• Title/Summary/Keyword: Saturated resin

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A Study on Electrical Degradation Properties of Epoxy Resin due to Moisture Absorption (흡습에 의한 에폭시 수지의 전기적 열화 특성에 관한 연구)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.656-661
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    • 2013
  • In this study, the moisture content, charge discharge current, electrostatic capacity and dielectric loss tangent are measured for the specimen of bisphenol type epoxy resin which is mixed with squared amorphous silica filler and dipped in hot water of $50^{\circ}C$ for 169 days. The results of this study are listed below. The longer of deposition day, the charge and discharge current was increased. It is considered that the reason is because there was water attack through the squared silica surface. The longer of deposition day, the absorption rate of all specimens was increased. It found that the absorption rate reached saturated state after 100 days. The higher frequency and the longer of deposition day, the $tan{\delta}$ was decreased. Also, It found that the $tan{\delta}$ and electrostatic capacity of the specimen which is mixed with squared filler are greater.

Structural and Physical Properties of Sealant Paste Prepared by Silica/Polymer Composites (실리카/고분자 복합체를 이용한 실란트 페이스트의 구조 및 물리적 특성)

  • Yoon, Jong-Kuk;Park, Jung-Il;Koo, Kyung-Wan;Jang, Young-Sil
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.6
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    • pp.916-921
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    • 2012
  • Sealant paste with silica immersed in cross-linked epoxy-acrylate polymer resin was prepared by thermal and UV curing process. The curing mechanism of polymer resin resulted from 2 functional groups of epoxy and acrylic structure. The properties of microstructure, thermal conductivity and mechanical strength were investigated for its various applications. The adhesion strength is increased by increasing the thermal curing time until 15 minutes, and curing efficiency is saturated over 20 minutes. The increase rate per day of pot life and viscosity is 4.8%, indicating it has excellent storage stability. It is found that the formulation of silica pastes can be applied to heavy industries, building materials, display and various industries.

Inhibitory Effect of Aged Petroleum Hydrocarbons on the Survival of Inoculated Microorganism in a Crude-Oil-Contaminated Site

  • Kang, Yoon-Suk;Park, Youn-Jong;Jung, Jae-Joon;Park, Woo-Jun
    • Journal of Microbiology and Biotechnology
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    • v.19 no.12
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    • pp.1672-1678
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    • 2009
  • We studied the effects of aged total petroleum hydrocarbons (aged TPH) on the survival of allochthonous diesel-degrading Rhodococcus sp. strain YS-7 in both laboratory and field investigations. The aged TPH extracted from a crude-oil-contaminated site were fractionized by thin-layer chromatography/flame ionization detection (TLC/FID). The three fractions identified were saturated aliphatic (SA), aromatic hydrocarbon (AH), and asphaltene-resin (AR). The ratio and composition of the separated fractions in the aged TPH were quite different from the crude-oil fractions. In the aged TPH, the SA and AH fractions were reduced and the AR fraction was dramatically increased compared with crude oil. The SA and AH fractions (2 mg/l each) of the aged TPH inhibited the growth of strain YS-7. Unexpectedly, the AR fraction had no effect on the survival of strain YS-7. However, crude oil (1,000 mg/l) did not inhibit the growth of strain YS-7. When strain YS-7 was inoculated into an aged crude-oil-contaminated field and its presence was monitored by fluorescent in situ hybridization (FISH), we discovered that it had disappeared on 36 days after the inoculation. For the first time, this study has demonstrated that the SA and AH fractions in aged TPH are more toxic to an allochthonous diesel-degrading strain than the AR fraction.

Immobilization of Burkholderia cepacia Lipase on Weak Base Styrene Resin Using Polyethyleneimine with Cross-linking (PEI(Polyethyleneimine)를 이용하여 음이온계 레진에 고정화된 Lipase AH 제조 및 효소적 Interesterification을 통한 반응 특성 연구)

  • Lee, Chi Woo;Lee, Ki Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.7
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    • pp.1025-1035
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    • 2014
  • This study assessed the effect of immobilized lipase on weak base styrene resin using polyethyleneimine (PEI) with cross-linking. Two procedures were used in this study. The first one, "mono-layer" lipase immobilization, involves washing PEI after adsorption. The second procedure, "multi-layer" lipase immobilization, has no washing before the cross-linking step. Treverlite XS-100200 (weak base styrene resin) was immersed with PEI solution (2.2 mg/mL). Lipase AH (from Burkholderia cepacia) was adsorbed onto the support coated with PEI before cross-linking with glutaraldehyde. Structured lipid was synthesized by immobilized lipase-catalyzed interesterification using canola oil, palmitic ethyl ester (PEE), and stearic ethyl ester (StEE). Total fatty acid contents of triacylglycerol (TAG) in structured lipids were analyzed to investigate activity, properties, and reusability of immobilized lipases. Activities of immobilized lipases on the multi-layer and mono-layer increased at a high concentration (8 mg/mL) of lipase solution used for immobilization. The results show that immobilized lipase with the mono-layer method at pH 8.0 on resin had the highest total saturated fatty acid content (26.17 area%). Activity of immobilized lipase with the multi-layer method at pH 7.5 on support was lower than that of the mono-layer, but total saturated fatty acid content was 16.79 area% higher than that of lipase AH (15.01 area%).

Simulation of Pervaporation Process Through Hollow Fiber Module for Treatment of Reactive Waste Stream from a Phenolic Resin Manufacturing Process (페놀수지 생산공정에서 배출되는 반응성 폐수처리를 위한 중공사막 모듈 투과증발 공정모사)

  • C. K Yeom;F. U. Baig
    • Membrane Journal
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    • v.13 no.4
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    • pp.257-267
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    • 2003
  • For the treatment of reactive phenolic resin waste, a simulation model of pervaporative dehydration process has been developed through hollow fiber membrane module. Some of basic parameters were determined directly from dehydration of the waste liquid through a flat sheet membrane to get realistic values. The simulation model was verified by comparing the simulated values with experimental data obtained from hollow fiber membrane module. Hollow fiber membranes with active layer coated on inside fiber were used, and feed flew through inside hollow fiber. Feed flow rate affected membrane performances and reaction by providing a corresponding temperature distribution of feed along with fiber length. Feed temperature is also a crucial factor to determine dehydration and reaction behavior by two competing ways; increasing temperature increases permeation rate as well as water formation rate. Once the permeate pressure is well below the saturated vapor pressure of feed, permeate pressure had a slightly negative effect on permeation performance by slightly reducing driving force. As the pressure approached the vapor pressure of feed, dehydration performances declined considerably due to the activity ratio of feed and permeate.

Improvement for Shielding Effectiveness of EMI Shield Layers using Conformal Spray Coating Scheme (콘포멀 스프레이 코팅으로 형성한 EMI 차단막의 차폐효과 개선)

  • Hur, Jung;Lee, Won-Hui
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.6
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    • pp.107-112
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    • 2018
  • Shielding effectiveness (SE) improvement with EMI shield layers fabricated by conformal spray coating system was studied. Silver or Nickel powder filled acrylic resin were sprayed on the samples. We compared the performance with the viscosity of 400 cPs and 100 cPs cases. The thickness range of the coating layer was 20 to 50 um for the silver, 60 to 120 um for the nickel. The shielding effectiveness was measured by ASTM D4935 using coaxial type TEM-cell. The silver-filled resin showed much better performance than that of the nickel-filled resin. The shielding effectiveness increased almost proportional to the thickness of the coating layers until being saturated around 63 dB for the silver-layer or around 34 dB for the nickel-layer. The best performance measured in this study was the shielding effectiveness of 63 dB with $35{\mu}m-thick$ of silver-layer.

A study on characteristic adgesive condition at microscopic interfaces and notch shape strength of GFRP composites laminates under low-hot-wet environment (저온.고온고습 환경시험에 의한 GFRP의 미시계면 접착상태 및 노치형상강도 특성에 관한 연구)

  • 김옥만;박귀성;한길영;이동기;김이곤
    • Journal of Ocean Engineering and Technology
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    • v.10 no.4
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    • pp.58-66
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    • 1996
  • The purpose of this investigation is to estimate the strength with the variations of the notch shape and the adgesive condition at the fiber/matrix micro interface of E-glass/PP laminates. To promote the degradation of the adhesive condition at the fiber/matrix micro interface without matrix dissolution loss, low-, hot-wet and spiking tests were carried out. The absorpotion properties and the tensile properties were compared accrding to the fiber orientation and the content. The results show that, firstly, saturated moisture absorption was reached at 5cycles and their absorptions of RD-40, UD-42 and UD-50 are 0.68%, 0.63%, 0.60%, respectively. Secondly, all the specimens investigated were mostly degraded at 5cycle, whereas UD-50 having ellipse shaped notch the least decrement of strength.

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Numerical and experimental analysis of the resin transfer molding process

  • Hattabi, Mohamed;Echaabi, Jamal;Bensalah, Mohamed Ouadi
    • Korea-Australia Rheology Journal
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    • v.20 no.1
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    • pp.7-14
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    • 2008
  • The objective of this work is to propose a procedure to simulate the flow in the LCM (Liquid Composites Molding) processes by finite difference discretization in a curvilinear coordinate system adapted to the shape of the saturated zone. The numerical results obtained are compared with experimental results obtained by an experimental device elaborated at our laboratory. It allows to realize linear and radial injections for different porosities and to observe the flow front kinetics. Numerical and experimental results are then compared with those of the literatures and excellent agreements are noticed. Finally, we suggest a concept of the capillary number to explain the variations of the permeability obtained for pressure values lower than 0.25 Bar.

Nanotube Morphology Change of Ti-Ta-Zr Alloy as Zr Content

  • Kim, Won-Gi;Choe, Han-Cheol;Ko, Yeong-Mu
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.105-106
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    • 2008
  • Nanotube morphology change of Ti-Ta-Zr alloy as Zr content increase has been researched using various experimental methods. Ti-Ta-Zr(3, 7 and 15 wt%) alloys were prepared by arc melting and nano-structure controlled for 24 hr at $1000^{\circ}C$ in argon atmosphere. Formation of oxide nanotubes are conducted by anodizing a Ti-Ta-Zr alloy in $H_3PO_4$ electrolytes with small amounts of fluoride ions at room temperature. Electrochemical experiments were carried out with conventional three-electrode configuration with a platinum counter electrode and a saturated calomel reference electrode. The samples were embedded with epoxy resin, leaving a square surface area of $10mm^2$ exposed to the anodizing electrolyte, 1.0M $H_3PO_4$ containing 0.8wt% NaF.

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Screening of Adsorbent to Reduce Salt Concentration in the Plastic Film House Soil under Continuous Vegetable Cultivation (시설채소재배지의 토양특성과 흡착제 종류별 염류경감 효과)

  • Ok, Yong-Sik;Yoo, Kyung-Yoal;Kim, Yoo-Bum;Chung, Doug-Young;Park, Yong-Ha;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.253-260
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    • 2005
  • Salt accumulation in the plastic film house soils under continuous cultivation condition causes problems such as salt damages to plants, nitrate accumulation in vegetables, groundwater contamination, etc. due to excess application of fertilizers. Objective of this research was to find an optimum adsorbent to reduce salt concentration in the soil solution of plastic film house soils, where crop injuries have been observed due to the salt accumulation. The soils were significantly high in available P $(1,431{\sim}6,516mg\;kg^{-1}),\;NO_3-N\;(117.60{\sim}395.73mg\;kg^{-1})$, exchangeable Ca $(4.06{\sim}11.07\;cmol_c\;kg^{-1})$ and Mg $(2.59{\sim}18.76\;cmol_c\;kg^{-1})$, as compared to those of the average upland soils in Korea. Soils were treated with each of adsorbent such as ion-exchange resin, zeolite, rice bran, etc. at 2% level and prepared into saturated-paste samples. After equilibrium, soil solution was vacuum-extracted from the soil and measured for changes of the pH, EC, and concentrations of $Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+,\;{NH_4}^+,\;{PO_4}^{3-}\;and\;{NO_3}^-$. Rice bran effectively removed ${PO_4}^{3-}\;and\;{NO_3}^-$ in the soil solution up to 100%. Efficiency was decreased in the orders of rice bran > ion-exchange resin > zeolite. Removal efficiencies of zeolite and ion-exchange resin for $Ca^{2+}$ were ranged from 1 to 65% and from 7 to 61%, respectively. Ion-exchange resin was also effective for removing $Mg^{2+},\;K^+,\;Na^+,\;and\;{NH_4}^+$. Overall results demonstrated that rice bran and ion-exchange resin could be applicable for salt accumulated soil to remove the respective anion and cation.