• Bulletin of the Korean Chemical Society
• /
• v.33 no.1
• /
• pp.243-247
• /
• 2012

Photocatalysis has been applied to decompose the waste and toxic materials produced in daily life and in the global environment. Pure $TiO_2$ (Zn-$TiO_2$-0) and Zn-doped $TiO_2$ (Zn-$TiO_2$-x, x = 3-10 mol %) samples were synthesized using a novel sol-gel and ammonia-evaporation method. The Zn-doped $TiO_2$ samples showed high photocatalytic activity for the degradation of methylene blue (MB). The physicochemical properties of the samples were investigated using XRD, SEM, ICP, DLS and BET methods. In addition, the most important measurement of photocatalytic ability was investigated by a UV-vis spectrophotometer. The effects of the mol % of zinc ion doping in $TiO_2$ on photocatalytic activity were studied. Among the mol % Zn ions investigated, the Zn-$TiO_2$-9 sample showed the highest photoreactivity. This sample removed 91.4% of the MB after 4 h, while the pure $TiO_2$ only removed 46.4% of the MB.

• Water for future
• /
• v.14 no.4
• /
• pp.27-34
• /
• 1981

The design flow of the urban strom drainage systems has been assessed largely on a basis of empirical relations between rainfall and runoff, and the rational formula has been widely used for the cities in our country. In order to estimate it more accurately, the urban runoff simulation model based on the RRl method has been developed and applied to the sample basin in this study. The rainfall hyetograph of the design stromfor the design flow has been obtained by the determination of the total rainfall and the temporal distributions of that rainfall. The total rainfall has been assessed from the empirical formula of rainfall intensity and the temporal distribution of that rainfall determined on the basis of Huff's method from the historical rainfall data of the basin. The virtual inflow hydrograph to each inlet of the basin has been constructed by computing the series of discharges in each time increment, using design strom hyetograph and time-area diagram. The actual runoff hydrograph at the basin outlet has been computed from the virtual inflow hydrographs by developing a relations between discharge and storage for the watershed. The discharge data for verification of the simulated runoff hydrograph are not available in the sample basin and so the sensitivity analysis of the simulation model has not been possible. The peak discharge for the design of drainage systems has been estimated from the computed runoff hydrograph at the basin outlet and compared to thatl obtained form the rational formula.

• Journal of Electrochemical Science and Technology
• /
• v.13 no.1
• /
• pp.90-99
• /
• 2022

Owing to the rising concern of global warming, lithium-ion batteries have gained immense attention over the past few years for the development of highly efficient electrochemical energy conversion and storage systems. In this study, alpha-phase VOPO₄·2H₂O with nanosheet morphology was prepared via a facile hydrothermal method for application in high-performance lithium-ion batteries. The X-ray diffraction and scanning electron microscopy (SEM) analyses indicated that the obtained sample had an alpha-2 (αII) phase, and the nanosheet morphology of the sample was confirmed using SEM. The lithium-ion battery with VOPO₄·2H₂O as the anode exhibited excellent long-term cycle life and a high capacity of 256.7 mAh g^-1 at room temperature. Prelithiation effectively improved the specific capacity of pristine VOPO₄·2H₂O. The underlying electrochemical mechanisms were investigated by carrying out AC impedance, rate capability, and other instrumental analyses.

• Journal of Applied Biological Chemistry
• /
• v.59 no.1
• /
• pp.69-74
• /
• 2016

The objective of this study was to examine the combined effect of fumaric acid with mild heat on the inactivation of microorganisms on spinach. Spinach leaves were inoculated with Escherichia coli O157:H7 and Listeria monocytogenes. Based on the results of single treatment of fumaric acid (0.1, 0.3, and 0.5%) or mild heat (40, 50, and $60^{\circ}C$) regarding the inactivation of the inoculated bacteria, the optimal condition for the combined treatment was suggested to be 0.5% fumaric acid and mild heat treatment at $50^{\circ}C$ for 5 min. The combined treatment of fumaric acid with mild heat caused 2.53 and 2.62 log reductions of the populations of L. monocytogenes and E. coli O157:H7, respectively. In addition, during storage of fresh spinach at $4^{\circ}C$ for 12 d, the combined treatment reduced initially the populations of total aerobic bacteria by 2.77 log CFU/g compared with the control. In particular, after 12 d of storage, the population of total aerobic bacteria for the combined treatment sample was 4.84 log CFU/g, whereas the control sample had 6.66 log CFU/g. Color and vitamin C content of spinach samples were not altered significantly by the combined treatment during storage. These results indicate that the combined treatment of fumaric acid with mild heat is an effective method to control microorganisms on spinach during storage.

• Korean Journal of Food Science and Technology
• /
• v.31 no.3
• /
• pp.688-696
• /
• 1999

Changes in quality during frozen storage of meat with thermal equalized freezing and various freezing methods were investigated. When beef were frozen at freezing rate of $0.39{\sim}0.66\;cm/h$, average diameter of ice crystal were about $30{\sim}50\;{\mu}m$ and showed broken tissues or irregular cracks. At freezing velocity of $1.14{\sim}2.26\;cm/h$, ice crystals of about $10{\sim}30\;{\mu}m$ was formed mainly inside or between fiber and slight destruction of tissues was occurred. The average diameter (D) of the ice crystals were related to the characteristic freezing time $(t_c)$ by the equation: $D({\mu}m)=4.089+26.88logt_c\;(r^2=0.913)$. Beef with still-air freezing showed higher drip loss than methods of immersion and thermal equalized freezing. Also, drip loss of pork was relatively lower than beef and showed highest value to 7.39% during storage on 40 days at air-blast freezing method. No apparent change of pH during storage of frozen beef and pork by freezing methods were detected. However, least changes for sample with thermal equalized freezing was found compare to sample with still-air and air blast freezing in VBN and TBA value. The fluctuation of frozen storage temperature did not cause noticeable changes on pH and water content. However, drip loss, VBN and TBA values were increased slowly as frequency of fluctuation increased.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.6
• /
• pp.804-812
• /
• 2003

This paper introduces optical methods for in-situ measurement of surface temperature and pressure transient in thermal processes having nanosecond time scales. In the temperature measurement, a p -Si thin film whose refractive index is calibrated as a function of temperature is embedded beneath the sample surface and the photothermal reflectance is monitored for estimating the surface temperature. The pressure transients are measured using the photoacoustic optical deflection method. The experimental technique is used to analyze the nanosecond laser induced vaporization process that is central to numerous engineering and bio-medical applications. Based on the experimental results, discussions are made on the experimental technique and the physical mechanisms of laser-driven explosive vaporization phenomena.

• Journal of the Korean Society of Food Culture
• /
• v.3 no.4
• /
• pp.391-396
• /
• 1988

The method for the measurement of texture hardening phenomena, which is the limiting factor of shelf-life of Yaksik in the market, was established. The changes in the hardening rate by the processing conditions and the storage temperature and time were examined. The standard sample made by traditional method could be kept at room temperature$(20{\circ}C)$ for 3 days and the multipuncture force measured at the end of marketable quality was 700g. The hardening rate increased rapidly by storing at $5^{\circ}C$ and the ratio of hardening rate constants between room temperature and $5^{\circ}C$ storage reached to $1.3{\sim}3.3$ depending on the processing condition. The largest ratio was observed by the sample made from pressure cooker. The addition of corn syrup retarded the hardening rate. The pressure cooking resulted in making too soft product, which diminished the panel preference, but it extend the shelf-life when products were stored at $5^{\circ}C$ microwave cooking resulted in making too hard texture which was not acceptable. The overall quality preference of Yaksik was decided by the textural preference and the latter showed significant inverse correlation with the maximum force of multipuncture test. Therefore, it was concluded that multipuncture test was useful for the measurement of the quality of Yaksik.

• Journal of Korean Society of Forest Science
• /
• v.112 no.1
• /
• pp.32-39
• /
• 2023

Using the logarithmic methods and the generalized method of moments (GMM), this study developed carbon storage equations for maple trees (Acer palmatum Thunb.) planted in an urban settlement area. A total of 20 maple trees of various ages and diameters were destructively harvested to determine their dry weight and carbon concentration by component. The allometric equations with DBH and DBH²×H as independent variables were developed to estimate the carbon storage for each tree component. The carbon concentration of tree components was the highest in stem wood (49.8%) and lowest in stem bark (46.5%). Allometric equations to estimate the carbon storage of tree components (stem, root, aboveground, and total) showed a similar coefficient of determinations (R²) between the allometric equations of the logarithmic method (0.7494-0.9036) and the GMM (0.7085-0.8847). However, the R² values of the leaves and branches were in the range of 0.3027 to 0.6380, lower than those of the R² of the other tree components. These results indicate that the carbon storage of maple trees growing in urban settlement areas can be efficiently predicted from the equations of GMM methods in the case of a small sample size or the heteroscedasticity of logarithmic equations.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.51 no.spc1
• /
• pp.92-102
• /
• 2006

Abundant proteins often cause problems in proteome study. Glutelin family proteins (hereafter referred to glutelin) are present in rice proteome sample as over-whelming constituents with very high abundance. In order to increase the number of identified proteins in rice proteome study, we developed a newly improved method for sample preparation through the removal of glutelin. When the protein samples from rice seed were extracted by the conventional trichloroacetic acid (TCA) extraction method, glutelin accounts for about 60% of total rice seed proteins in SDS gels. Using our new water extraction method, glutelin consists of only about 10% of total proteins. After analyzing on a two-dimensional gel electrophoresis (2-DE), 937 protein spots were detected using the conventional TCA extraction method. On the other hand, 1240 proteins could be seen using the new water extraction method. The selectivity for non-glutelin and less abundant protein by the water extraction method was also confirmed by ESI-Q/TOF mass spectrometry analysis. Thus, the new water extraction method developed here can be efficiently used to study the proteome analysis of rice storage seed.

• The Korean Journal of Food And Nutrition
• /
• v.25 no.4
• /
• pp.1033-1038
• /
• 2012

This study was done to provide basic information about the storage and distribution of specialty grade coffee of which the market will be expanded through customer sensory evaluation according to the storage period of specialty grade coffee by the SCAA classified method with consideration to defective beans and scent. The specialty grade coffee sample of this study was extracted on day 1, day 14, and day 28. The water content showed a significant reduction on the 28th storage day and there was no pH change according to the storage period. Color degree was brightened according to the preservation period before and after grinding but there was no significant difference. The panels for sensory evaluation considered of 24 university. The sensory evaluation consist of aroma, bitterness, and astringency, acidity, aftertaste, overall satisfaction, and items for strength estimation consist of aroma, acidity and bitterness. The sensory evaluation was expressed by applying a 5 point Likert scale. The results showed that as the storage period increased so too did the aroma and the strength of bitterness. Preference was the highest on day 1 in every items except aroma and astrigency. However on day 14 and day 28, most of the sensory evaluation became low and then became high, which was inconsistent. Male students were not consistent in their evaluation according to the preservation period, but female students rated aroma and bitterness the lowest on preservation period day 1 and they prefer after a storage period of 1 day in regards to the entire degree of satisfaction including sour test. astrigency and aftertaste. The analysis of visiting frequency for coffee shops used demonstrated that the longer the preservation period, the lower the preference but was not significant in the case of involving a little frequency group. The group that did not like Americano coffee evaluated that the longer the preservation period, the lower the preference based on Americano coffee preference analysis. There was no consistency between the storage period day 14 and day 28 in strength and preference, but preference for storage period day 1 was high in every group, which means that the quality of coffee is affected by the preservation period.