimation of both the non-linear and inverse non-linear polynomial is achieved using the Least Square Error (LSE) method. Using these parameters closed form pre-distorter can be easily created. We also used the 'partial peak cancellation and clipping' method to remove the high peak present in the non constant amplitude of the OFDM signal responsible to drive the amplifier in near saturation region for better performance of the system