• Title/Summary/Keyword: Sample testing

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An Electrochemical Method to Predict Corrosion Rates in Soils

  • Dafter, M.R
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.217-225
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    • 2016
  • Linear polarization resistance (LPR) testing of soils has been used extensively by a number of water utilities across Australia for many years now to determine the condition of buried ferrous water mains. The LPR test itself is a relatively simple, inexpensive test that serves as a substitute for actual exhumation and physical inspection of buried water mains to determine corrosion losses. LPR testing results (and the corresponding pit depth estimates) in combination with proprietary pipe failure algorithms can provideauseful predictive tool in determiningthe current and future conditions of an asset. Anumber of LPR tests have been developed on soil by various researchers over the years1), but few have gained widespread commercial use, partly due to the difficulty in replicating the results. This author developed an electrochemical cell that was suitable for LPR soil testing and utilized this cell to test a series of soil samples obtained through an extensive program of field exhumations. The objective of this testing was to examine the relationship between short-term electrochemical testing and long-term in-situ corrosion of buried water mains, utilizing an LPR test that could be robustly replicated. Forty-one soil samples and related corrosion data were obtained from ad hoc condition assessments of buried water mains located throughout the Hunter region of New South Wales, Australia. Each sample was subjected to the electrochemical test developed by the author, and the resulting polarization data were compared with long-term pitting data obtained from each water main. The results of this testing program enabled the author to undertake a comprehensive review of the LPR technique as it is applied to soils and to examine whether correlations can be made between LPR testing results and long-term field corrosion.

Measurement of Cortisol in Human Serum by Isotope Dilution Liquid Chromatography/Mass Spectrometry and a Comparison through a Proficiency Testing

  • Lee, Hwa-Shim;Shin, Hye-Sun;Park, Sang-Ryoul;Park, Chang-Joon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1149-1154
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    • 2010
  • Liquid chromatography/mass spectrometry using isotope dilution method has been established as a primary method for the measurement of cortisol in human serum. Verification of this method was accomplished by the participation in Consultative Committee for Amount of Substance-Metrology in Chemistry (CCQM) pilot study. Two levels of cortisol certified reference materials were prepared and certified by the established method. They were used as sample materials for the proficiency testing. The expanded uncertainty in the measurement of cortisol in human serum was approximately 1.2% at 95% confidence level. The results of the proficiency testing showed a good precision among the participants, but some bias to the certified values. This means that commercial field laboratories should keep traceability chain to SI unit through available reference measurement procedures and/or available reference materials.

Hydraulic conductivity of cemented sand from experiments and 3D Image based numerical analysis

  • Subramanian, Sathya;Zhang, Yi;Vinoth, Ganapathiraman;Moon, Juhyuk;Ku, Taeseo
    • Geomechanics and Engineering
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    • v.21 no.5
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    • pp.423-432
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    • 2020
  • Hydraulic conductivity is one of the engineering properties of soil. This study focusses on the influence of cement content on the hydraulic conductivity of cemented sand, which is investigated based on the results from numerical analysis and laboratory testing. For numerical analysis the cemented samples were scanned using X-ray Computed Tomography (CT) while laboratory testing was carried out using a triaxial setup. Numerical analysis enables us to simulate flow through the sample and provides insight to the microstructure. It quantifies the pore volume, proportion of interconnected voids and pore size distribution in both cemented and uncemented samples, which could be computed only through empirical equations in case of laboratory testing. With reduction in global voids, the interconnecting voids within the samples also reduce with cement content. Gamma cumulative distribution function is used to predict the percentage of voids lesser than a given pore volume. Finally, the results obtained from both numerical analysis and laboratory testing are compared.

Taming of large diameter triaxial setup

  • Nair, Asha M.;Madhavi Latha, G.
    • Geomechanics and Engineering
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    • v.4 no.4
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    • pp.251-262
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    • 2012
  • Triaxial tests are essential to estimate the shear strength properties of the soil or rock. Normally triaxial tests are carried out on samples of 38 mm diameter and 76 mm height. Granular materials, predominantly used in base/sub-base construction of pavements or in railways have size range of 60-75 mm. Determination of shear strength parameters of those materials can be made possible only through triaxial tests on large diameter samples. This paper describes a large diameter cyclic triaxial testing facility set up in the Geotechnical Engineering lab of Indian Institute of Science. This setup consists of 100 kN capacity dynamic loading frame, which facilitates testing of samples of up to 300 mm diameter and 600 mm height. The loading ram can be actuated up to a maximum frequency of 10 Hz, with maximum amplitude of 100 mm. The setup is capable of carrying out static as well as dynamic triaxial tests under isotropic, anisotropic conditions with a maximum confining pressure of 1 MPa. Working with this setup is a difficult task because of the size of the sample. In this paper, a detailed discussion on the various problems encountered during the initial testing using the equipment, the ideas and solutions adopted to solve them are presented. Pilot experiments on granular sub-base material of 53 mm down size are also presented.

Determination of Sample Sizes of Bivariate Efficacy and Safety Outcomes (이변량 효능과 안전성 이항변수의 표본수 결정방법)

  • Lee, Hyun-Hak;Song, Hae-Hiang
    • The Korean Journal of Applied Statistics
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    • v.22 no.2
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    • pp.341-353
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    • 2009
  • We consider sample-size determination problem motivated by comparative clinical trials where patient outcomes are characterized by a bivariate outcome of efficacy and safety. Thall and Cheng (1999) presented a sample size methodology for the case of bivariate binary outcomes. We propose a bivariate Wilcoxon-Mann-Whitney(WMW) statistics for sample-size determination for binary outcomes, and this nonparametric method can be equally used to determine sample sizes of ordinal outcomes. The two methods of sample size determination rely on the same testing strategy for the target parameters but differs in the test statistics, an asymptotic bivariate normal statistic of the transformed proportions in Thall and Cheng (1999) and nonparametric bivariate WMW statistic in the other method. Sample sizes are calculated for the two experimental oncology trials, described in Thall and Cheng (1999), and for the first trial example the sample sizes of a bivariate WMW statistic are smaller than those of Thall and Cheng (1999), while for the second trial example the reverse is true.

A Study of the Efficacy to Control the Bacteria Colony of Scalp in Ayurvedic Oils on Clinical Testing

  • Choi, Jung-Myung
    • Journal of Fashion Business
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    • v.13 no.6
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    • pp.45-60
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    • 2009
  • This study examined the efficacy of restraining the increase of the bacteria colony of scalp according to the application of the Ayurvedic base oils and essential oils to scalp and hair. The result is as follows. The experiment illustrated that as the result of doing the paired sample t-test of a treated group and a control group according to constitutional oiling, the efficacy of the statistically significant decrease of the colony manifested in six tested groups except the group of Pitta constitution to which sesame and lavender were applied. Also, in a group that sesame was applied to Vata constitution and a group that coconut and lavender were applied to Pitta constitution, according to the passage of time, the result of being reduced the number of the colony was obtained and it showed that the oiling suitable for each constitution has the efficacy to decrease the colony of scalp. At the same time, regardless of the constitutions, the application of oils also showed the efficacy of restraining the increase of the bacteria colony of scalp. As the result of performing Paired Sample t-test for the subjective evaluation of the subjects in pre and post clinical testing, In the analysis of questionnaire that were obtained before and after the clinical testing, the results of all of the items except the item questioning a degree of inflammation appeared to be significant. That is to say, the subjects answered that a degree of keratin or a pain in scalp, an amount of sebum and a degree of hair damage were decreased after the application of oil more than before it. And in the question of a degree of hair damage, the application of oils were proved as having the efficacy to improve the hair damage.

The Effect of Dilution on Porticle Deposition in The Entry Deposit of The Ferrogroms (Ferrography에서 샘풀희석률이 마모입자 정량분석에 미치는 영향)

  • 권오관
    • Tribology and Lubricants
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    • v.1 no.1
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    • pp.38-45
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    • 1985
  • Ferrograms prepared from off samples collected during testing in the transition region were originally diluted at 20:1. To obtain some information about the effect of dilution on the analysis procedures, a series of measurements were made on ferrograms prepared to different dilutions in the range 6 to 30:1 from oil samples collected after testing in the four ball machine at the 51 kg and 55 kg load, respectively, Fig. 1. The variations in area covered, perimeter, intercept and particle count were then plotted as a function of dilution level and appropriate mathematical expressions established such that the results obtained at any dilution level specified within the range can then be corrected back to an equivalent undiluted value. The effect of dilution on the variance of the particle size distribution was also investigated. The main results are tabulated, Tables 1-5 and also plotted as a function of dilution, level Figs. 2-9.

A minimum combination t-test method for testing differences in population means based on a group of samples of size one (크기가 1인 표본들로 구성된 집단에 기반한 모평균의 차이를 검정하기 위한 최소 조합 t-검정 방법)

  • Heo, Miyoung;Lim, Changwon
    • The Korean Journal of Applied Statistics
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    • v.30 no.2
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    • pp.301-309
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    • 2017
  • It is often possible to test for differences in population means when two or more samples are extracted from each N population. However, it is not possible to test for the mean difference if one sample is extracted from each population since a sample mean does not exist. But, by dividing a group of samples extracted one by one into two groups and generating a sample mean, we can identify a heterogeneity that may exist within the group by comparing the differences of the groups' mean. Therefore, we propose a minimum combination t-test method that can test the mean difference by the number of combinations that can be divided into two groups. In this paper, we proposed a method to test differences between means to check heterogeneity in a group of extracted samples. We verified the performance of the method by simulation study and obtained the results through real data analysis.

A Study on the Smoke Hazard Increase of Flame-retardant-treated Interior Decorative Textile -Focused on Viscose Rayon Textile Wallcovering- (난연 처리된 실내장식섬유의 연기 위해성 증가에 관한 연구 -비스코스 레이온 섬유 벽지를 중심으로-)

  • Lee, Joonhan;Kim, Sun Mee
    • Journal of Fashion Business
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    • v.24 no.3
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    • pp.30-39
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    • 2020
  • This study was conducted to identify problems in domestic flame-retardant performance specifications. Currently, the domestic wallcovering anti-inflammatory regulations are not prepared for damage caused by smoke, with the carbonized area as the main function. In particular, given that smoke is the main cause of human casualties and injuries in a fire, it is reasonable that the flame density and toxicity of the wallcovering should also be the main performance indicators. The scope and method of research in this study were as follows. First, a prior study related to fire on various wallcoverings was considered. Second, it raised questions about the effects of smoke in the event of a fire and domestic anti-inflammatory performance tests. Third, textile wallcovering samples were manufactured with viscose rayon for experimental verification of the problems and tested by Korean and EU standards without flame retardant processing to analyze the differences between each regulation. Fourth, the performance of flame retardant wallcovering according to Korean standards was evaluated using smoke density and harmful gas testing methods. The results of each test were as follows. Non-fire retardant wallcovering was rejected by Korea standards. However, B-s1.d0 in Europe. Smoke density testing and harmful gas by domestic combustion processing on the same sample showed that the smoke density increased about 4.3 times more than before, and the harmful gas test showed that the suspension of the post-processing sample slowed earlier than the non-processed sample.

Photostability evaluation of Jawarishe Jalinoos

  • Shahnawaz, Shahnawaz;Rahman, Khaleequr;Sultana, Arshiya;Sultana, Shabiya
    • CELLMED
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    • v.11 no.4
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    • pp.18.1-18.8
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    • 2021
  • Jawarishe Jalinoos (JJ) is an orally used formulation available in semisolid dosage form, prepared with powdered plant materials mixed in honey or sugar syrup. It has many admirable pharmacological effects and used in Unani medicine to treat various acute and chronic disorders since ancient times. The ICH Harmonised Tripartite Guideline stated that photostability testing should be an essential part of stability testing to confirm that light exposure does not result in an unacceptable change in drugs substance and finished products. To date, the effect of light on JJ is not studied, in this study photostability evaluation of JJ was carried out. The test sample was manufactured with genuine ingredients in the in-door pharmacy of the National Institute of Unani Medicine. JJ was packed in two transparent polyethylene terephthalate airtight containers. The first sample was analysed at zero-day and the second sample was placed in a stability chamber subjected to light challenge with an overall illumination of 1.2 million lux hours combined with near ultraviolet energy of 200-watt hours per square meter by using option 2, along with 30±2℃ temperature and relative humidity 70±5%. Analysis of both finished products showed no considerable changes in organoleptic characters. Less than 5% variation was observed in physicochemical parameters. HPTLC fingerprinting showed justifiable variation. Microbial load and specific counts were within the limit prescribed by WHO. As no unacceptable changes were noted in JJ subjecting to light challenge, it is concluded that JJ is a photostable Unani compound formulation.