• 제목/요약/키워드: Salt form

검색결과 346건 처리시간 0.026초

팽창재를 혼입한 고내구성 해양콘크리트의 염화물 확산특성에 관한 연구 (A Study on the Chloride Migration Properties of High Durable Marine Concrete Using the Expansion Production Admixture)

  • 김경민;류동우;박상준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.697-700
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    • 2008
  • 본 연구에서는 고로슬래그 혼합시멘트와 3성분계 저발열 혼합시멘트를 대상으로 하고, 여기에 CSA계 팽창재를 혼입함으로서 이에 따른 수축보상 효과와 함께 염해저항 특성에 미치는 영향에 대하여 검토하였다. 검토결과, 배합조건이 OPC이고, 팽창재 혼입율이 8%인 경우는 팽창재를 혼입하지 않은 경우에 비해 최대 43.7배까지팽창하는 것으로 평가되었고, 굵은골재 최대치수가 콘크리트의 길이변화특성에 미치는 영향은 적은 것으로 나타났다. 염해저항성은 굵은골재 최대치수가 클수록, 그리고 팽창재 혼입율이 증가할수록 개선되는 것으로 평가되었는데, 본 연구범위에서는 팽창재를 8% 혼입한 콘크리트의 염해저항성이 팽창재를 혼입하지 않은 경우에 비해 약 16% 정도 유리한 것으로 평가되었다.

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규불화염계 수화열 저감제가 첨가된 시멘트 모르타르의 수화열 변화 및 균열저감 특성 (Hydration Heat and Crack-Reducing Properties of Cement Mortar Added Fluosilicate Salt Based Hydration Heat Reducer)

  • 김진용;이효송;이영우;김도수;이병기;길배수;한승구
    • 한국세라믹학회지
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    • 제42권3호
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    • pp.198-204
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    • 2005
  • 본 연구에서는 규불화염, 가용성 실리카, 방향족계 고분자 축합물 그리고 잠열특성을 지닌 질산염계 무기화합물로 구성된 규불화염계 수화열 저감제를 시멘트 모르타르의 수화열 및 건조수축에 미치는 영향을 조사하였다. 규불화염계 수화열 저감제의 첨가로 시멘트 모르타르의 단열상승온도 및 건조수축에 의한 길이변화가 저감되는 특성을 나타내었다. 또한, 규불화염계 수화열 저감제가 첨가된 판상형 시멘트 모르타르 시험체의 균열 패턴을 측정한 결과, 수화열 저감과 건조수축에 의해 길이변화가 저감되는 복합적 효과를 통해 시멘트 모르타르의 균열저감성이 개선되는 것을 확인하였다.

Effects of kimchi supplementation on blood pressure and cardiac hypertrophy with varying sodium content in spontaneously hypertensive rats

  • Lee, Seung-Min;Cho, Yoon-Su;Chung, Hye-Kyung;Shin, Dong-Hyuk;Ha, Woel-Kyu;Lee, Sang-Chul;Shin, Min-Jeong
    • Nutrition Research and Practice
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    • 제6권4호
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    • pp.315-321
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    • 2012
  • We tested the effects of dietary intake of freeze-dried Korean traditional fermented cabbage (generally known as kimchi) with varying amounts of sodium on blood pressure and cardiac hypertrophy in spontaneously hypertensive rats (SHRs). Wistar-Kyoto rats (WKY), as a control group, received a regular AIN-76 diet, and the SHRs were divided into four groups. The SHR group was fed a regular diet without kimchi supplementation, the SHR-L group was fed the regular diet supplemented with low sodium kimchi containing 1.4% salt by wet weight, which was provided in a freeze-dried form, the SHR-M group was supplemented with medium levels of sodium kimchi containing 2.4% salt, and the SHR-H group was supplemented with high sodium kimchi containing 3.0% salt. Blood pressure was measured over 6 weeks, and cardiac hypertrophy was examined by measuring heart and left ventricle weights and cardiac histology. SHRs showed higher blood pressure compared to that in WKY rats, which was further elevated by consuming high sodium containing kimchi but was not influenced by supplementing with low sodium kimchi. None of the SHR groups showed significant differences in cardiac and left ventricular mass or cardiomyocyte size. Levels of serum biochemical parameters, including blood urea nitrogen, creatinine, glutamic-oxaloacetic transaminase, glutamic-pyruvic transaminase, sodium, and potassium were not different among the groups. Elevations in serum levels of aldosterone in SHR rats decreased in the low sodium kimchi group. These results suggest that consuming low sodium kimchi may not adversely affect blood pressure and cardiac function even under a hypertensive condition.

니켈 도금액의 붕산분석에 관한 연구 (Theoretical Study of Boric Acid Determination In Nickel Plating Solution)

  • 염희택
    • 한국표면공학회지
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    • 제4권1호
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    • pp.5-15
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    • 1971
  • "Rapid Determination of Boric Acid in Nickel Plating Solution" by the addition of Na$_2$C$_2$O$_4$ and thus preventing the precipitation of i(OH)$_2$ during titiration , has previously been reported. In this paper, the exact amount of glycerine and the complexing possibility of oxalate with nickel has been determined by measn of conductivity titrations. This experimental work has been supported by the mathematical application of the Debye-Huckel and mass action equitions as well as statistical analysis. The results were ; (1) Fro determining boric acid in nickel plating solution, 20 ml of 400ml/ι glycerine was sufficient, since 97% of the H$_3$BO$_3$ was dissoicated by this addition. (2) In the absence of Na$_2$C$_2$O$_4$ the continious precipitation of Ni(OH)$_2$ during titration with NaOH even past end -point for boric acid determination resulted in considerable anlaytical error. (3) In the presence of Na$_2$C$_2$O$_4$ during titration , Ni++ combined with C$_2$O$_4$-to form NiC$_2$O$_4$. The solution with this precititate of very fine, colloidal , trantsparent particles, remained quite clear for approximately 2 hours. Therefore it was shown that the presence of Na$_2$C$_2$O$_4$ prevents the formation of gross Ni(OH)$_2$ precititation by forming NiC$_2$O$_4$ instead of a complex salt with Ni++ , which did not interfere with the visible determination of the end point for boric acid with NaOH titation. This observous may be interpreted in the light of the previously published solubility ratio for NiC$_2$O$_4$ and Ni(OH)$_2$, 0.3mg/100g H$_2$O(25$^{\circ}C$), respectively. Precipitation of the less soluble , albeit transparent salt, NiC$_2$O$_4$ precluded therefore the precipitation of the Ni(OH)$_2$ salt.

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코치닐 염색(染色)에서 키토산처리(處理) 방법(方法)의 변화(變化)가 면(綿), 나일론, PET의 염색(染色)에 미치는 영향(影響) (II) - 세탁(洗濯)에 의한 색상변화(色相變化), 세탁견뢰도(洗濯堅牢度)와 마찰견뢰도(摩擦堅牢度) 특성(特性)에 관(關)하여 - (Effect of Chitosan Treatment Methods on the Dyeing of Cotton, Nylon, and PET using Cochineal (II) - Focusing on Color Change by Laundering, Washfastness and Abrasion Fastness -)

  • 이동민;전동원;김종준
    • 패션비즈니스
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    • 제9권2호
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    • pp.71-83
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    • 2005
  • In this study, we reviewed the color changes accompanying the laundering, wash fastness, and abrasion fastness of chitosan-treated cochineal-dyed fabrics. The treatment methods were classified into two based on the chitosan treatment: (Method 1): fabric specimens were pre-treated with chitosan prior to the dyeing procedure in salt form. (Method 2): the state of chitosan acid salt formation, coated on the yarn surface, was destroyed and neutralized prior to the dyeing process. The changes in the chitosan treatment methods bear more important meaning in view of the durability. In Method 1, it is highly likely for the chitosan to be detached from the surface by water during laundering since the chitosan is coated as acid salt state. In Method 2, the resistance d the chitosan to water was supposed to revive since the chitosan would return to its original state. Differences in the resistance of the chitosan treatrrent, however, according to the Method 1 and Method 2, fell short of our expectations. In Method 2, the wash fastness did not improve as we expected since the bond between the fibers comprising fabric specimens and the chitosan is not high even if the chitosan itself has high resistance to water.

芳香族 디히드라진에 關한 硏究 (第 1 報). 테트라아조늄염을 通한 파라페닐렌디히드라진의 합성 및 디히드라존의 生成 (Studies on Aromatic Dihydrazines (I). Synthesis of p-Phenylenedihydrazine via Tetrazonium Salt and Formation of Dihydrazones)

  • 이우영
    • 대한화학회지
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    • 제18권1호
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    • pp.50-57
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    • 1974
  • 芳香族디아민을 강한 광물산의 妓質中에서 디아조化하고, 이때 얻은 테트라아조늄염을 還元함으로서 芳香族 디히드라진類의 合成에 응용할 수 있는 실용적인 方法을 創案하였다. 파라페닐렌디아민을 진한 鹽酸 또는 45% 過鹽素酸을 妓質로 해서 低溫에서 아질산나트륨으로디아조化하여 얻은 테트라아조늄鹽을 염화주석(II)으로 還元하여 파라페닐렌디히드라진(PPDH)을 鹽酸鹽의 微細한 針狀結晶으로 分離하였다. PPDH의 遊離鹽期는 空氣中에서 酸化되기 쉽기 때문에不安定하여 分離할수 없었다. PPDH${\cdot}$2HCl은 明確한 융점을 보이지 않고 $^180{\circ}C$에서 炭化되면서 分解하였다. PPDH는 芳香族 모노히드라진과 유사한 性質이 있었으며, 초산염의 緩衝溶液에서 알데히드 및 케톤과 반응시키면 재빨리 反應하여 노랑색 내지 갈색을 띤 縮合化合物인 디히드라존이 生成되었다. 이것은 PPDH가 디카르보닐化合物과 反應하여 高分子의 폴리마나 還狀縮合物을 形成할 것임을 暗示한다.

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Chlorination of TRU/RE/SrOx in Oxide Spent Nuclear Fuel Using Ammonium Chloride as a Chlorinating Agent

  • Yoon, Dalsung;Paek, Seungwoo;Lee, Sang-Kwon;Lee, Ju Ho;Lee, Chang Hwa
    • 방사성폐기물학회지
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    • 제20권2호
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    • pp.193-207
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    • 2022
  • Thermodynamically, TRUOx, REOx, and SrOx can be chlorinated using ammonium chloride (NH4Cl) as a chlorinating agent, whereas uranium oxides (U3O8 and UO2) remain in the oxide form. In the preliminary experiments of this study, U3O8 and CeO2 are reacted separately with NH4Cl at 623 K in a sealed reactor. CeO2 is highly reactive with NH4Cl and becomes chlorinated into CeCl3. The chlorination yield ranges from 96% to 100%. By contrast, U3O8 remains as UO2 even after chlorination. We produced U/REOx- and U/SrOx-simulated fuels to understand the chlorination characteristics of the oxide compounds. Each simulated fuel is chlorinated with NH4Cl, and the products are dissolved in LiCl-KCl salt to separate the oxide compounds from the chloride salt. The oxide compounds precipitate at the bottom. The precipitate and salt phases are sampled and analyzed via X-ray diffraction, scanning electron microscope-energy dispersive spectroscopy, and inductively coupled plasma-optical emission spectroscopy. The analysis results indicate that REOx and SrOx can be easily chlorinated from the simulated fuels; however, only a few of U oxide phases is chlorinated, particularly from the U/SrOx-simulated fuels.

Effect of Heavy Metal Resistant and Halotolerant Rhizobacterium Bacillus safensis KJW143 on Soybean under Salinty and Cadmium Exposure

  • Eun-Hae Kwon;Ho-Jun Gam;Yosep Kang;Jin-Ryeol Jeon;Ji-In Woo;Sang-Mo Kang;In-Jung Lee
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2023년도 춘계학술대회
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    • pp.32-32
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    • 2023
  • Cadmium and salt exposure to crops is considered vulnerable for production as well as consumption. To address these challenges, the current study aimed to mitigate the toxicity induced by salt and cadmium in soybean plants through the application of bacterial strain Bacillus safensis KJW143 isolated from the rhizosphere of oriental melon..The bioassay analysis revealed that KJW143 is a highly salt-tolerant and cadmium-resistant (Cd) strain with an innate ability to produce melatonin, gibberellin (GA3), Indole-3-Acetic Acid (IAA), and organic acids (i.e., acetic, succinic, lactic, and propionic acids). Soybean plants at 20 days old were treated with KJW143 in a different form (pellet, broth, and together) and their effect on plant performance was investigated. Inoculation with KJW143enhanced plant biomass and growth attributes in soybean plants compared to the control (non-treated). In particular, we observed that only pellet-treated showed 65%, 27.5%, and 28.7% increase in growth (shoot fresh weight) compared to broth, broth with pellet, and control. In addition, bacterial strain KJW143 treatment (only pellet) modulated the physiochemical apparatus of soybean plants by increasing glucose (390%), arabinose (166%), citric acid (22.98%) and reducing hydrogen peroxide (29.7%), catalase (32.1%), salicylic acid (25.6%) compared to plants with combined stressed plants (cd and salinity). These findings suggest that bacterial strain KJW143 could be usedas a biofertilizer to minimize the probable risk of heavy metal and salinity stress on crops.

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한반도 해안염습지와 사구 염생식물 분포 (Distribution of halophytes in coastal salt marsh and on sand dunes in Korea)

  • 심현보;조원범;최병희
    • 식물분류학회지
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    • 제39권4호
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    • pp.264-276
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    • 2009
  • 본 연구는 한반도산 염생식물 분포를 밝히기 위해 해안 염습지와 사구 95지역을 조사하였다. 연구결과 남한의 해안과 섬지역 등에서 21과 44속 57종 4변종 1품종 등 62 염생식물이 기록되었다. 이 중 33분류군은 사구에 자라며, 나머지 29분류군은 염습지에 자라는 식물이다. 61지역이 조사된 서해안에는 58분류군이 분포하였으며, 이들 중 염습지에서는 나문재, 칠면초, 갈대, 갯잔디, 천일사초가, 사구에서는 수송나물, 갯완두, 갯길경, 갯메꽃이 많이 발견되었다. 한편 15지역이 조사된 남해안에는 서해안 보다 적은 45분류군이 분포하였다. 13지역이 조사된 동해안에는 44분류군이 분포하였으며, 흔히 발견된 식물은 수송나물, 갯완두, 갯메꽃으로 모두 사구식물이다. 해란초는 한반도에서는 동해안에서만 조사되었다. 6 지역이 조사된 제주도에는 30분류군이 분포하였다. 해녀콩은 국내에서는 제주도에서만 발견되었다. 한국산 염생식물 중 약 절반은 12종의 명아주과, 12종의 벼과, 7종의 국화과 등 3과에 속하였다.

겔화 전처리법을 이용한 폐용융염의 고형화 (Solidification of Molten Salt Waste by Gel-Route Pre-treatment)

  • 박환서;김인태;김환영;유승곤;김준형
    • 방사성폐기물학회지
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    • 제3권1호
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    • pp.57-65
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    • 2005
  • 본 연구는 사용 후 핵연료의 금속전환 공정에서 발생되는 폐용융염을 고형화하는 방법으로 GRSS(Gel-Route Slabilization/Solidifcation)개념을 이용한 전처 리법을 제안하였다. Sodium silicate와 H3p04로 구성된 물질계에서는 SiO$_2$에 의해 형성되는 반응모듈 내에서 휘발성 핵종은 열적으로 안정한 화합물로 전환된다. 얻어진 생성물은 붕규산 유리매질과의 반응을 통하여 Li는 Li$_{3}$PO$\_4$ 형태로 유지되며 Cs 및 Sr은 유리매질내에 포용될 수 있다. 또한 sodium silicate, H$_{3}$PO$_4$ 및 ZrCl$_4$로 이루어진 물질계를 이용하여 내구성이 우수한 WZP 세라믹 고화매질을 합성하였다. $700^{circ}C$이상에서 NZP구조가 형성되며, Cs가 Li보다 우선하여 NZP구조를 형성하였다. 이상의 결과로부터, GRSS를 이용한 폐용융염의 전처리는 단순한 공정과 열적 안정성을 통하여 검증된 고화매질로 고형화가 가능토록하는 유효한 접근법이라 할 수 있으며, 수화학적 안정성의 검증을 통하여 ANL의 제올라이트를 이용한 고화법에 대한 대안이 될 것으로 기대된다.

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