• Title/Summary/Keyword: Sample matrix

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Effect of Annealing Temperature on the Permeability and Magneto-Impedance Behaviors of Fe68.5Mn5Si13.5B9Nb3Cu1 Amorphous Alloy

  • Le Anh-Than;Ha, Nguyen Duy;Kim, Chong-Oh;Rhee, Jang-Roh;Chau Nguyen;Hoa Nguyen Quang;Tho Nguyen Due;Lee, Hee-Bok
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.55-59
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    • 2006
  • The effect of annealing temperature on the permeability and giant magneto-impedance (GMI) behaviors of $Fe_{68.5}Mn_{5}Si_{13.5}B_9Nb_3Cu_1$ amorphous alloy has been systematically investigated. The nanocrystalline $Fe_{68.5}Mn_{5}Si_{13.5}B_9Nb_3Cu_1$ alloys consisting of ultra-fine $(Fe,Mn)_3Si$ grains embedded in an amorphous matrix were obtained by annealing their precursor alloy at the temperature range from $500^{\circ}C\;to\;600^{\circ}C$ for 1 hour in vacuum. The permeability and GMI profiles were measured as a function of external magnetic field. It was found that the increase of both the permeability and the GMI effect with increasing annealing temperature up to $535^{\circ}C$ was observed and ascribed to the ultrasoft magnetic properties in the sample, whereas an opposite tendency was found when annealed at $600^{\circ}C$ which is due to the microstructural changes caused by high-temperature annealing. The study of temperature dependence on the permeability and GMI effect showed some insights into the nature of the magnetic exchange coupling between nanocrystallized grains through the amorphous boundaries in nanocrystalline magnetic materials.

Multivariate Analysis among Leaf/Smoke Components and Sensory Properties about Tobacco Leaves Blending Ratio

  • Lee Seung-Yong;Lee Whan-Woo;Lee Kyung-Ku;Kim Young-Hoh
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.141-152
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    • 2005
  • This study focused on the relationships among leaf and smoke components and sensory properties following tobacco leaf blending. A completely randomized experimental design was used to evaluate components of leaf and smoke and sensory properties for sample cigarettes with four mixtures of flue cured and burley tobacco (40:60, 60:40, 80:20 and 100:0). Eleven leaf components, six smoke components, and eight sensory properties of smoking taste were analyzed. A sensory evaluation method known as quantitative descriptive analysis was used to evaluate perceptual strength on a fifteen score scale. Raw data from ten trained panelists were obtained and statistically analyzed. Based on the MANOVA, clustering analysis, correlation matrix and partial least square (PLS) method were applied to find out which smoke component most affected sensory properties. The PLS method was used to remove the influence between explanatory variables in the leaf, smoke components derived from the results. High correlations (p<0.0l) were found among ten specific leaf and smoke components and sensory attributes. Total nitrogen, ammonia, total volatile base, and nitrate in the leaf were significantly correlated (p<0.05) with impact, bitterness, tobacco taste, irritation, smoke volume, and smoke pungency. From the results of PLS analysis, influence variables are used to explain about the correlation. In terms of bitterness, with only two explanatory variables, Leaf $NO_3$ and Leaf crude fiber were enough for guessing their correlation. In the distance weighted least square fitting analysis, carbon monoxide highly influenced bitterness, hay like taste, and smoke volume.

Source Identification of Ambient Size-by-Size Particulate Using the Positive Matrix Factorization Model on the Border of Yongin and Suwon (PMF 모델을 이용한 용인-수원경계지역에서의 부유분진의 크기별 오염원 확인)

  • Oh, Mi-Seok;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.2
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    • pp.108-121
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    • 2009
  • The suspended particulate matters have been collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005${\sim}$Sep. 2007) in Kyung Hee University-Global Campus located on the border of Yongin and Suwon. The 20 chemical species (Al, Mn, Si, Fe, Cu, Pb, Cr, Ni, V, Cd, Ba, $Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an ICP-AES and an IC after performing proper pre-treatments of each sample filter. Based on these chemical information, the PMF receptor model was applied to identify the source of ambient size-by-size particulate matters. The receptor modeling is the one of the statistical methods to achieve resonable air pollution management strategies. A total of 10 sources was identified in 9 size-ranges such as long-range transport, secondary aerosol, $NH_{4}NO_{3}$ related source, coal combustion, sea-salt, soil, oil combustion, auto emission, incineration, and biomass burning. Especially, the secondary aerosol source assorted in fine and coarse modes was intensively studied.

The effects of Mg2Si(p) on microstructure and mechanical properties of AA332 composite

  • Zainon, Fizam;Ahmad, Khairel Rafezi;Daud, Ruslizam
    • Advances in materials Research
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    • v.5 no.1
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    • pp.55-66
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    • 2016
  • This paper describes a study on the effects of $Mg_2Si_{(p)}$ addition on the microstructure, porosity, and mechanical properties namely hardness and tensile properties of AA332 composite. Each composite respectively contains 5, 10, 15, and 20 wt% reinforcement particles developed by a stir-casting. The molten composite was stirred at 600 rpm and melted at $900^{\circ}C{\pm}5^{\circ}C$. The $Mg_2Si$ particles were wrapped in an aluminum foil to keep them from burning when melting. The findings revealed that the microstructure of $Mg_2Si_{(p)}/AA332$ consists of ${\alpha}$-Al, binary eutectic ($Al+Mg_2Si$), $Mg_2Si$ particles, and intermetallic compound. The intermetallic compound was identified as Fe-rich and Cu-rich, formed as polygonal or blocky, Chinese script, needle-like, and polyhendrons or "skeleton like". The porosity of $Mg_2Si_{(p)}/AA332$ composite increased from 8-10% and the density decreased from 9-12% from as-cast. Mechanical properties such as hardness increased for over 42% from as-cast and the highest UTS, elongation, and maximum Q.I were achieved in the sample of 10% $Mg_2Si$. The study concludes that combined with AA332, the amount of 10 wt% of$Mg_2Si$ is a suitable reinforcement quantity with the combination ofAA332.

Development of a Smoking and Drinking Prevention Program for Adolescents using Intervention Mapping (Intervention Mapping 설계를 통한 중학생 대상 흡연음주예방 교육프로그램 개발)

  • Kye, Su-Yeon;Choi, Seul-Ki;Park, Kee-Ho
    • The Journal of Korean Society for School & Community Health Education
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    • v.12 no.3
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    • pp.1-15
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    • 2011
  • Objectives: We describe the development of a smoking and drinking prevention program for adolescents, using intervention mapping. Methods: The study sample consisted of 1,000 high school second-grade students from 6 high schools in Seoul. The PRECEDE model was applied for the needs assessment. We carried out a social diagnosis by assessing the factors such as the quality of life, happiness level, and satisfaction with school life; an epidemiological diagnosis on the perceived health status, stress levels, and priority of health issues; a behavioral diagnosis on the smoking and drinking rate and the intention to smoke and drink; and an educational diagnosis on knowledge, beliefs, attitudes, self-efficacy, outcome expectations, social norms and life skills. Results: The development process included a needs assessment, identifying factors that influence smoking and drinking among adolescents. Intention, knowledge, perceived norms, perceived benefit, perceived cost, perceived susceptibility, self-efficacy, and life skills were identified as determinants. Three performance objectives were formulated to describe what an individual needs to do in order to avoid smoking and drinking. Subsequently, we constructed an intervention matrix by crossing the performance objectives with the selected determinants. Each cell describes the learning objectives of the smoking and drinking prevention program. The program used methods from the transtheoretical model, such as consciousness raising, outcome expectations, self-reevaluation, self-liberation, counterconditioning, environmental reevaluation, and stimulus control. The program deals with the effects of smoking and drinking, self-improvement, decision making, understanding advertisements, communication skills, social relationships, and assertiveness. Conclusions: By using the process of intervention mapping, the program developer was able to ensure a systematical incorporation of empirical and new data and theories to guide the intervention design. Programs targeting other health-related behavior and other methods or strategies can also be developed using this intervention mapping process.

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Preconcentration of Iron(III), Lead(II), Cobalt(II) and Chromium(III) on Amberlite XAD-1180 Resin Loaded with 4-(2-Pyridylazo)-resorcinol (PAR) and Their Determination by FAAS

  • Tokalloglu, Serife;Kartal, Senol
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1293-1296
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    • 2006
  • In this study, a solid phase extraction method has been developed for the preconcentration and separation of the elements Cr(III), Fe(III), Co(II) and Pb(II) at trace levels by using a column packed with Amberlite XAD-1180 resin loaded with 4-(2-pyridylazo)-resorcinol (PAR) reagent. After preconcentrating, the metals retained on the column were eluted with 20 mL of 3 mol/L $HNO_3$ and then determined by flame atomic absorption spectrometry (FAAS). The factors affecting the recovery of the elements, such as pH, type and concentration of eluent, volume of sample and elution solution, and matrix components, were also ascertained. The recoveries of Cr(III), Fe(III), Co(II) and Pb(II) were found to be $99\;{\pm}\;4,\;97\;{\pm}\;3,\;95\;{\pm}\;3$ and $98\;{\pm}\;4$%, respectively, under the optimum conditions at 95% confidence level and the relative standard deviations found by analyzing of nine replicates were $\leq4.4$%. The preconcentration factors for Cr(III), Fe(III), Co(II) and Pb(II) were found as 75, 125, 50 and 75 respectively. The detection limits (DL, 3s/b) were 3.0 $\mu g/L$ for Cr(III), 1.25 $\mu g/L$ for Fe(III), 3.3 $\mu g/L$ for Co(II), and 7.2 $\mu g/L$ for Pb(II). The recoveries achieved by adding of metals at known concentrations to samples and the analysis results of Buffalo river sediment (RM 8704) show that the described method has a good accuracy. The proposed method was applied to tap water, stream water, salt and street dust samples.

Analysis of Cadmium in Urine using Flame and Flameless Atomic Absorption Spectrophotometry (불꽃 및 비불꽃원자흡수분광법을 이용한 뇨중 카드뮴 분석)

  • Ham, Yong-Gyu;Lee, Seok-Ki;Jeon, Jae-Hong;Joung, Chang-Ung;Son, Bu-Soon
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.355-359
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    • 1999
  • Trace cadmium was determined in urine by flame and nameless AAS. Inflame method, cadmium was extracted into MIBK from Cd-DDTC complex. In flameless method, samples were pretreated with 1%, Triton X-100. 1% $HNO_3$ and matrix modifier $Pd(NO_3)_2$. Analysis of cadmium was, performed at $450-750^{\circ}C$ ashing temperature by use of pyrocoated tubes. Results of analysis, flameless method superior in sample treatment and reproducibility to flame method and highest absorbance was obtained at $550^{\circ}C$ ashing temperature. 100 mg/L $Pd(NO_3)_2$ concentration. Proposed method were applied to the determination of cadmium in standard urine Lononorm-Metalle 3.

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Rapid Detection of Escherichia coli in Fresh Foods Using a Combination of Enrichment and PCR Analysis

  • Choi, Yukyung;Lee, Sujung;Lee, Heeyoung;Lee, Soomin;Kim, Sejeong;Lee, Jeeyeon;Ha, Jimyeong;Oh, Hyemin;Lee, Yewon;Kim, Yujin;Yoon, Yohan
    • Food Science of Animal Resources
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    • v.38 no.4
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    • pp.829-834
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    • 2018
  • The objective of this study was to determine the minimum enrichment time for different types of food matrix (pork, beef, and fresh-cut lettuce) in an effort to improve Escherichia coli detection efficiency. Fresh pork (20 g), beef (20 g), and fresh-cut lettuce (20 g) were inoculated at 1, 2, and 3 Log CFU/g of Escherichia coli. Samples were enriched in filter bags for 3 or 5 h at $44.5^{\circ}C$, depending on sample type. E. coli cell counts in the samples were enriched in E. coli (EC) broth at 3 or 5 h. One milliliter of the enriched culture medium was used for DNA extraction, and PCR assays were performed using primers specific for uidA gene. To detect E. coli (uidA) in the samples, a 3-4 Log CFU/mL cell concentration was required. However, E. coli was detected at 1 Log CFU/g in fresh pork, beef, and fresh-cut lettuce after 5, 5, and 3-h enrichment, respectively. In conclusion, 5-h enrichment for fresh meats and 3-h enrichment for fresh-cut lettuce in EC broth at $44.5^{\circ}C$, and PCR analysis using uidA gene-specific primers were appropriate to detect E. coli rapidly in food samples.

Effect of Titanium Dioxide in BaO-ZnO-B2O3-SiO2 Glasses on the Optical Properties of Color Conversion Glass (BaO-ZnO-B2O3-SiO2계 유리에서 TiO2의 첨가가 색변환 유리의 광특성에 미치는 영향)

  • Jeong, HyeonJin;Lim, Tae-Young;Kim, Jin-Ho;Lee, MiJai;Hwang, Jonghee;Hwang, Pyeong Ha;Park, Tae-Ho;Shin, Dongwook
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.710-714
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    • 2014
  • The effect of titanium dioxide ($TiO_2$) on the properties of color conversion glasses was examined for glasses based on $BaO-ZnO-B_2O_3-SiO_2$. One glass sample, containing 25 mol% of each component, was used as a reference; the other three glass samples contained 1, 3, and 5 mol% $TiO_2$, respectively. The four color conversion glass samples were prepared by sintering a mixture of glass frits and a $YAG:Ce^+$ phosphor. The characteristics of the color conversion glass samples, such as luminous efficacy, luminance, CIE (Commission International de I'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) were analyzed according to the PL spectrum. The refractive index of the glass samples was found to increase with the titanium dioxide content. In conclusion, luminous efficacy of color conversion glasses increased as the content of $TiO_2$ was raised in the glass matrix.

Preparation and Electrochemical Properties of Polymeric Composite Electrolytes Containing Organic Clay Materials (Organic Clay가 첨가된 고분자 복합 전해질의 제조 및 전기화학적 성질)

  • Kim, Seok;Hwang, Eun-Ju;Lee, Jea-Rock;Kim, Hyung-Il;Park, Soo-Jin
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.297-301
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    • 2007
  • In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt ($LiClO_4$), and sodium montmorillonite ($Na^+-MMT$) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of $Na^+-MMT$, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.