• Title/Summary/Keyword: SVET

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Anti-Corrosion Performance of the Novel Pigment, Ion-Exchanged Zeolite for the Protection of Galvanized Steel (아연도금강판의 방식을 위한 새로운 방청안료인 이온 교환된 제올라이트의 방청 성능)

  • Kim, Jung-Teag;Jeong, Ho-Su;Ryu, Sang-Su;Lee, Gun-Dae;Park, Jong-Myung
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.745-751
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    • 2011
  • In this study, zinc or cerium exchanged zeolite was introduced to develop a novel anti-corrosion pigment. The primer paint was made using them and was coated on galvanized(GI) steel. The anti-corrosion performance was measured using electrochemical impedance spectroscopy(EIS). And scanning vibrating electrode technique(SVET) was employed to observe the cut-edge corrosion process of the coated GI steel. From EIS and SVET results, it could be confirmed that Ce ion-exchanged zeolite showed the anti-corrosion performance higher than Shieldex C303 and Zn ionexchanged zeolite. Finally, it was found that metal ion-exchanged zeolite may provide new possibility as the smart cathodic corrosion inhibitor delivery systems on galvanized steels.

Corrosion Monitoring of PEO-Pretreated Magnesium Alloys

  • Gnedenkov, A.S.;Sinebryukhov, S.L.;Mashtalyar, D.V.;Gnedenkov, S.V.;Sergienko, V.I.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.151-159
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    • 2017
  • The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

Study on Methods of Enhancement and Measurement of Corrosion Resistance for Subsea Equipment made of Aluminum (알루미늄으로 제작된 심해 장비의 부식 저항 능력 향상 방법 및 측정 방법 조사)

  • Seo, Youngkyun;Jung, Jung-Yeul
    • Plant Journal
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    • v.16 no.3
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    • pp.47-52
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    • 2020
  • This study investigated the methodologies to enhance the corrosion resistance and the ways to measure for subsea equipment made of aluminum. The methodologies for the anticorrosion were cathodic protection, conversion coating, anodizing and organic coating. The simply analyzed ways to measure the corrosion resistance were Scanning Electron Microscope (SEM), Electrochemical Impedance Spectroscopy (EIS), Glow discharge optical emission spectrum spectroscopy (GD-OES), Fourier Transform Infrared Spectroscopy (FT-IR), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Scanning Vibrating Electrode Technique (SVET), contact angle and interfacial tension. The most widely used tools for increasing the corrosion resistance were the anodizing and the organic coating. Many ways were evenly used to measure corrosion. The methods more frequently utilized were SEM for the surface investigation and the contact angle to evaluate the corrosion resistance.

Corrosion behavior of Zn-MgZn2 Eutectic Structure in Zn-Mg-Al alloy coated steel (Zn-Mg-Al 합금도금강판의 Zn-MgZn2 공정조직의 부식거동)

  • Lee, Jae-Won;Son, Hong-Gyun;Min, Jae-Gyu;Yu, Yeong-Ran;Gwak, Yeong-Jin;Kim, Tae-Yeop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.280-280
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    • 2012
  • Mg의 첨가한 Zn-Mg-Al 합금도금강판에 형성된 $Zn-MgZn_2$ 공정조직의 부식거동을 이해하고자 진공 고주파 용해로 $MgZn_2$ 제작한 후 Zn와 galvanic coupling하여 $MgZn_2$합금과 Zn간의 galvanic corrosion 거동을 알아보았다. $MgZn_2-Zn$ galvanic coupling의 SVET 결과에서 $MgZn_2$가 anode, Zn가 cathode가 됨을 확인되었다. $MgZn_2$의 Zn와의 galvanic corrosion 평가에서 galvanic current는 Zn 보다 낮은 potential에서 anodic current density를 나타내었으며, galvanic potential은 $MgZn_2$전위로부터 두 합금의 혼합전위를 향해 증가함을 알 수 있었다. Zn-Mg-Al 합금도금강판의 염수분무 평가에서도 초기 $Zn-MgZn_2$ 공정조직에서 $MgZn_2$가 용출되는 것이 관찰되었다.

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