• Title/Summary/Keyword: Salt form

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A Study on the Chloride Migration Properties of High Durable Marine Concrete Using the Expansion Production Admixture (팽창재를 혼입한 고내구성 해양콘크리트의 염화물 확산특성에 관한 연구)

  • Kim, Kyoung-Min;Ryu, Dong-Woo;Park, Sang-Joon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.697-700
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    • 2008
  • Recently, high strength, flowability, and durability of concrete were required according to increase of large scale and high rise structure. However, cracks occurred easily on the high performance concrete. In this reason, using expansion agent for reducing shrinkage cracks were increased, but it did not consider on durability of high performance concrete. Accordingly, this study1 investigated the resistance of shrinkage and damage form salt by mixing CSA expansion agent on the blast-furnace slag cement and mixed cement for the low heat of hydration by three components. The cases that 8% of expansion agent was mixed and the proportion was OPC were expanded till 43.7 times compared with control concrete. For the resistance to the damage of salt, it was improved when mixing ratio was incresed and the maximum size of coarse aggregate growed bigger. In this study, the resistance to the damage of salt of the cases that 8% of expansion agent was mixed was improved about 16% compared with control concrete.

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Hydration Heat and Crack-Reducing Properties of Cement Mortar Added Fluosilicate Salt Based Hydration Heat Reducer (규불화염계 수화열 저감제가 첨가된 시멘트 모르타르의 수화열 변화 및 균열저감 특성)

  • Kim, Jin-Yong;Lee, Hyo-Song;Rhee, Young-Woo;Kim, Do-Su;Lee, Byoung-Ky;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.198-204
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    • 2005
  • Fluosilicate salts based hydration heat reducer(SWP-HR), used in this study, is composed of fluosilicate salts, soluble silica, aromatic polymer condensate and nitrate salt based inorganic compound with latent heat property. Effects of SWP-HR addition on the hydration heat and anti-crack property of cement mortar were investigated. Adiabatic hydration temperature and drying shrinkage length of SWP-HR added cement mortar had a tendency to decrease compared to those of cement mortar without SWP-HR addition. Also, it was confirmed through crack pattern experiment of plate-form specimen for elucidating crack-reducing characteristic that anti-crack property of SWP-HR added cement mortar was improved.

Effects of kimchi supplementation on blood pressure and cardiac hypertrophy with varying sodium content in spontaneously hypertensive rats

  • Lee, Seung-Min;Cho, Yoon-Su;Chung, Hye-Kyung;Shin, Dong-Hyuk;Ha, Woel-Kyu;Lee, Sang-Chul;Shin, Min-Jeong
    • Nutrition Research and Practice
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    • v.6 no.4
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    • pp.315-321
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    • 2012
  • We tested the effects of dietary intake of freeze-dried Korean traditional fermented cabbage (generally known as kimchi) with varying amounts of sodium on blood pressure and cardiac hypertrophy in spontaneously hypertensive rats (SHRs). Wistar-Kyoto rats (WKY), as a control group, received a regular AIN-76 diet, and the SHRs were divided into four groups. The SHR group was fed a regular diet without kimchi supplementation, the SHR-L group was fed the regular diet supplemented with low sodium kimchi containing 1.4% salt by wet weight, which was provided in a freeze-dried form, the SHR-M group was supplemented with medium levels of sodium kimchi containing 2.4% salt, and the SHR-H group was supplemented with high sodium kimchi containing 3.0% salt. Blood pressure was measured over 6 weeks, and cardiac hypertrophy was examined by measuring heart and left ventricle weights and cardiac histology. SHRs showed higher blood pressure compared to that in WKY rats, which was further elevated by consuming high sodium containing kimchi but was not influenced by supplementing with low sodium kimchi. None of the SHR groups showed significant differences in cardiac and left ventricular mass or cardiomyocyte size. Levels of serum biochemical parameters, including blood urea nitrogen, creatinine, glutamic-oxaloacetic transaminase, glutamic-pyruvic transaminase, sodium, and potassium were not different among the groups. Elevations in serum levels of aldosterone in SHR rats decreased in the low sodium kimchi group. These results suggest that consuming low sodium kimchi may not adversely affect blood pressure and cardiac function even under a hypertensive condition.

Theoretical Study of Boric Acid Determination In Nickel Plating Solution (니켈 도금액의 붕산분석에 관한 연구)

  • 염희택
    • Journal of the Korean institute of surface engineering
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    • v.4 no.1
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    • pp.5-15
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    • 1971
  • "Rapid Determination of Boric Acid in Nickel Plating Solution" by the addition of Na$_2$C$_2$O$_4$ and thus preventing the precipitation of i(OH)$_2$ during titiration , has previously been reported. In this paper, the exact amount of glycerine and the complexing possibility of oxalate with nickel has been determined by measn of conductivity titrations. This experimental work has been supported by the mathematical application of the Debye-Huckel and mass action equitions as well as statistical analysis. The results were ; (1) Fro determining boric acid in nickel plating solution, 20 ml of 400ml/ι glycerine was sufficient, since 97% of the H$_3$BO$_3$ was dissoicated by this addition. (2) In the absence of Na$_2$C$_2$O$_4$ the continious precipitation of Ni(OH)$_2$ during titration with NaOH even past end -point for boric acid determination resulted in considerable anlaytical error. (3) In the presence of Na$_2$C$_2$O$_4$ during titration , Ni++ combined with C$_2$O$_4$-to form NiC$_2$O$_4$. The solution with this precititate of very fine, colloidal , trantsparent particles, remained quite clear for approximately 2 hours. Therefore it was shown that the presence of Na$_2$C$_2$O$_4$ prevents the formation of gross Ni(OH)$_2$ precititation by forming NiC$_2$O$_4$ instead of a complex salt with Ni++ , which did not interfere with the visible determination of the end point for boric acid with NaOH titation. This observous may be interpreted in the light of the previously published solubility ratio for NiC$_2$O$_4$ and Ni(OH)$_2$, 0.3mg/100g H$_2$O(25$^{\circ}C$), respectively. Precipitation of the less soluble , albeit transparent salt, NiC$_2$O$_4$ precluded therefore the precipitation of the Ni(OH)$_2$ salt.

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Effect of Chitosan Treatment Methods on the Dyeing of Cotton, Nylon, and PET using Cochineal (II) - Focusing on Color Change by Laundering, Washfastness and Abrasion Fastness - (코치닐 염색(染色)에서 키토산처리(處理) 방법(方法)의 변화(變化)가 면(綿), 나일론, PET의 염색(染色)에 미치는 영향(影響) (II) - 세탁(洗濯)에 의한 색상변화(色相變化), 세탁견뢰도(洗濯堅牢度)와 마찰견뢰도(摩擦堅牢度) 특성(特性)에 관(關)하여 -)

  • Lee, Dong-Min;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.9 no.2
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    • pp.71-83
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    • 2005
  • In this study, we reviewed the color changes accompanying the laundering, wash fastness, and abrasion fastness of chitosan-treated cochineal-dyed fabrics. The treatment methods were classified into two based on the chitosan treatment: (Method 1): fabric specimens were pre-treated with chitosan prior to the dyeing procedure in salt form. (Method 2): the state of chitosan acid salt formation, coated on the yarn surface, was destroyed and neutralized prior to the dyeing process. The changes in the chitosan treatment methods bear more important meaning in view of the durability. In Method 1, it is highly likely for the chitosan to be detached from the surface by water during laundering since the chitosan is coated as acid salt state. In Method 2, the resistance d the chitosan to water was supposed to revive since the chitosan would return to its original state. Differences in the resistance of the chitosan treatrrent, however, according to the Method 1 and Method 2, fell short of our expectations. In Method 2, the wash fastness did not improve as we expected since the bond between the fibers comprising fabric specimens and the chitosan is not high even if the chitosan itself has high resistance to water.

Studies on Aromatic Dihydrazines (I). Synthesis of p-Phenylenedihydrazine via Tetrazonium Salt and Formation of Dihydrazones (芳香族 디히드라진에 關한 硏究 (第 1 報). 테트라아조늄염을 通한 파라페닐렌디히드라진의 합성 및 디히드라존의 生成)

  • Woo Young Lee
    • Journal of the Korean Chemical Society
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    • v.18 no.1
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    • pp.50-57
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    • 1974
  • A practical method applicable to the synthesis of aromatic dihydrazines was proposed by reducing tetrazonium salt in strong mineral acid media. By diazotizing p-phenylenediamine with sodium nitrite in a medium of concentrated hydrochloric acid or 45 % perchloric acid at $-5 {\sim} -10{\circ}C$ and reducing the tetrazonium salt with stannous chloride, p-phenylenedihydrazine (PPDH) was separated in the form of hydrochloride as colorless fine needles. Since PPDH was subject to oxidation and unstable, the free base could not be isolated. PPDH${\cdot}$2HCl was decomposed at $^180{\circ}C$ without showing sharp melting point. It behaved largely as aromatic monohydrazines, and reacted immediately with aldehydes and ketones in acetate buffer, giving generally yellow to brownish condensation products, dihydrazones. This suggests that PPDH will react with dicarbonyl compounds producing high molecular polymers or cyclization products.

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Chlorination of TRU/RE/SrOx in Oxide Spent Nuclear Fuel Using Ammonium Chloride as a Chlorinating Agent

  • Yoon, Dalsung;Paek, Seungwoo;Lee, Sang-Kwon;Lee, Ju Ho;Lee, Chang Hwa
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.2
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    • pp.193-207
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    • 2022
  • Thermodynamically, TRUOx, REOx, and SrOx can be chlorinated using ammonium chloride (NH4Cl) as a chlorinating agent, whereas uranium oxides (U3O8 and UO2) remain in the oxide form. In the preliminary experiments of this study, U3O8 and CeO2 are reacted separately with NH4Cl at 623 K in a sealed reactor. CeO2 is highly reactive with NH4Cl and becomes chlorinated into CeCl3. The chlorination yield ranges from 96% to 100%. By contrast, U3O8 remains as UO2 even after chlorination. We produced U/REOx- and U/SrOx-simulated fuels to understand the chlorination characteristics of the oxide compounds. Each simulated fuel is chlorinated with NH4Cl, and the products are dissolved in LiCl-KCl salt to separate the oxide compounds from the chloride salt. The oxide compounds precipitate at the bottom. The precipitate and salt phases are sampled and analyzed via X-ray diffraction, scanning electron microscope-energy dispersive spectroscopy, and inductively coupled plasma-optical emission spectroscopy. The analysis results indicate that REOx and SrOx can be easily chlorinated from the simulated fuels; however, only a few of U oxide phases is chlorinated, particularly from the U/SrOx-simulated fuels.

Effect of Heavy Metal Resistant and Halotolerant Rhizobacterium Bacillus safensis KJW143 on Soybean under Salinty and Cadmium Exposure

  • Eun-Hae Kwon;Ho-Jun Gam;Yosep Kang;Jin-Ryeol Jeon;Ji-In Woo;Sang-Mo Kang;In-Jung Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2023.04a
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    • pp.32-32
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    • 2023
  • Cadmium and salt exposure to crops is considered vulnerable for production as well as consumption. To address these challenges, the current study aimed to mitigate the toxicity induced by salt and cadmium in soybean plants through the application of bacterial strain Bacillus safensis KJW143 isolated from the rhizosphere of oriental melon..The bioassay analysis revealed that KJW143 is a highly salt-tolerant and cadmium-resistant (Cd) strain with an innate ability to produce melatonin, gibberellin (GA3), Indole-3-Acetic Acid (IAA), and organic acids (i.e., acetic, succinic, lactic, and propionic acids). Soybean plants at 20 days old were treated with KJW143 in a different form (pellet, broth, and together) and their effect on plant performance was investigated. Inoculation with KJW143enhanced plant biomass and growth attributes in soybean plants compared to the control (non-treated). In particular, we observed that only pellet-treated showed 65%, 27.5%, and 28.7% increase in growth (shoot fresh weight) compared to broth, broth with pellet, and control. In addition, bacterial strain KJW143 treatment (only pellet) modulated the physiochemical apparatus of soybean plants by increasing glucose (390%), arabinose (166%), citric acid (22.98%) and reducing hydrogen peroxide (29.7%), catalase (32.1%), salicylic acid (25.6%) compared to plants with combined stressed plants (cd and salinity). These findings suggest that bacterial strain KJW143 could be usedas a biofertilizer to minimize the probable risk of heavy metal and salinity stress on crops.

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Distribution of halophytes in coastal salt marsh and on sand dunes in Korea (한반도 해안염습지와 사구 염생식물 분포)

  • Shim, Hyun-Bo;Cho, Won-Bum;Choi, Byoung-Hee
    • Korean Journal of Plant Taxonomy
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    • v.39 no.4
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    • pp.264-276
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    • 2009
  • To elucidate the distribution of halophytes in Korea, we surveyed 95 coastal salt marsh and sand dune areas. As a result, 62 halophytes of 57 species, 4 varieties and 1 form belonging to 44 genera and 21 families were recorded from coastal regions and islands of South Korea. Of these, 33 taxa were plants growing on sand dunes and the other 29 in salt marsh. Fifty eight taxa were found on the west coast, which was surveyed at 61 areas. The most common species among them were Suaeda glauca (Bunge) Bunge, Suaeda japonica Makino, Phragmites communis Trin., Zoysia sinica Hance, Carex scabrifolia Steud. in salt marsh, and Salsola komarrovii Iljin, Lathyrus japonicus Willd., Limonium tetragonum (Thunb.) A.A. Bulloc, Calystegia soldanella Roem. & Schult. on sand dunes. On the other hand, only 45 taxa were found on the southern coast, surveyed at 15 areas. On the east coast, surveyed at 13 areas, 44 taxa were found. The most common species were Salsola komarrovii Iljin, Lathyrus japonicus Willd., Calystegia soldanella Roem. & Schult., on sand dunes and Linaria japonica Miq., which on the Korean peninsula is found only on the east coast. On Jeju Island, surveyed at 6 areas, 30 taxa of halophytes were found. Canavalia lineata (Thunb.) DC. is found in Korea only on Jeju Island. About half of the Korean halophytes were members of three families (Chenopodiaceae: 12 species, Poaceae: 12 species and Asteraceae: 7 species).

Solidification of Molten Salt Waste by Gel-Route Pre-treatment (겔화 전처리법을 이용한 폐용융염의 고형화)

  • Park Hwan Seo;Kim In Tae;Kim Hwan Young;Ryu Seung Kon;Kim Joon Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.1
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    • pp.57-65
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    • 2005
  • This study suggested a new method for the solidification of molten salt waste generated from the electro-metallurgical process in the spent fuel treatment. Using binary material system, sodium silicate and phosphoric acid, metal chlorides were converted into metal phosphate in the micro-reaction module formed by SiO$_{2} particles. The volatile element in the reaction module would little vaporized below 1100$^{circ}$C After the gel product was mixed with borosilicate glass powder and thermally treated at 1000$^{circ}$C, li exists as Li$_{3}$PO$_4$ separated from glass phase and, Cs and Sr would be incorporated into an amorphous phase from XRD analysis. In case of the addition of ZrCl$_{4}$ to the binary system, the gel products were transformed into NZP structure considered as an prospective ceramic waste form after heat-treatment above 700 $^{circ}$C. From these results, the gel-route pretreatment can be considered as an effective approach to the solidincation of molten salt waste by the confirmed process or waste form and this also would be an alternative method on the ANL method using zeolites in USA by the confirmation of its chemical durability as an future work.

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